Static and dynamic structures of pentacarbonyl-chromium(0) and -tungsten(0) complexes of dithioether ligands: I. Symmetrical dithioether complexes and X-ray crystal structure of [W(CO) 5( tBuSCH 2S tBu)]
The complexes [M(CO) 5(RSCH 2SR)] (M Cr, R Et, iPr, tBu; M W, R Me, Et, iPr, tBu) were synthesised. Total bandshape NMR analysis was used to measure energies of inversion of the coordinated S atom in the tungsten complexes. Δ G‡ (298.15 K) values were in the range 34–42 kJ mol −1. An X-ray s...
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| Veröffentlicht in: | Journal of organometallic chemistry 1992-08, Vol.437 (1), p.191-199 |
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| container_issue | 1 |
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| container_title | Journal of organometallic chemistry |
| container_volume | 437 |
| creator | Abel, Edward W. Orrell, Keith G. Rahoo, Haji Šik, Vladimir Mazid, Mohammed A. Hursthouse, Michael B. |
| description | The complexes [M(CO)
5(RSCH
2SR)] (M Cr, R Et,
iPr,
tBu; M W, R Me, Et,
iPr,
tBu) were synthesised. Total bandshape NMR analysis was used to measure energies of inversion of the coordinated S atom in the tungsten complexes. Δ
G‡ (298.15 K) values were in the range 34–42 kJ mol
−1. An X-ray structure of [W(CO)
5(
tBuSCH
2S
tBu)] was obtained. |
| doi_str_mv | 10.1016/0022-328X(92)83443-L |
| format | Article |
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5(RSCH
2SR)] (M Cr, R Et,
iPr,
tBu; M W, R Me, Et,
iPr,
tBu) were synthesised. Total bandshape NMR analysis was used to measure energies of inversion of the coordinated S atom in the tungsten complexes. Δ
G‡ (298.15 K) values were in the range 34–42 kJ mol
−1. An X-ray structure of [W(CO)
5(
tBuSCH
2S
tBu)] was obtained.</description><identifier>ISSN: 0022-328X</identifier><identifier>EISSN: 1872-8561</identifier><identifier>DOI: 10.1016/0022-328X(92)83443-L</identifier><identifier>CODEN: JORCAI</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Carbonyl and nitrosyl compounds, and their complexes ; Carbonyl and nitrosyl metals ; Chemistry ; Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; Inorganic chemistry and origins of life ; Inorganic compounds ; Physics ; Preparations and properties ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids</subject><ispartof>Journal of organometallic chemistry, 1992-08, Vol.437 (1), p.191-199</ispartof><rights>1992</rights><rights>1992 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/0022-328X(92)83443-L$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,781,785,3551,27926,27927,45997</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=5516461$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Abel, Edward W.</creatorcontrib><creatorcontrib>Orrell, Keith G.</creatorcontrib><creatorcontrib>Rahoo, Haji</creatorcontrib><creatorcontrib>Šik, Vladimir</creatorcontrib><creatorcontrib>Mazid, Mohammed A.</creatorcontrib><creatorcontrib>Hursthouse, Michael B.</creatorcontrib><title>Static and dynamic structures of pentacarbonyl-chromium(0) and -tungsten(0) complexes of dithioether ligands: I. Symmetrical dithioether complexes and X-ray crystal structure of [W(CO) 5( tBuSCH 2S tBu)]</title><title>Journal of organometallic chemistry</title><description>The complexes [M(CO)
5(RSCH
2SR)] (M Cr, R Et,
iPr,
tBu; M W, R Me, Et,
iPr,
tBu) were synthesised. Total bandshape NMR analysis was used to measure energies of inversion of the coordinated S atom in the tungsten complexes. Δ
G‡ (298.15 K) values were in the range 34–42 kJ mol
−1. An X-ray structure of [W(CO)
5(
tBuSCH
2S
tBu)] was obtained.</description><subject>Carbonyl and nitrosyl compounds, and their complexes</subject><subject>Carbonyl and nitrosyl metals</subject><subject>Chemistry</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>Inorganic chemistry and origins of life</subject><subject>Inorganic compounds</subject><subject>Physics</subject><subject>Preparations and properties</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><issn>0022-328X</issn><issn>1872-8561</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1992</creationdate><recordtype>article</recordtype><recordid>eNpVkc1qGzEUhUVJIE7SN8hCiy7shVxJMxprsgikQ1sHDF44oYEQhCzdiRXmx0ia0nnGvlRm4uKS1T1cvnO4l4PQFaNzRln2lVLOScLl4zTnM5mkaUJWn9CEyQUnUmTsBE2OyBk6D-GVUsoSKifo7ybq6AzWjcW2b3Q96BB9Z2LnIeC2xHtoojbab9umr4jZ-bZ2XT2ls3cPiV3zEiI048K09b6CPwefdXHnWog78LhyLwMcrvHdHG_6uobondHVB-a_ecx9JF732Pg-xIE7XjQGP_2aFusZFlMcv3WbYon5ZlSz50t0WuoqwOd_8wI9_Ph-XyzJav3zrrhdEWCCR7KAfLuVdCulBZlasygl5ExkKYe0ZCyHXDOtrRa5lkJCIkxOS2moAc4tsya5QF8OuXsdhi9Krxvjgtp7V2vfKyFYlmZswG4OGAy3_HbgVTAOGgPWeTBR2dYpRtXYoBrrUWM9KufqvUG1St4AnXSSnA</recordid><startdate>19920829</startdate><enddate>19920829</enddate><creator>Abel, Edward W.</creator><creator>Orrell, Keith G.</creator><creator>Rahoo, Haji</creator><creator>Šik, Vladimir</creator><creator>Mazid, Mohammed A.</creator><creator>Hursthouse, Michael B.</creator><general>Elsevier B.V</general><general>Elsevier Science</general><scope>IQODW</scope></search><sort><creationdate>19920829</creationdate><title>Static and dynamic structures of pentacarbonyl-chromium(0) and -tungsten(0) complexes of dithioether ligands: I. Symmetrical dithioether complexes and X-ray crystal structure of [W(CO) 5( tBuSCH 2S tBu)]</title><author>Abel, Edward W. ; Orrell, Keith G. ; Rahoo, Haji ; Šik, Vladimir ; Mazid, Mohammed A. ; Hursthouse, Michael B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-e152t-7e9bb80b88de84dc7f8e915642e4f119e9a1aada59a858e35c90f8c0ce22d1dc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1992</creationdate><topic>Carbonyl and nitrosyl compounds, and their complexes</topic><topic>Carbonyl and nitrosyl metals</topic><topic>Chemistry</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>Inorganic chemistry and origins of life</topic><topic>Inorganic compounds</topic><topic>Physics</topic><topic>Preparations and properties</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Abel, Edward W.</creatorcontrib><creatorcontrib>Orrell, Keith G.</creatorcontrib><creatorcontrib>Rahoo, Haji</creatorcontrib><creatorcontrib>Šik, Vladimir</creatorcontrib><creatorcontrib>Mazid, Mohammed A.</creatorcontrib><creatorcontrib>Hursthouse, Michael B.</creatorcontrib><collection>Pascal-Francis</collection><jtitle>Journal of organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Abel, Edward W.</au><au>Orrell, Keith G.</au><au>Rahoo, Haji</au><au>Šik, Vladimir</au><au>Mazid, Mohammed A.</au><au>Hursthouse, Michael B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Static and dynamic structures of pentacarbonyl-chromium(0) and -tungsten(0) complexes of dithioether ligands: I. Symmetrical dithioether complexes and X-ray crystal structure of [W(CO) 5( tBuSCH 2S tBu)]</atitle><jtitle>Journal of organometallic chemistry</jtitle><date>1992-08-29</date><risdate>1992</risdate><volume>437</volume><issue>1</issue><spage>191</spage><epage>199</epage><pages>191-199</pages><issn>0022-328X</issn><eissn>1872-8561</eissn><coden>JORCAI</coden><abstract>The complexes [M(CO)
5(RSCH
2SR)] (M Cr, R Et,
iPr,
tBu; M W, R Me, Et,
iPr,
tBu) were synthesised. Total bandshape NMR analysis was used to measure energies of inversion of the coordinated S atom in the tungsten complexes. Δ
G‡ (298.15 K) values were in the range 34–42 kJ mol
−1. An X-ray structure of [W(CO)
5(
tBuSCH
2S
tBu)] was obtained.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/0022-328X(92)83443-L</doi><tpages>9</tpages></addata></record> |
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| ispartof | Journal of organometallic chemistry, 1992-08, Vol.437 (1), p.191-199 |
| issn | 0022-328X 1872-8561 |
| language | eng |
| recordid | cdi_pascalfrancis_primary_5516461 |
| source | Access via ScienceDirect (Elsevier) |
| subjects | Carbonyl and nitrosyl compounds, and their complexes Carbonyl and nitrosyl metals Chemistry Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Inorganic chemistry and origins of life Inorganic compounds Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | Static and dynamic structures of pentacarbonyl-chromium(0) and -tungsten(0) complexes of dithioether ligands: I. Symmetrical dithioether complexes and X-ray crystal structure of [W(CO) 5( tBuSCH 2S tBu)] |
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