OsO3F2 and OsO2F4, Preparation and Crystal Structures

The new method for preparing OsO3F2 is presented. Its crystal structure reveals a polymeric chain structure with distorted octahedral geometry for the OsO3F3 units and symmetrical, non‐linear fluorine bridges. The OsO3F3 unit has a facial geometry. This structure is not in accord with predictions on...

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Veröffentlicht in:	Chemische Berichte 1993-06, Vol.126 (6), p.1331-1336
Hauptverfasser:	Bougon, Roland, Buu, Ban, Seppelt, Konard
Format:	Artikel
Sprache:	eng
Schlagworte:	Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Halides, chalcogenides and analogous compounds of group vb Inorganic compounds Osmium difluoride trioxide Osmium difluoride trioxide, preparation, structure Osmium tetrafluoride dioxide Osmium tetrafluoride dioxide, preparation, structure Physics preparation structure Structure of solids and liquids crystallography Structure of specific crystalline solids
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