Pyramidalization of the sp2-Hybridized Carbon Atoms in 1,4-Bridged 2,5-Cyclohexadienes

The 2,5‐cyclohexadiene‐2,3‐dicarbonitrile derivatives 1–7, the 1,4‐positions of which are linked by bridges with increasing lengths, have been prepared in order to determine the influence of the bridging on the structural parameters of this system. Therefore, we have examined the molecular structure...

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Veröffentlicht in:	Chemische Berichte 1992-09, Vol.125 (9), p.2067-2073
Hauptverfasser:	Irngartinger, Hermann, Oeser, Thomas, Jahn, Reiner, Kallfaß, Dietmar
Format:	Artikel
Sprache:	eng
Schlagworte:	1,4‐bridged 2,5‐Cyclohexadienes 4-bridged 5-Cyclohexadienes Atomic and molecular physics Exact sciences and technology Interatomic distances and angles Molecular properties and interactions with photons Physics Properties of molecules and molecular ions pyramidalized sp2 Carbon atoms X-ray structure analyses of
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