NEW SURFACES AND TECHNIQUES FOR STUDIES OF INTERPARTICLE FORCES

Several methods of preparing surfaces suitable for interparticle surface forces measurements are presented. Treatment of muscovite mica surfaces with a water vapour plasma introduces surface hydroxyl groups. These groups can react with chlorosilanes to form organo functionalized surfaces. The forces...

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Veröffentlicht in:Journal of dispersion science and technology 1994-01, Vol.15 (3), p.375-397
Hauptverfasser: Claesson, P. M., Parkert, J.L., Fröberg, J.C.
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container_title Journal of dispersion science and technology
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creator Claesson, P. M.
Parkert, J.L.
Fröberg, J.C.
description Several methods of preparing surfaces suitable for interparticle surface forces measurements are presented. Treatment of muscovite mica surfaces with a water vapour plasma introduces surface hydroxyl groups. These groups can react with chlorosilanes to form organo functionalized surfaces. The forces between water vapour plasma treated mica surfaces in aqueous solutions are well described by DLVO theory except for the presence of a short-range (D < 10 Å) additional repulsion. After reaction with a fluorocarbon containing silane the surfaces become hydrophobic and a long-range attraction acts between the surfaces in water. Smooth glass spheres can be obtained by melting a glass rod in a gas burner. These surfaces are ideal substrates for a new type of surface force apparatus that uses a bimorph force sensor for measuring surface forces. The chemistry of the glass surfaces is readily modified
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1532-2351
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source Taylor & Francis Journals Complete
subjects Chemistry
Colloidal state and disperse state
Exact sciences and technology
General and physical chemistry
Physical and chemical studies. Granulometry. Electrokinetic phenomena
title NEW SURFACES AND TECHNIQUES FOR STUDIES OF INTERPARTICLE FORCES
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