[P4(CpAl)6]: A Compound with an Unusual P4Al6 Cage Structure
Two face‐sharing Al4P4 cubes, which lack two P atoms at the corners—this is the (idealized) framework of the title compound in the crystal. According to calculations, the isomer with adamantane structure is less stable by 30 to 80 kJ mol−1. As a result of quantum mechanical calculations on the model...
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| Veröffentlicht in: | Angewandte Chemie (International ed.) 1994-02, Vol.33 (2), p.199-200 |
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| container_issue | 2 |
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| container_title | Angewandte Chemie (International ed.) |
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| creator | Dohmeier, Carsten Schnöckel, Hansgeorg Robl, Christian Schneider, Uwe Ahlrichs, Reinhart |
| description | Two face‐sharing Al4P4 cubes, which lack two P atoms at the corners—this is the (idealized) framework of the title compound in the crystal. According to calculations, the isomer with adamantane structure is less stable by 30 to 80 kJ mol−1. As a result of quantum mechanical calculations on the model [P4(CpAl)6], [P4(Cp*Al)6] can be characterized as an electron‐deficient compound that is stabilized by considerable ionic bonding contributions. |
| doi_str_mv | 10.1002/anie.199401991 |
| format | Article |
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According to calculations, the isomer with adamantane structure is less stable by 30 to 80 kJ mol−1. 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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Al, ga, in, tl, zn, cd, hg derivatives Chemistry Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Organic chemistry Organic compounds Organometalloidal and organometallic compounds Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | [P4(CpAl)6]: A Compound with an Unusual P4Al6 Cage Structure |
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