Thermal coupling of methane: A comparison between kinetic model data and experimental data
Thermal coupling of methane was investigated in a tubular flow reactor in the temperature range 1200–1500°C at atmospheric pressure. The main products observed were ethane, ethene, ethyne, benzene and “coke”. A mechanistic simulation model was developed for this process. The kinetic scheme consists...
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| Veröffentlicht in: | Thermochimica acta 1994-01, Vol.232 (1), p.155-169 |
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| container_title | Thermochimica acta |
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| creator | Olsvik, Ola Billaud, Francis |
| description | Thermal coupling of methane was investigated in a tubular flow reactor in the temperature range 1200–1500°C at atmospheric pressure.
The main products observed were ethane, ethene, ethyne, benzene and “coke”. A mechanistic simulation model was developed for this process. The kinetic scheme consists of 32 reversible free radical reactions and one irreversible free radical reaction. The model data provide good agreement with experimental data for the conditions being studied.
A sensitivity analysis was used to find the main free radical reactions in the formation and consumption of the reported products. |
| doi_str_mv | 10.1016/0040-6031(94)80055-3 |
| format | Article |
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The main products observed were ethane, ethene, ethyne, benzene and “coke”. A mechanistic simulation model was developed for this process. The kinetic scheme consists of 32 reversible free radical reactions and one irreversible free radical reaction. The model data provide good agreement with experimental data for the conditions being studied.
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The main products observed were ethane, ethene, ethyne, benzene and “coke”. A mechanistic simulation model was developed for this process. The kinetic scheme consists of 32 reversible free radical reactions and one irreversible free radical reaction. The model data provide good agreement with experimental data for the conditions being studied.
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The main products observed were ethane, ethene, ethyne, benzene and “coke”. A mechanistic simulation model was developed for this process. The kinetic scheme consists of 32 reversible free radical reactions and one irreversible free radical reaction. The model data provide good agreement with experimental data for the conditions being studied.
A sensitivity analysis was used to find the main free radical reactions in the formation and consumption of the reported products.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/0040-6031(94)80055-3</doi><tpages>15</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0040-6031 |
| ispartof | Thermochimica acta, 1994-01, Vol.232 (1), p.155-169 |
| issn | 0040-6031 1872-762X |
| language | eng |
| recordid | cdi_pascalfrancis_primary_4038806 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Chemical thermodynamics Chemistry Elements, mineral and organic compounds Exact sciences and technology General and physical chemistry Thermodynamic properties |
| title | Thermal coupling of methane: A comparison between kinetic model data and experimental data |
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