Crosslinking of cis-1,4-polyisoprene rubber by electron beam irradiation
Various unsaturated polyfunctional monomers were kneaded into cis‐1,4‐polyisoprene containing fillers under 80°C and then irradiated using an electron beam accelerator to prepare vulcanized rubber with good quality. Results showed that 2G (diethyleneglycol dimethacrylate) is the best sensitizer. The...
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Veröffentlicht in: | Journal of applied polymer science 1997-10, Vol.66 (1), p.113-116 |
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creator | Xu, Yunshu Siswono, Heri Yoshii, Fumio Makuuchi, Keizo |
description | Various unsaturated polyfunctional monomers were kneaded into cis‐1,4‐polyisoprene containing fillers under 80°C and then irradiated using an electron beam accelerator to prepare vulcanized rubber with good quality. Results showed that 2G (diethyleneglycol dimethacrylate) is the best sensitizer. The optimal tensile strength of vulcanized IR was obtained by using 14 phr 2G and irradiated to 180 kGy. Compared with the sulfur vulcanizate, greater values of tensile strength, elongation at break, and 100% stress were found with the radiation‐cured IR. Their Young's modulus and tan σ were similar. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 66: 113–116, 1997 |
doi_str_mv | 10.1002/(SICI)1097-4628(19971003)66:1<113::AID-APP13>3.0.CO;2-2 |
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Appl. Polym. Sci</addtitle><description>Various unsaturated polyfunctional monomers were kneaded into cis‐1,4‐polyisoprene containing fillers under 80°C and then irradiated using an electron beam accelerator to prepare vulcanized rubber with good quality. Results showed that 2G (diethyleneglycol dimethacrylate) is the best sensitizer. The optimal tensile strength of vulcanized IR was obtained by using 14 phr 2G and irradiated to 180 kGy. Compared with the sulfur vulcanizate, greater values of tensile strength, elongation at break, and 100% stress were found with the radiation‐cured IR. Their Young's modulus and tan σ were similar. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 66: 113–116, 1997</description><subject>4-polyisoprene</subject><subject>Applied sciences</subject><subject>cis-1</subject><subject>cis‐1,4‐polyisoprene</subject><subject>Crosslinking and degradation</subject><subject>electron beam</subject><subject>Exact sciences and technology</subject><subject>physical properties</subject><subject>Physicochemistry of polymers</subject><subject>polyfunctional monomer</subject><subject>Polymers and radiations</subject><subject>radiation crosslinking</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><recordid>eNo90F1L6zAYwPEgR3Bn-h164YWCmXlrmkxRRtU5FSfo4Xj3kKapRLt2JBPdt7dzOnIRyJP8CT-EzikZUELY8cHjJJ8cUqIzLCRTB1TrrBvwQymH9JRSPhyOJhd49PBA-RkfkEE-PWGYbaHe5s0f1OtKFCut0x30N8ZXQihNieyh6zy0Mda-efPNS9JWifUR0yOB52299LGdB9e4JLwXhQtJsUxc7ewitE1SODNLfAim9Gbh22YXbVemjm7vZ--jf1eXT_k1vpuOJ_noDr9wrjhmpXQkE45ZS5jh3ClXVaoQJdG8NLKyzhhWpUKVqbWKCC1LYVPGnJKCFCLlfbS_7s5NtKaugmm6L8M8-JkJS2CZ0qTT6aPn9bUPX7vlZkwJrFBhZQorH1j5wK8pSAkUOlPoSOGbFDgQyKfAuvV90KXxOu3jwn1u0ia8gcx4lsL_-zHc3Cg91voWKP8C5cOANg</recordid><startdate>19971003</startdate><enddate>19971003</enddate><creator>Xu, Yunshu</creator><creator>Siswono, Heri</creator><creator>Yoshii, Fumio</creator><creator>Makuuchi, Keizo</creator><general>John Wiley & Sons, Inc</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope></search><sort><creationdate>19971003</creationdate><title>Crosslinking of cis-1,4-polyisoprene rubber by electron beam irradiation</title><author>Xu, Yunshu ; Siswono, Heri ; Yoshii, Fumio ; Makuuchi, Keizo</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-g3383-2d6e074e2cc02a33e8eff8b4d093da6fceaa2f548d5cc80496d4c522e8640b453</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><topic>4-polyisoprene</topic><topic>Applied sciences</topic><topic>cis-1</topic><topic>cis‐1,4‐polyisoprene</topic><topic>Crosslinking and degradation</topic><topic>electron beam</topic><topic>Exact sciences and technology</topic><topic>physical properties</topic><topic>Physicochemistry of polymers</topic><topic>polyfunctional monomer</topic><topic>Polymers and radiations</topic><topic>radiation crosslinking</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xu, Yunshu</creatorcontrib><creatorcontrib>Siswono, Heri</creatorcontrib><creatorcontrib>Yoshii, Fumio</creatorcontrib><creatorcontrib>Makuuchi, Keizo</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xu, Yunshu</au><au>Siswono, Heri</au><au>Yoshii, Fumio</au><au>Makuuchi, Keizo</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crosslinking of cis-1,4-polyisoprene rubber by electron beam irradiation</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>1997-10-03</date><risdate>1997</risdate><volume>66</volume><issue>1</issue><spage>113</spage><epage>116</epage><pages>113-116</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>Various unsaturated polyfunctional monomers were kneaded into cis‐1,4‐polyisoprene containing fillers under 80°C and then irradiated using an electron beam accelerator to prepare vulcanized rubber with good quality. Results showed that 2G (diethyleneglycol dimethacrylate) is the best sensitizer. The optimal tensile strength of vulcanized IR was obtained by using 14 phr 2G and irradiated to 180 kGy. Compared with the sulfur vulcanizate, greater values of tensile strength, elongation at break, and 100% stress were found with the radiation‐cured IR. Their Young's modulus and tan σ were similar. © 1997 John Wiley & Sons, Inc. J Appl Polym Sci 66: 113–116, 1997</abstract><cop>New York</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/(SICI)1097-4628(19971003)66:1<113::AID-APP13>3.0.CO;2-2</doi><tpages>4</tpages></addata></record> |
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source | Wiley Online Library Journals Frontfile Complete |
subjects | 4-polyisoprene Applied sciences cis-1 cis‐1,4‐polyisoprene Crosslinking and degradation electron beam Exact sciences and technology physical properties Physicochemistry of polymers polyfunctional monomer Polymers and radiations radiation crosslinking |
title | Crosslinking of cis-1,4-polyisoprene rubber by electron beam irradiation |
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