Functional polymers supported on porous silica: I. Grafting active precursors onto porous silica
A set of porous silica has been grafted with trialkoxysilane coupling agents carrying either a γ-propyl methacryloyl group, a γ-propyl thiol or a γ-propyl amine group. The grafts have been characterized by diffuse reflectance Fourier transform infrared spectroscopy and 29Si and 13C cross-polarizatio...
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| Veröffentlicht in: | Reactive polymers 1991, Vol.16 (1), p.41-49 |
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| container_end_page | 49 |
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| container_issue | 1 |
| container_start_page | 41 |
| container_title | Reactive polymers |
| container_volume | 16 |
| creator | Carlier, Eric Guyot, Alain Revillon, André Llauro-Darricades, Marie-France Petiaud, Roger |
| description | A set of porous silica has been grafted with trialkoxysilane coupling agents carrying either a γ-propyl methacryloyl group, a γ-propyl thiol or a γ-propyl amine group. The grafts have been characterized by diffuse reflectance Fourier transform infrared spectroscopy and
29Si and
13C cross-polarization magic-angle-spinning nuclear magnetic resonance; the grafting yields were estimated from elemental analysis. The grafted amine was further reacted with azobiscyanovaleric acid. The grafted materials are to be used as co-monomer, transfer agent or initiator for a further grafting of a functional polymer via a radical polymerization. |
| doi_str_mv | 10.1016/0923-1137(91)90284-U |
| format | Article |
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29Si and
13C cross-polarization magic-angle-spinning nuclear magnetic resonance; the grafting yields were estimated from elemental analysis. The grafted amine was further reacted with azobiscyanovaleric acid. The grafted materials are to be used as co-monomer, transfer agent or initiator for a further grafting of a functional polymer via a radical polymerization.</description><identifier>ISSN: 0923-1137</identifier><identifier>EISSN: 1873-1678</identifier><identifier>DOI: 10.1016/0923-1137(91)90284-U</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Applied sciences ; Exact sciences and technology ; functional polymers ; grafting characterization ; Organic polymers ; Physicochemistry of polymers ; Polymerization ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; silica coupling agents ; silica grafted polymers ; silica supports</subject><ispartof>Reactive polymers, 1991, Vol.16 (1), p.41-49</ispartof><rights>1991</rights><rights>1992 INIST-CNRS</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,4010,27900,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=4994820$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Carlier, Eric</creatorcontrib><creatorcontrib>Guyot, Alain</creatorcontrib><creatorcontrib>Revillon, André</creatorcontrib><creatorcontrib>Llauro-Darricades, Marie-France</creatorcontrib><creatorcontrib>Petiaud, Roger</creatorcontrib><title>Functional polymers supported on porous silica: I. Grafting active precursors onto porous silica</title><title>Reactive polymers</title><description>A set of porous silica has been grafted with trialkoxysilane coupling agents carrying either a γ-propyl methacryloyl group, a γ-propyl thiol or a γ-propyl amine group. The grafts have been characterized by diffuse reflectance Fourier transform infrared spectroscopy and
29Si and
13C cross-polarization magic-angle-spinning nuclear magnetic resonance; the grafting yields were estimated from elemental analysis. The grafted amine was further reacted with azobiscyanovaleric acid. The grafted materials are to be used as co-monomer, transfer agent or initiator for a further grafting of a functional polymer via a radical polymerization.</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>functional polymers</subject><subject>grafting characterization</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>silica coupling agents</subject><subject>silica grafted polymers</subject><subject>silica supports</subject><issn>0923-1137</issn><issn>1873-1678</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1991</creationdate><recordtype>article</recordtype><recordid>eNpVkE1LAzEQhoMoWKv_wMMePOhhayb7kcSDIMXWQsGLPcd8rUS2myXZLfTfN7UieBrmnfcdZh6EbgHPAEP9iDkpcoCC3nN44JiwMt-coQkwmuSasnM0-bNcoqsYvzEGmiYT9LkYOz0438k2632739oQszj2vQ-DNZnvkhr8mDTXOi2fstUsWwbZDK77ymRK7mzWB6vHEH1K-m7w_xPX6KKRbbQ3v3WKNovXj_lbvn5fruYv69xCRYZcSeAUW7AVk6yqVcFrQ6Ah0taK0BII58ZyRWtNlDEVrbBKrQJtVKEYp8UU3Z329jJq2TZBdtpF0Qe3lWEvSs5LRnCyPZ9sNt2yczaIqJ3ttDUufTEI450ALI5YxZGZODITHMQPVrEpDheybZo</recordid><startdate>1991</startdate><enddate>1991</enddate><creator>Carlier, Eric</creator><creator>Guyot, Alain</creator><creator>Revillon, André</creator><creator>Llauro-Darricades, Marie-France</creator><creator>Petiaud, Roger</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope></search><sort><creationdate>1991</creationdate><title>Functional polymers supported on porous silica: I. Grafting active precursors onto porous silica</title><author>Carlier, Eric ; Guyot, Alain ; Revillon, André ; Llauro-Darricades, Marie-France ; Petiaud, Roger</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-e152t-ba1970e1e58a856b396d21f2ae6b2741299de9b76c2bdd5750be9bb1cdb3b8973</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1991</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>functional polymers</topic><topic>grafting characterization</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>silica coupling agents</topic><topic>silica grafted polymers</topic><topic>silica supports</topic><toplevel>online_resources</toplevel><creatorcontrib>Carlier, Eric</creatorcontrib><creatorcontrib>Guyot, Alain</creatorcontrib><creatorcontrib>Revillon, André</creatorcontrib><creatorcontrib>Llauro-Darricades, Marie-France</creatorcontrib><creatorcontrib>Petiaud, Roger</creatorcontrib><collection>Pascal-Francis</collection><jtitle>Reactive polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Carlier, Eric</au><au>Guyot, Alain</au><au>Revillon, André</au><au>Llauro-Darricades, Marie-France</au><au>Petiaud, Roger</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Functional polymers supported on porous silica: I. Grafting active precursors onto porous silica</atitle><jtitle>Reactive polymers</jtitle><date>1991</date><risdate>1991</risdate><volume>16</volume><issue>1</issue><spage>41</spage><epage>49</epage><pages>41-49</pages><issn>0923-1137</issn><eissn>1873-1678</eissn><abstract>A set of porous silica has been grafted with trialkoxysilane coupling agents carrying either a γ-propyl methacryloyl group, a γ-propyl thiol or a γ-propyl amine group. The grafts have been characterized by diffuse reflectance Fourier transform infrared spectroscopy and
29Si and
13C cross-polarization magic-angle-spinning nuclear magnetic resonance; the grafting yields were estimated from elemental analysis. The grafted amine was further reacted with azobiscyanovaleric acid. The grafted materials are to be used as co-monomer, transfer agent or initiator for a further grafting of a functional polymer via a radical polymerization.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/0923-1137(91)90284-U</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
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| ispartof | Reactive polymers, 1991, Vol.16 (1), p.41-49 |
| issn | 0923-1137 1873-1678 |
| language | eng |
| recordid | cdi_pascalfrancis_primary_4994820 |
| source | Alma/SFX Local Collection |
| subjects | Applied sciences Exact sciences and technology functional polymers grafting characterization Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts silica coupling agents silica grafted polymers silica supports |
| title | Functional polymers supported on porous silica: I. Grafting active precursors onto porous silica |
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