Double-electron transfer from Xe to Xe4+ at low energies as observed in the trap of a fourier-transform ion cyclotron resonance mass spectrometer
Multiply charged Xen+ ions with n⩽5 were generated by electron impact on xenon gas in the external ion source of a Fourier‐transform ion cyclotron resonance (FT‐ICR) mass spectrometer. These ions were transferred to and trapped in the low pressure FT‐ICR cell. Subsequently, xenon ions with a particu...
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Veröffentlicht in: | Rapid communications in mass spectrometry 1993-08, Vol.7 (8), p.780-783 |
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creator | von Köding, Holger Pinkse, Frans A. Nibbering, Nico M. M. |
description | Multiply charged Xen+ ions with n⩽5 were generated by electron impact on xenon gas in the external ion source of a Fourier‐transform ion cyclotron resonance (FT‐ICR) mass spectrometer. These ions were transferred to and trapped in the low pressure FT‐ICR cell. Subsequently, xenon ions with a particular mass and charge state were selected by ejection of all other unwanted ions from the FT‐ICR cell and allowed to react with neutral xenon atoms. It was found that, in the interactions between Xe4+ ions and neutral xenon atoms, not only does a single electron transfer take place, but also a double electron transfer. |
doi_str_mv | 10.1002/rcm.1290070819 |
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M.</creator><creatorcontrib>von Köding, Holger ; Pinkse, Frans A. ; Nibbering, Nico M. M.</creatorcontrib><description>Multiply charged Xen+ ions with n⩽5 were generated by electron impact on xenon gas in the external ion source of a Fourier‐transform ion cyclotron resonance (FT‐ICR) mass spectrometer. These ions were transferred to and trapped in the low pressure FT‐ICR cell. Subsequently, xenon ions with a particular mass and charge state were selected by ejection of all other unwanted ions from the FT‐ICR cell and allowed to react with neutral xenon atoms. It was found that, in the interactions between Xe4+ ions and neutral xenon atoms, not only does a single electron transfer take place, but also a double electron transfer.</description><identifier>ISSN: 0951-4198</identifier><identifier>EISSN: 1097-0231</identifier><identifier>DOI: 10.1002/rcm.1290070819</identifier><language>eng</language><publisher>London: Heyden & Son Limited</publisher><subject>Chemistry ; Exact sciences and technology ; Inorganic chemistry and origins of life ; Kinetics and mechanism of reactions</subject><ispartof>Rapid communications in mass spectrometry, 1993-08, Vol.7 (8), p.780-783</ispartof><rights>Copyright © 1993 John Wiley & Sons, Ltd.</rights><rights>1994 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Frcm.1290070819$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Frcm.1290070819$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,777,781,1412,27905,27906,45555,45556</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=3748628$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>von Köding, Holger</creatorcontrib><creatorcontrib>Pinkse, Frans A.</creatorcontrib><creatorcontrib>Nibbering, Nico M. M.</creatorcontrib><title>Double-electron transfer from Xe to Xe4+ at low energies as observed in the trap of a fourier-transform ion cyclotron resonance mass spectrometer</title><title>Rapid communications in mass spectrometry</title><addtitle>Rapid Commun. Mass Spectrom</addtitle><description>Multiply charged Xen+ ions with n⩽5 were generated by electron impact on xenon gas in the external ion source of a Fourier‐transform ion cyclotron resonance (FT‐ICR) mass spectrometer. These ions were transferred to and trapped in the low pressure FT‐ICR cell. Subsequently, xenon ions with a particular mass and charge state were selected by ejection of all other unwanted ions from the FT‐ICR cell and allowed to react with neutral xenon atoms. It was found that, in the interactions between Xe4+ ions and neutral xenon atoms, not only does a single electron transfer take place, but also a double electron transfer.</description><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Inorganic chemistry and origins of life</subject><subject>Kinetics and mechanism of reactions</subject><issn>0951-4198</issn><issn>1097-0231</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1993</creationdate><recordtype>article</recordtype><recordid>eNpFkEFP3DAQhS3USmyhV84-9FYFZuIkto9021IWClXVCsTFcpxxcZvEKzuU7s_oP25gK7jMaDTzvTd6jB0gHCJAeZTccIilBpCgUO-wBYKWBZQCX7AF6BqLCrXaZa9y_gmAWJewYH_fx7u2p4J6clOKI5-SHbOnxH2KA78mPsW5Vm-5nXgf7zmNlH4EytxmHttM6Td1PMzcLT2wax49t9zHuxQoFVu1mAYeZm23cX18dEmU42hHR3ywOfO8fnQfaKK0z15622d6_b_vse8fP3xbfirOL09Ol8fnRUCUukAJvsSm1h68blslReWg7XSlO42ybrSrtKCmVqKWXSeEapBUJ6wrheqs7sQee7PVXdvsbO_nT13IZp3CYNPGCFmpplTzmd6e3YeeNk9rBPMQuplDN8-hm6_Lz8_TzBZbNuSJ_jyxNv0yjRSyNlcXJ6Y-W32B1buVuRH_ALG-iRk</recordid><startdate>199308</startdate><enddate>199308</enddate><creator>von Köding, Holger</creator><creator>Pinkse, Frans A.</creator><creator>Nibbering, Nico M. M.</creator><general>Heyden & Son Limited</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope></search><sort><creationdate>199308</creationdate><title>Double-electron transfer from Xe to Xe4+ at low energies as observed in the trap of a fourier-transform ion cyclotron resonance mass spectrometer</title><author>von Köding, Holger ; Pinkse, Frans A. ; Nibbering, Nico M. M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i1179-170f21659f0f9bb8734c0bd949d917569c493e658357dd33861e8d3ac238da9d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Inorganic chemistry and origins of life</topic><topic>Kinetics and mechanism of reactions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>von Köding, Holger</creatorcontrib><creatorcontrib>Pinkse, Frans A.</creatorcontrib><creatorcontrib>Nibbering, Nico M. M.</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><jtitle>Rapid communications in mass spectrometry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>von Köding, Holger</au><au>Pinkse, Frans A.</au><au>Nibbering, Nico M. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Double-electron transfer from Xe to Xe4+ at low energies as observed in the trap of a fourier-transform ion cyclotron resonance mass spectrometer</atitle><jtitle>Rapid communications in mass spectrometry</jtitle><addtitle>Rapid Commun. Mass Spectrom</addtitle><date>1993-08</date><risdate>1993</risdate><volume>7</volume><issue>8</issue><spage>780</spage><epage>783</epage><pages>780-783</pages><issn>0951-4198</issn><eissn>1097-0231</eissn><abstract>Multiply charged Xen+ ions with n⩽5 were generated by electron impact on xenon gas in the external ion source of a Fourier‐transform ion cyclotron resonance (FT‐ICR) mass spectrometer. These ions were transferred to and trapped in the low pressure FT‐ICR cell. Subsequently, xenon ions with a particular mass and charge state were selected by ejection of all other unwanted ions from the FT‐ICR cell and allowed to react with neutral xenon atoms. It was found that, in the interactions between Xe4+ ions and neutral xenon atoms, not only does a single electron transfer take place, but also a double electron transfer.</abstract><cop>London</cop><pub>Heyden & Son Limited</pub><doi>10.1002/rcm.1290070819</doi><tpages>4</tpages></addata></record> |
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source | Wiley Online Library Journals Frontfile Complete |
subjects | Chemistry Exact sciences and technology Inorganic chemistry and origins of life Kinetics and mechanism of reactions |
title | Double-electron transfer from Xe to Xe4+ at low energies as observed in the trap of a fourier-transform ion cyclotron resonance mass spectrometer |
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