Excitation of the six lowest electronic transitions in water by 9-20 eV electrons

We report differential and integral cross sections for excitation of the 3B1, 1B1, 3A2, 1A2, 3A1 and 1A1 states of H2O by 9-20 eV electrons. The measurements are taken by conventional differential electron energy loss spectroscopy techniques, while the calculations employ the Schwinger multichannel...

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Veröffentlicht in:Journal of physics. B, Atomic, molecular, and optical physics Atomic, molecular, and optical physics, 2013-06, Vol.46 (12), p.125201-1-16
Hauptverfasser: Ralphs, K, Serna, G, Hargreaves, L R, Khakoo, M A, Winstead, C, McKoy, V
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container_issue 12
container_start_page 125201
container_title Journal of physics. B, Atomic, molecular, and optical physics
container_volume 46
creator Ralphs, K
Serna, G
Hargreaves, L R
Khakoo, M A
Winstead, C
McKoy, V
description We report differential and integral cross sections for excitation of the 3B1, 1B1, 3A2, 1A2, 3A1 and 1A1 states of H2O by 9-20 eV electrons. The measurements are taken by conventional differential electron energy loss spectroscopy techniques, while the calculations employ the Schwinger multichannel method within a ten-channel approximation. The new data are compared with previous experimental and theoretical results. The present measurements and calculations agree reasonably well both with each other and with prior theoretical efforts but show discrepancies with prior measurements. Reasons for those discrepancies are considered and discussed.
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subjects Approximation
Atomic and molecular collision processes and interactions
Atomic and molecular physics
Cross sections (physics)
Electron energy loss spectroscopy
Electron scattering
electronic excitation
Electronics
Exact sciences and technology
Excitation
Integrals
low-energy electron scattering
Mathematical analysis
Molecular excitation and ionization by electron impact
Multichannel
Physics
water
title Excitation of the six lowest electronic transitions in water by 9-20 eV electrons
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