Living cationic polymerization of styrene by the bifunctional initiating system 1,4-bis(1-chloroethyl)benzene/SnCl4 in the presence of 2,6-di-tert-butylpyridine

The polymerization of styrene was studied by using a bifunctional initiator, 1,4‐bis(1‐chloroethyl)benzene (1). It was demonstrated that living polymerization can be achieved in the styrene/1/SnCl4 system in chloroform at −15°C in the presence of 2,6‐di‐tert‐butylpyridine. The number‐average molecul...

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Veröffentlicht in:	Macromolecular chemistry and physics 1994-06, Vol.195 (6), p.2187-2194
Hauptverfasser:	Kwon, Oh-Sig, Gho, Chang Gi, Choi, Byong-Seok, Choi, Sam-Kwon
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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