Direct Measurement of Energy Barriers on Rough and Heterogeneous Solid Surfaces
The "three-liquid" contact angle approach to the surface free energy components of solids was applied to poly (vinyl fluoride), rough and flattened, with and without flame treatment. Lifshitz-van der Waals (LW), γ LW SL , and acid-base (AB), γ LW SL , components were determined and used to...
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| Veröffentlicht in: | The Journal of adhesion 1997-06, Vol.63 (1-3), p.141-157 |
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| container_issue | 1-3 |
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| container_title | The Journal of adhesion |
| container_volume | 63 |
| creator | Lloyd, Thomas B. Connelly, Guy M. |
| description | The "three-liquid" contact angle approach to the surface free energy components of solids was applied to poly (vinyl fluoride), rough and flattened, with and without flame treatment. Lifshitz-van der Waals (LW), γ
LW
SL
, and acid-base (AB), γ
LW
SL
, components were determined and used to calculate −δG
SL
(W
adhesion
SL
) for the formation of interfaces of five liquids with polymer. The automated goniometer allowed the determination of the energy barriers, −δ G*
SL
as the advancing liquid moved from pinned configuration to a metastable one. The acid-base component of the barriers was much greater than the LW, and the magnitude of the barriers was only slightly reduced by flattening. |
| doi_str_mv | 10.1080/00218469708015218 |
| format | Article |
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LW
SL
, and acid-base (AB), γ
LW
SL
, components were determined and used to calculate −δG
SL
(W
adhesion
SL
) for the formation of interfaces of five liquids with polymer. The automated goniometer allowed the determination of the energy barriers, −δ G*
SL
as the advancing liquid moved from pinned configuration to a metastable one. The acid-base component of the barriers was much greater than the LW, and the magnitude of the barriers was only slightly reduced by flattening.</description><identifier>ISSN: 0021-8464</identifier><identifier>EISSN: 1545-5823</identifier><identifier>EISSN: 1563-518X</identifier><identifier>DOI: 10.1080/00218469708015218</identifier><identifier>CODEN: JADNAJ</identifier><language>eng</language><publisher>Basingstoke: Taylor & Francis Group</publisher><subject>acid-base parameters ; Applied sciences ; contact angle ; energy barriers to wetting ; Exact sciences and technology ; hysteresis ; Lifshitz-van der Waals forces ; Liquid-solid adhesion ; Physical properties ; Polymer industry, paints, wood ; Properties and testing ; Surface properties ; Technology of polymers</subject><ispartof>The Journal of adhesion, 1997-06, Vol.63 (1-3), p.141-157</ispartof><rights>Copyright Taylor & Francis Group, LLC 1997</rights><rights>1997 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c373t-daddae0c92c0ad4e1d74b87a920327ba94c13eb7f64fd0b596ac3ccaa87452463</citedby><cites>FETCH-LOGICAL-c373t-daddae0c92c0ad4e1d74b87a920327ba94c13eb7f64fd0b596ac3ccaa87452463</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.tandfonline.com/doi/pdf/10.1080/00218469708015218$$EPDF$$P50$$Ginformaworld$$H</linktopdf><linktohtml>$$Uhttps://www.tandfonline.com/doi/full/10.1080/00218469708015218$$EHTML$$P50$$Ginformaworld$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,59626,60415</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=2712450$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Lloyd, Thomas B.</creatorcontrib><creatorcontrib>Connelly, Guy M.</creatorcontrib><title>Direct Measurement of Energy Barriers on Rough and Heterogeneous Solid Surfaces</title><title>The Journal of adhesion</title><description>The "three-liquid" contact angle approach to the surface free energy components of solids was applied to poly (vinyl fluoride), rough and flattened, with and without flame treatment. Lifshitz-van der Waals (LW), γ
LW
SL
, and acid-base (AB), γ
LW
SL
, components were determined and used to calculate −δG
SL
(W
adhesion
SL
) for the formation of interfaces of five liquids with polymer. The automated goniometer allowed the determination of the energy barriers, −δ G*
SL
as the advancing liquid moved from pinned configuration to a metastable one. The acid-base component of the barriers was much greater than the LW, and the magnitude of the barriers was only slightly reduced by flattening.</description><subject>acid-base parameters</subject><subject>Applied sciences</subject><subject>contact angle</subject><subject>energy barriers to wetting</subject><subject>Exact sciences and technology</subject><subject>hysteresis</subject><subject>Lifshitz-van der Waals forces</subject><subject>Liquid-solid adhesion</subject><subject>Physical properties</subject><subject>Polymer industry, paints, wood</subject><subject>Properties and testing</subject><subject>Surface properties</subject><subject>Technology of polymers</subject><issn>0021-8464</issn><issn>1545-5823</issn><issn>1563-518X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLw0AUhQdRsNT-AHezcBudVzIJuNFaH1ApWF2Hm3nUQJopdxK0_96Uqpsiru693PMdDoeQc84uOcvZFWOC5yor9HDwdNiPyIinKk3SXMhjMtr9k0GgTskkxrpiLM-ZLKQckcVdjc509NlB7NGtXdvR4Omsdbja0ltArB1GGlr6EvrVO4XW0kfXOQwr17rQR7oMTW3pskcPxsUzcuKhiW7yPcfk7X72On1M5ouHp-nNPDFSyy6xYC04ZgphGFjluNWqyjUUgkmhKyiU4dJV2mfKW1alRQZGGgOQa5UKlckx4XtfgyFGdL7cYL0G3JaclbtSyoNSBuZiz2wgGmg8Qmvq-AsKzYVK2SDTe1nd-oBr-AjY2LKDbRPwhzkwL7vPbiCv_yXl3_m-ADfShvU</recordid><startdate>19970601</startdate><enddate>19970601</enddate><creator>Lloyd, Thomas B.</creator><creator>Connelly, Guy M.</creator><general>Taylor & Francis Group</general><general>Taylor and Francis</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19970601</creationdate><title>Direct Measurement of Energy Barriers on Rough and Heterogeneous Solid Surfaces</title><author>Lloyd, Thomas B. ; Connelly, Guy M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c373t-daddae0c92c0ad4e1d74b87a920327ba94c13eb7f64fd0b596ac3ccaa87452463</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><topic>acid-base parameters</topic><topic>Applied sciences</topic><topic>contact angle</topic><topic>energy barriers to wetting</topic><topic>Exact sciences and technology</topic><topic>hysteresis</topic><topic>Lifshitz-van der Waals forces</topic><topic>Liquid-solid adhesion</topic><topic>Physical properties</topic><topic>Polymer industry, paints, wood</topic><topic>Properties and testing</topic><topic>Surface properties</topic><topic>Technology of polymers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lloyd, Thomas B.</creatorcontrib><creatorcontrib>Connelly, Guy M.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>The Journal of adhesion</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lloyd, Thomas B.</au><au>Connelly, Guy M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Direct Measurement of Energy Barriers on Rough and Heterogeneous Solid Surfaces</atitle><jtitle>The Journal of adhesion</jtitle><date>1997-06-01</date><risdate>1997</risdate><volume>63</volume><issue>1-3</issue><spage>141</spage><epage>157</epage><pages>141-157</pages><issn>0021-8464</issn><eissn>1545-5823</eissn><eissn>1563-518X</eissn><coden>JADNAJ</coden><abstract>The "three-liquid" contact angle approach to the surface free energy components of solids was applied to poly (vinyl fluoride), rough and flattened, with and without flame treatment. Lifshitz-van der Waals (LW), γ
LW
SL
, and acid-base (AB), γ
LW
SL
, components were determined and used to calculate −δG
SL
(W
adhesion
SL
) for the formation of interfaces of five liquids with polymer. The automated goniometer allowed the determination of the energy barriers, −δ G*
SL
as the advancing liquid moved from pinned configuration to a metastable one. The acid-base component of the barriers was much greater than the LW, and the magnitude of the barriers was only slightly reduced by flattening.</abstract><cop>Basingstoke</cop><pub>Taylor & Francis Group</pub><doi>10.1080/00218469708015218</doi><tpages>17</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-8464 |
| ispartof | The Journal of adhesion, 1997-06, Vol.63 (1-3), p.141-157 |
| issn | 0021-8464 1545-5823 1563-518X |
| language | eng |
| recordid | cdi_pascalfrancis_primary_2712450 |
| source | Taylor & Francis Journals Complete |
| subjects | acid-base parameters Applied sciences contact angle energy barriers to wetting Exact sciences and technology hysteresis Lifshitz-van der Waals forces Liquid-solid adhesion Physical properties Polymer industry, paints, wood Properties and testing Surface properties Technology of polymers |
| title | Direct Measurement of Energy Barriers on Rough and Heterogeneous Solid Surfaces |
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