Organometallic Phosphinimines as Building Blocks for Potential New Radiopharmaceuticals. Synthesis, Structure and Reactivity of Ph3P=NH2+ReO4
Reactions of the organometallic phosphinimine Ph P=N-SiMe (1), with aqueous ReO and ReO yield the ion pairs Ph P=NH MO (M=Re (2); Re (4)). The ion pairs undergo dehydration upon heating to produce the neutral Re(VII) species: Ph P=N-MO (M=Re (3); Re (5)). The solid state structure of Ph P=NH ReO (2)...
Gespeichert in:
| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1993-10, Vol.48 (10), p.1381-1385 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1385 |
|---|---|
| container_issue | 10 |
| container_start_page | 1381 |
| container_title | Zeitschrift für Naturforschung. B, A journal of chemical sciences |
| container_volume | 48 |
| creator | Katti, Kattesh V. Singh, Prahlad R. Barnes, Charles L. Katti, Kavita K. Kopicka, Karel Ketring, Alan R. Volkert, Wynn A. |
| description | Reactions of the organometallic phosphinimine Ph
P=N-SiMe
(1), with aqueous ReO
and
ReO
yield the ion pairs Ph
P=NH
MO
(M=Re (2);
Re (4)). The ion pairs undergo dehydration upon heating to produce the neutral Re(VII) species: Ph
P=N-MO
(M=Re (3);
Re (5)). The solid state structure of Ph
P=NH
ReO
(2) shows the presence of hydrogen bonding between the iminato hydrogen and the rhenium oxo center. The relevance of such reactions for the design of new radiopharmaceuticals is discussed |
| doi_str_mv | 10.1515/znb-1993-1012 |
| format | Article |
| fullrecord | <record><control><sourceid>walterdegruyter_pasca</sourceid><recordid>TN_cdi_pascalfrancis_primary_3849907</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1515_znb_1993_101248101381</sourcerecordid><originalsourceid>FETCH-LOGICAL-p207t-c5f1356a13cba97d5815ecb2c7da233f90b6f372787d198e40cd5662f5e169583</originalsourceid><addsrcrecordid>eNotkEtPwzAQhC0EEuVx5O4DNwh44ziODxyg4iVVbVXgHG0dpzWkTmQ7oPIf-M-kgsvsHGZ3Rx8hZ8CuQIC4_nbLBJTiCTBI98gIilwkEkDukxFTPE2YlPkhOQrhnTFQWcZG5GfmV-jajYnYNFbT-boN3do6u7HOBIqB3vW2qaxb0bum1R-B1q2n8zYaFy02dGq-6AIr23Zr9BvUpo9WYxOu6MvWxbUJNlzSl-h7HXtvKLqKLgzqaD9t3NK2Hh7y-c30Kb1YmFl2Qg7qYdmc_s9j8vZw_zp-Siazx-fx7STpUiZjokUNXOQIXC9RyUoUIIxeplpWmHJeK7bMay5TWcgKVGEypiuR52ktDORKFPyYnP_d7TAMbWuPTttQdt5u0G9LXmRKMTnEbv5iX9hE4yuz8v12MOV723s3FCyBlTv05YC-3KEvd-izYlBeAP8FrAV7Yw</addsrcrecordid><sourcetype>Index Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Organometallic Phosphinimines as Building Blocks for Potential New Radiopharmaceuticals. Synthesis, Structure and Reactivity of Ph3P=NH2+ReO4</title><source>Alma/SFX Local Collection</source><creator>Katti, Kattesh V. ; Singh, Prahlad R. ; Barnes, Charles L. ; Katti, Kavita K. ; Kopicka, Karel ; Ketring, Alan R. ; Volkert, Wynn A.</creator><creatorcontrib>Katti, Kattesh V. ; Singh, Prahlad R. ; Barnes, Charles L. ; Katti, Kavita K. ; Kopicka, Karel ; Ketring, Alan R. ; Volkert, Wynn A.</creatorcontrib><description>Reactions of the organometallic phosphinimine Ph
P=N-SiMe
(1), with aqueous ReO
and
ReO
yield the ion pairs Ph
P=NH
MO
(M=Re (2);
Re (4)). The ion pairs undergo dehydration upon heating to produce the neutral Re(VII) species: Ph
P=N-MO
(M=Re (3);
Re (5)). The solid state structure of Ph
P=NH
ReO
(2) shows the presence of hydrogen bonding between the iminato hydrogen and the rhenium oxo center. The relevance of such reactions for the design of new radiopharmaceuticals is discussed</description><identifier>ISSN: 0932-0776</identifier><identifier>EISSN: 1865-7117</identifier><identifier>DOI: 10.1515/znb-1993-1012</identifier><identifier>CODEN: ZNBSEN</identifier><language>eng</language><publisher>Tübingen: Verlag der Zeitschrift für Naturforschung</publisher><subject>Chemistry ; Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; Organic chemistry ; Organic compounds ; Organometalloidal and organometallic compounds ; P derivatives ; Physics ; Preparations and properties ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids</subject><ispartof>Zeitschrift für Naturforschung. B, A journal of chemical sciences, 1993-10, Vol.48 (10), p.1381-1385</ispartof><rights>1994 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=3849907$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Katti, Kattesh V.</creatorcontrib><creatorcontrib>Singh, Prahlad R.</creatorcontrib><creatorcontrib>Barnes, Charles L.</creatorcontrib><creatorcontrib>Katti, Kavita K.</creatorcontrib><creatorcontrib>Kopicka, Karel</creatorcontrib><creatorcontrib>Ketring, Alan R.</creatorcontrib><creatorcontrib>Volkert, Wynn A.</creatorcontrib><title>Organometallic Phosphinimines as Building Blocks for Potential New Radiopharmaceuticals. Synthesis, Structure and Reactivity of Ph3P=NH2+ReO4</title><title>Zeitschrift für Naturforschung. B, A journal of chemical sciences</title><description>Reactions of the organometallic phosphinimine Ph
P=N-SiMe
(1), with aqueous ReO
and
ReO
yield the ion pairs Ph
P=NH
MO
(M=Re (2);
Re (4)). The ion pairs undergo dehydration upon heating to produce the neutral Re(VII) species: Ph
P=N-MO
(M=Re (3);
Re (5)). The solid state structure of Ph
P=NH
ReO
(2) shows the presence of hydrogen bonding between the iminato hydrogen and the rhenium oxo center. The relevance of such reactions for the design of new radiopharmaceuticals is discussed</description><subject>Chemistry</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>Organic chemistry</subject><subject>Organic compounds</subject><subject>Organometalloidal and organometallic compounds</subject><subject>P derivatives</subject><subject>Physics</subject><subject>Preparations and properties</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><issn>0932-0776</issn><issn>1865-7117</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNotkEtPwzAQhC0EEuVx5O4DNwh44ziODxyg4iVVbVXgHG0dpzWkTmQ7oPIf-M-kgsvsHGZ3Rx8hZ8CuQIC4_nbLBJTiCTBI98gIilwkEkDukxFTPE2YlPkhOQrhnTFQWcZG5GfmV-jajYnYNFbT-boN3do6u7HOBIqB3vW2qaxb0bum1R-B1q2n8zYaFy02dGq-6AIr23Zr9BvUpo9WYxOu6MvWxbUJNlzSl-h7HXtvKLqKLgzqaD9t3NK2Hh7y-c30Kb1YmFl2Qg7qYdmc_s9j8vZw_zp-Siazx-fx7STpUiZjokUNXOQIXC9RyUoUIIxeplpWmHJeK7bMay5TWcgKVGEypiuR52ktDORKFPyYnP_d7TAMbWuPTttQdt5u0G9LXmRKMTnEbv5iX9hE4yuz8v12MOV723s3FCyBlTv05YC-3KEvd-izYlBeAP8FrAV7Yw</recordid><startdate>19931001</startdate><enddate>19931001</enddate><creator>Katti, Kattesh V.</creator><creator>Singh, Prahlad R.</creator><creator>Barnes, Charles L.</creator><creator>Katti, Kavita K.</creator><creator>Kopicka, Karel</creator><creator>Ketring, Alan R.</creator><creator>Volkert, Wynn A.</creator><general>Verlag der Zeitschrift für Naturforschung</general><scope>IQODW</scope></search><sort><creationdate>19931001</creationdate><title>Organometallic Phosphinimines as Building Blocks for Potential New Radiopharmaceuticals. Synthesis, Structure and Reactivity of Ph3P=NH2+ReO4</title><author>Katti, Kattesh V. ; Singh, Prahlad R. ; Barnes, Charles L. ; Katti, Kavita K. ; Kopicka, Karel ; Ketring, Alan R. ; Volkert, Wynn A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p207t-c5f1356a13cba97d5815ecb2c7da233f90b6f372787d198e40cd5662f5e169583</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>Chemistry</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>Organic chemistry</topic><topic>Organic compounds</topic><topic>Organometalloidal and organometallic compounds</topic><topic>P derivatives</topic><topic>Physics</topic><topic>Preparations and properties</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Katti, Kattesh V.</creatorcontrib><creatorcontrib>Singh, Prahlad R.</creatorcontrib><creatorcontrib>Barnes, Charles L.</creatorcontrib><creatorcontrib>Katti, Kavita K.</creatorcontrib><creatorcontrib>Kopicka, Karel</creatorcontrib><creatorcontrib>Ketring, Alan R.</creatorcontrib><creatorcontrib>Volkert, Wynn A.</creatorcontrib><collection>Pascal-Francis</collection><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Katti, Kattesh V.</au><au>Singh, Prahlad R.</au><au>Barnes, Charles L.</au><au>Katti, Kavita K.</au><au>Kopicka, Karel</au><au>Ketring, Alan R.</au><au>Volkert, Wynn A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Organometallic Phosphinimines as Building Blocks for Potential New Radiopharmaceuticals. Synthesis, Structure and Reactivity of Ph3P=NH2+ReO4</atitle><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle><date>1993-10-01</date><risdate>1993</risdate><volume>48</volume><issue>10</issue><spage>1381</spage><epage>1385</epage><pages>1381-1385</pages><issn>0932-0776</issn><eissn>1865-7117</eissn><coden>ZNBSEN</coden><abstract>Reactions of the organometallic phosphinimine Ph
P=N-SiMe
(1), with aqueous ReO
and
ReO
yield the ion pairs Ph
P=NH
MO
(M=Re (2);
Re (4)). The ion pairs undergo dehydration upon heating to produce the neutral Re(VII) species: Ph
P=N-MO
(M=Re (3);
Re (5)). The solid state structure of Ph
P=NH
ReO
(2) shows the presence of hydrogen bonding between the iminato hydrogen and the rhenium oxo center. The relevance of such reactions for the design of new radiopharmaceuticals is discussed</abstract><cop>Tübingen</cop><pub>Verlag der Zeitschrift für Naturforschung</pub><doi>10.1515/znb-1993-1012</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0932-0776 |
| ispartof | Zeitschrift für Naturforschung. B, A journal of chemical sciences, 1993-10, Vol.48 (10), p.1381-1385 |
| issn | 0932-0776 1865-7117 |
| language | eng |
| recordid | cdi_pascalfrancis_primary_3849907 |
| source | Alma/SFX Local Collection |
| subjects | Chemistry Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Organic chemistry Organic compounds Organometalloidal and organometallic compounds P derivatives Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | Organometallic Phosphinimines as Building Blocks for Potential New Radiopharmaceuticals. Synthesis, Structure and Reactivity of Ph3P=NH2+ReO4 |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-23T13%3A36%3A32IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-walterdegruyter_pasca&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Organometallic%20Phosphinimines%20as%20Building%20Blocks%20for%20Potential%20New%20Radiopharmaceuticals.%20Synthesis,%20Structure%20and%20Reactivity%20of%20Ph3P=NH2+ReO4&rft.jtitle=Zeitschrift%20f%C3%BCr%20Naturforschung.%20B,%20A%20journal%20of%20chemical%20sciences&rft.au=Katti,%20Kattesh%20V.&rft.date=1993-10-01&rft.volume=48&rft.issue=10&rft.spage=1381&rft.epage=1385&rft.pages=1381-1385&rft.issn=0932-0776&rft.eissn=1865-7117&rft.coden=ZNBSEN&rft_id=info:doi/10.1515/znb-1993-1012&rft_dat=%3Cwalterdegruyter_pasca%3E10_1515_znb_1993_101248101381%3C/walterdegruyter_pasca%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |