Unusual rearrangement of triangulane gem-dibromides in the presence of methyllithium

Triangulane gem-dibromides in the presence of methyllithium undergo rearrangement of dibromospiropentyl fragment into 1-bromomethyl-2-bromocyclobutenyl one. Triangulane gem-dibromides in the presence of methyllithium undergo rearrangement of dibromospiropentyl fragment into 1-bromomethyl-2- bromocyc...

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Veröffentlicht in:	Tetrahedron 1992, Vol.48 (45), p.9977-9984
Hauptverfasser:	Lukin, Kirill A., Zefirov, Nikolai S., Yufit, Dmitri S., Struchkov, Yuri T.
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Aliphatic, non-condensed and condensed benzenic, and alicyclic compounds Chemistry Chemistry, Organic Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Organic chemistry Organic compounds Physical Sciences Physics Preparations and properties Science & Technology Structure of solids and liquids crystallography Structure of specific crystalline solids
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Beschreibung
Zusammenfassung:	Triangulane gem-dibromides in the presence of methyllithium undergo rearrangement of dibromospiropentyl fragment into 1-bromomethyl-2-bromocyclobutenyl one. Triangulane gem-dibromides in the presence of methyllithium undergo rearrangement of dibromospiropentyl fragment into 1-bromomethyl-2- bromocyclobutenyl one.
ISSN:	0040-4020 1464-5416
DOI:	10.1016/S0040-4020(01)92287-2