Evaluation and characterisation of chemically modified polymers as secondary electron emitters
Measurements of secondary electron emission coefficient and surface work function Phi are reported for polyacrylonitrile (PAN) and polytetrafluoroethylene (PTFE) in the virgin and chemically modified forms. A single pulse method was used for SEE measurements and a retarding field method for estimati...
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Veröffentlicht in: | Journal of physics. D, Applied physics Applied physics, 1987-12, Vol.20 (12), p.1631-1636 |
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creator | Dake, S B Rajopadhye, N R Bhoraskar, S V |
description | Measurements of secondary electron emission coefficient and surface work function Phi are reported for polyacrylonitrile (PAN) and polytetrafluoroethylene (PTFE) in the virgin and chemically modified forms. A single pulse method was used for SEE measurements and a retarding field method for estimating the work function. Doping of PTFE with alkali metals (Na and Li) and pyrolysis of PAN at 300 deg C led to an increase in the surface conductivity. The processing of the surface effectively increased the SEE yield in these polymers. Electrical conductivity and XPS results were used to explain the chemical structures of modified polymers. 23 ref.--AA |
doi_str_mv | 10.1088/0022-3727/20/12/014 |
format | Article |
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A single pulse method was used for SEE measurements and a retarding field method for estimating the work function. Doping of PTFE with alkali metals (Na and Li) and pyrolysis of PAN at 300 deg C led to an increase in the surface conductivity. The processing of the surface effectively increased the SEE yield in these polymers. Electrical conductivity and XPS results were used to explain the chemical structures of modified polymers. 23 ref.--AA</description><identifier>ISSN: 0022-3727</identifier><identifier>EISSN: 1361-6463</identifier><identifier>DOI: 10.1088/0022-3727/20/12/014</identifier><identifier>CODEN: JPAPBE</identifier><language>eng</language><publisher>Bristol: IOP Publishing</publisher><subject>Applied sciences ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Properties and characterization ; Structure, morphology and analysis</subject><ispartof>Journal of physics. 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D, Applied physics</title><description>Measurements of secondary electron emission coefficient and surface work function Phi are reported for polyacrylonitrile (PAN) and polytetrafluoroethylene (PTFE) in the virgin and chemically modified forms. A single pulse method was used for SEE measurements and a retarding field method for estimating the work function. Doping of PTFE with alkali metals (Na and Li) and pyrolysis of PAN at 300 deg C led to an increase in the surface conductivity. The processing of the surface effectively increased the SEE yield in these polymers. Electrical conductivity and XPS results were used to explain the chemical structures of modified polymers. 23 ref.--AA</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><subject>Structure, morphology and analysis</subject><issn>0022-3727</issn><issn>1361-6463</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1987</creationdate><recordtype>article</recordtype><recordid>eNqNkE1LxDAQhoMouK7-Ai89iAeh23y1aY-y-AULXvRqmKZTjLRNTbrC_nuz7LIXRTwFJs_7MvMQcsnogtGyzCjlPBWKq4zTjPGMMnlEZkwULC1kIY7J7ECckrMQPiileVGyGXm7-4JuDZN1QwJDk5h38GAm9Dbshq6NM-ytga7bJL1rbGuxSUbXbXr0IYGQBDRuaMBvEuzQTD6mYmCKJeGcnLTQBbzYv3Pyen_3snxMV88PT8vbVWok41NaYd7QmuVlo1TNQWCdI68EVZxhJaGAulCqzU3DFQLKHOLVRkgBXPG6rLiYk-td7-jd5xrDpHsbDHYdDOjWQXOpVEHL_F9gHpVGUOxA410IHls9etvHIzWjeitdb5XqrVLN44TrKD2mrvb1EKKx1sNgbDhEFRWykiJiNzvMuvHw-UufHps2wouf8F9LfAMBx50b</recordid><startdate>19871214</startdate><enddate>19871214</enddate><creator>Dake, S B</creator><creator>Rajopadhye, N R</creator><creator>Bhoraskar, S V</creator><general>IOP Publishing</general><general>Institute of Physics</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>7SR</scope><scope>JG9</scope></search><sort><creationdate>19871214</creationdate><title>Evaluation and characterisation of chemically modified polymers as secondary electron emitters</title><author>Dake, S B ; Rajopadhye, N R ; Bhoraskar, S V</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c412t-9e5d0b158d77b2a3eb5e2930721e94a6ab677f5cd27eae45a108c343a272b8923</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1987</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Properties and characterization</topic><topic>Structure, morphology and analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dake, S B</creatorcontrib><creatorcontrib>Rajopadhye, N R</creatorcontrib><creatorcontrib>Bhoraskar, S V</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Research Database</collection><jtitle>Journal of physics. 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subjects | Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Properties and characterization Structure, morphology and analysis |
title | Evaluation and characterisation of chemically modified polymers as secondary electron emitters |
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