Organosiloxanes with functional groups: X. Reactions of H-cyclosiloxanes with 1,4-bis(trimethylsiloxy)but-2-yne to multifunctional surface active compounds
The reaction of H-cyclosiloxanes [Me(H)SiO] n ( 1, n = 4; 2, n = 5) with 1,4-bis(trimethylsiloxy)but-2-yne ( 3) in the presence of a Pt-catalyst has been studied. Depending on the molar ratio, mono-substituted and fully substituted products were obtained in nearly quantitative yield, of which the co...
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| Veröffentlicht in: | Journal of organometallic chemistry 1990-06, Vol.389 (3), p.289-294 |
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| container_end_page | 294 |
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| container_issue | 3 |
| container_start_page | 289 |
| container_title | Journal of organometallic chemistry |
| container_volume | 389 |
| creator | Sonnek, G. Jancke, H. Pasynkiewicz, S. Ziemkowska, W. |
| description | The reaction of H-cyclosiloxanes [Me(H)SiO]
n
(
1,
n = 4;
2,
n = 5) with 1,4-bis(trimethylsiloxy)but-2-yne (
3) in the presence of a Pt-catalyst has been studied. Depending on the molar ratio, mono-substituted and fully substituted products were obtained in nearly quantitative yield, of which the compound 1,4-bis(trimethylsiloxy)but-2-enecyclosiloxane exists in configurational isomers. |
| doi_str_mv | 10.1016/0022-328X(90)85423-V |
| format | Article |
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n
(
1,
n = 4;
2,
n = 5) with 1,4-bis(trimethylsiloxy)but-2-yne (
3) in the presence of a Pt-catalyst has been studied. Depending on the molar ratio, mono-substituted and fully substituted products were obtained in nearly quantitative yield, of which the compound 1,4-bis(trimethylsiloxy)but-2-enecyclosiloxane exists in configurational isomers.</description><identifier>ISSN: 0022-328X</identifier><identifier>EISSN: 1872-8561</identifier><identifier>DOI: 10.1016/0022-328X(90)85423-V</identifier><identifier>CODEN: JORCAI</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Chemistry ; Exact sciences and technology ; Organic chemistry ; Organometalloidal and organometallic compounds ; Preparations and properties ; Si derivatives</subject><ispartof>Journal of organometallic chemistry, 1990-06, Vol.389 (3), p.289-294</ispartof><rights>1990</rights><rights>1990 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/0022-328X(90)85423-V$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=6951632$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Sonnek, G.</creatorcontrib><creatorcontrib>Jancke, H.</creatorcontrib><creatorcontrib>Pasynkiewicz, S.</creatorcontrib><creatorcontrib>Ziemkowska, W.</creatorcontrib><title>Organosiloxanes with functional groups: X. Reactions of H-cyclosiloxanes with 1,4-bis(trimethylsiloxy)but-2-yne to multifunctional surface active compounds</title><title>Journal of organometallic chemistry</title><description>The reaction of H-cyclosiloxanes [Me(H)SiO]
n
(
1,
n = 4;
2,
n = 5) with 1,4-bis(trimethylsiloxy)but-2-yne (
3) in the presence of a Pt-catalyst has been studied. Depending on the molar ratio, mono-substituted and fully substituted products were obtained in nearly quantitative yield, of which the compound 1,4-bis(trimethylsiloxy)but-2-enecyclosiloxane exists in configurational isomers.</description><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Organic chemistry</subject><subject>Organometalloidal and organometallic compounds</subject><subject>Preparations and properties</subject><subject>Si derivatives</subject><issn>0022-328X</issn><issn>1872-8561</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1990</creationdate><recordtype>article</recordtype><recordid>eNpdUV1LwzAUDaLgnP4DH_LgwwZm5qNNWx8EGeqEwUB07C2kabJFumY06bS_xT_ruomITxfuPffcc88B4JLgEcGE32BMKWI0XQwyPEzjiDI0PwI9kiYUpTEnx6D3CzkFZ96_Y4wJw2kPfM3qpayct6X7lJX28MOGFTRNpYJ1lSzhsnbNxt_CxQi-aLnveugMnCDVqvL_IrmOUG79INR2rcOqLffzdpg3AVHUVhoGB9dNGeyfE76pjVQaduxbDZVbb1xTFf4cnBhZen3xU_vg7fHhdTxB09nT8_h-ijSJaUAyVianEiuSURJxybDRlKe8YLmiRS4zpkmCTZqwxGRxESkuEyyNiaK0iDHjrA-uDrwb6ZUsTS0rZb3Y7H6QdSt4FhPO6A52d4DpnZat1bXwyupK6cLWWgVROCsIFl0iorNbdHaLDIt9ImLOvgEdLYO7</recordid><startdate>19900619</startdate><enddate>19900619</enddate><creator>Sonnek, G.</creator><creator>Jancke, H.</creator><creator>Pasynkiewicz, S.</creator><creator>Ziemkowska, W.</creator><general>Elsevier B.V</general><general>Elsevier Science</general><scope>IQODW</scope></search><sort><creationdate>19900619</creationdate><title>Organosiloxanes with functional groups: X. Reactions of H-cyclosiloxanes with 1,4-bis(trimethylsiloxy)but-2-yne to multifunctional surface active compounds</title><author>Sonnek, G. ; Jancke, H. ; Pasynkiewicz, S. ; Ziemkowska, W.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-e152t-a5cfb2a0c192146a30fe2686d3bc2dba93e170f8737f95d4c6a70aff448d50363</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1990</creationdate><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Organic chemistry</topic><topic>Organometalloidal and organometallic compounds</topic><topic>Preparations and properties</topic><topic>Si derivatives</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sonnek, G.</creatorcontrib><creatorcontrib>Jancke, H.</creatorcontrib><creatorcontrib>Pasynkiewicz, S.</creatorcontrib><creatorcontrib>Ziemkowska, W.</creatorcontrib><collection>Pascal-Francis</collection><jtitle>Journal of organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sonnek, G.</au><au>Jancke, H.</au><au>Pasynkiewicz, S.</au><au>Ziemkowska, W.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Organosiloxanes with functional groups: X. Reactions of H-cyclosiloxanes with 1,4-bis(trimethylsiloxy)but-2-yne to multifunctional surface active compounds</atitle><jtitle>Journal of organometallic chemistry</jtitle><date>1990-06-19</date><risdate>1990</risdate><volume>389</volume><issue>3</issue><spage>289</spage><epage>294</epage><pages>289-294</pages><issn>0022-328X</issn><eissn>1872-8561</eissn><coden>JORCAI</coden><abstract>The reaction of H-cyclosiloxanes [Me(H)SiO]
n
(
1,
n = 4;
2,
n = 5) with 1,4-bis(trimethylsiloxy)but-2-yne (
3) in the presence of a Pt-catalyst has been studied. Depending on the molar ratio, mono-substituted and fully substituted products were obtained in nearly quantitative yield, of which the compound 1,4-bis(trimethylsiloxy)but-2-enecyclosiloxane exists in configurational isomers.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/0022-328X(90)85423-V</doi><tpages>6</tpages></addata></record> |
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| ispartof | Journal of organometallic chemistry, 1990-06, Vol.389 (3), p.289-294 |
| issn | 0022-328X 1872-8561 |
| language | eng |
| recordid | cdi_pascalfrancis_primary_6951632 |
| source | Elsevier ScienceDirect Journals Complete - AutoHoldings |
| subjects | Chemistry Exact sciences and technology Organic chemistry Organometalloidal and organometallic compounds Preparations and properties Si derivatives |
| title | Organosiloxanes with functional groups: X. Reactions of H-cyclosiloxanes with 1,4-bis(trimethylsiloxy)but-2-yne to multifunctional surface active compounds |
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