SYNTHESIS OF (R)- AND (S)-1,2-DIACYLOXYPROPYL-3-ARSONIC ACIDS: OPTICALLY ACTIVE ARSONOLIPIDS

Reaction of trisodium arsenite with (R)- and (S)-glycidol affords in good yields the (R)- and (S)-1,2-dihydroxypropyl-3-arsonic acid, the tetrabutylammonium salt of which upon acylation with myristic, palmitic and stearic anhydrides in the presence of pyridine gives, in moderate to low yields, optic...

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Veröffentlicht in:	Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1992-10, Vol.71 (1-4), p.99-105
Hauptverfasser:	Serves, Spyros V., Tsivgoulis, Gerasimos M., Sotiropoulos, Demetrios N., Ioannou, Panayiotis V., Jain, Mahendra K.
Format:	Artikel
Sprache:	eng
Schlagworte:	acylation Chemistry conglomerates decomposition Exact sciences and technology Lipids Optically active arsonic acids optically active arsonolipids Organic chemistry Preparations and properties thermotropic phase transitions
Online-Zugang:	Volltext
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