The T-Al3 (Mn, Pd) quasicrystalline approximant: Chemical order and phason defects
The structure of an orthorhombic phase called T-Al 3 Mn, Pd, with the composition Al 72· Pd 3·2 Mn 24·5 , has been determined by single-crystal X-ray diffraction. The space group is Pnma and the magnitudes of the cell parameters are a = 14.717 A, b = 12.510 Å and c = 12.594 A. The final reliability...
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| Veröffentlicht in: | Philosophical magazine letters 1997-04, Vol.75 (4), p.197-208 |
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| creator | Klein, H. Boudard, M. Audier, M. DE BOISSIEU, M. Vincent, H. Beraha, L. Duneau, M. |
| description | The structure of an orthorhombic phase called T-Al
3
Mn, Pd, with the composition Al
72·
Pd
3·2
Mn
24·5
, has been determined by single-crystal X-ray diffraction. The space group is Pnma and the magnitudes of the cell parameters are a = 14.717 A, b = 12.510 Å and c = 12.594 A. The final reliability factor is R = 0.022 and for 2734 independent reflections. The structure exhibits a strong chemical ordering and is compared to the isomorphic phase T-Al
3
Mn and to the closely related R-Al
60
Mn
11
Ni
4
phase. The possibility of a phase transformation occurring through the motion of phason defects, between the T-Al
3
(Mn, Pd) orthorhombic phase and another orthorhombic phase, isomorphic to the R-Al
60
Mn
11
Ni
4
phase, is briefly discussed. |
| doi_str_mv | 10.1080/095008397179624 |
| format | Article |
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3
Mn, Pd, with the composition Al
72·
Pd
3·2
Mn
24·5
, has been determined by single-crystal X-ray diffraction. The space group is Pnma and the magnitudes of the cell parameters are a = 14.717 A, b = 12.510 Å and c = 12.594 A. The final reliability factor is R = 0.022 and for 2734 independent reflections. The structure exhibits a strong chemical ordering and is compared to the isomorphic phase T-Al
3
Mn and to the closely related R-Al
60
Mn
11
Ni
4
phase. The possibility of a phase transformation occurring through the motion of phason defects, between the T-Al
3
(Mn, Pd) orthorhombic phase and another orthorhombic phase, isomorphic to the R-Al
60
Mn
11
Ni
4
phase, is briefly discussed.</description><identifier>ISSN: 0950-0839</identifier><identifier>EISSN: 1362-3036</identifier><identifier>DOI: 10.1080/095008397179624</identifier><identifier>CODEN: PMLEEG</identifier><language>eng</language><publisher>London: Taylor & Francis Group</publisher><subject>Alloys ; Applied sciences ; Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; Metals. Metallurgy ; Physics ; Quasicrystals ; Semi-periodic solids ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids</subject><ispartof>Philosophical magazine letters, 1997-04, Vol.75 (4), p.197-208</ispartof><rights>Copyright Taylor & Francis Group, LLC 1997</rights><rights>1997 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.tandfonline.com/doi/pdf/10.1080/095008397179624$$EPDF$$P50$$Ginformaworld$$H</linktopdf><linktohtml>$$Uhttps://www.tandfonline.com/doi/full/10.1080/095008397179624$$EHTML$$P50$$Ginformaworld$$H</linktohtml><link.rule.ids>314,780,784,27869,27924,27925,59647,60436</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=2625236$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Klein, H.</creatorcontrib><creatorcontrib>Boudard, M.</creatorcontrib><creatorcontrib>Audier, M.</creatorcontrib><creatorcontrib>DE BOISSIEU, M.</creatorcontrib><creatorcontrib>Vincent, H.</creatorcontrib><creatorcontrib>Beraha, L.</creatorcontrib><creatorcontrib>Duneau, M.</creatorcontrib><title>The T-Al3 (Mn, Pd) quasicrystalline approximant: Chemical order and phason defects</title><title>Philosophical magazine letters</title><description>The structure of an orthorhombic phase called T-Al
3
Mn, Pd, with the composition Al
72·
Pd
3·2
Mn
24·5
, has been determined by single-crystal X-ray diffraction. The space group is Pnma and the magnitudes of the cell parameters are a = 14.717 A, b = 12.510 Å and c = 12.594 A. The final reliability factor is R = 0.022 and for 2734 independent reflections. The structure exhibits a strong chemical ordering and is compared to the isomorphic phase T-Al
3
Mn and to the closely related R-Al
60
Mn
11
Ni
4
phase. The possibility of a phase transformation occurring through the motion of phason defects, between the T-Al
3
(Mn, Pd) orthorhombic phase and another orthorhombic phase, isomorphic to the R-Al
60
Mn
11
Ni
4
phase, is briefly discussed.</description><subject>Alloys</subject><subject>Applied sciences</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>Metals. Metallurgy</subject><subject>Physics</subject><subject>Quasicrystals</subject><subject>Semi-periodic solids</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><issn>0950-0839</issn><issn>1362-3036</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><sourceid>K30</sourceid><recordid>eNqFkc1LAzEQxYMoWKtnrwE9KLg6STabbG-l-AUVRep5SfNBt2yzbZJi-9-7pfXixdMc3u_NvJlB6JLAPQEJD1ByAMlKQURZ0PwI9QgraMaAFceot1OznXyKzmKcA0Be5ryHPicziyfZsGH45s3f4Q9zi1drFWsdtjGppqm9xWq5DO2mXiifBng0s4taqwa3wdiAlTd4OVOx9dhYZ3WK5-jEqSbai0Pto6-nx8noJRu_P7-OhuOsppSmzAplnZagLTV5boSmupAkl5ZbI0FQJwxjxknCQU-NMaUkzomplc5xVzLL-uhq37cLt1rbmKp5uw6-G1kRwUFSoJR31PWBUrFL7YLyuo7VMnTrhG1FC8opKzqM77HauzYs1HcbGlMltW3a8Ov5c-EqbVLnG_zrYwSq3Yv-NmA_Y22CxQ</recordid><startdate>19970401</startdate><enddate>19970401</enddate><creator>Klein, H.</creator><creator>Boudard, M.</creator><creator>Audier, M.</creator><creator>DE BOISSIEU, M.</creator><creator>Vincent, H.</creator><creator>Beraha, L.</creator><creator>Duneau, M.</creator><general>Taylor & Francis Group</general><general>Taylor & Francis</general><general>Taylor and Francis</general><scope>IQODW</scope><scope>HAGHG</scope><scope>IZSXY</scope><scope>K30</scope><scope>PAAUG</scope><scope>PAWHS</scope><scope>PAWZZ</scope><scope>PAXOH</scope><scope>PBHAV</scope><scope>PBQSW</scope><scope>PBYQZ</scope><scope>PCIWU</scope><scope>PCMID</scope><scope>PCZJX</scope><scope>PDGRG</scope><scope>PDWWI</scope><scope>PETMR</scope><scope>PFVGT</scope><scope>PGXDX</scope><scope>PIHIL</scope><scope>PISVA</scope><scope>PJCTQ</scope><scope>PJTMS</scope><scope>PLCHJ</scope><scope>PMHAD</scope><scope>PNQDJ</scope><scope>POUND</scope><scope>PPLAD</scope><scope>PQAPC</scope><scope>PQCAN</scope><scope>PQCMW</scope><scope>PQEME</scope><scope>PQHKH</scope><scope>PQMID</scope><scope>PQNCT</scope><scope>PQNET</scope><scope>PQSCT</scope><scope>PQSET</scope><scope>PSVJG</scope><scope>PVMQY</scope><scope>PZGFC</scope></search><sort><creationdate>19970401</creationdate><title>The T-Al3 (Mn, Pd) quasicrystalline approximant: Chemical order and phason defects</title><author>Klein, H. ; Boudard, M. ; Audier, M. ; DE BOISSIEU, M. ; Vincent, H. ; Beraha, L. ; Duneau, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i222t-e7aefc80ce2d44d7c2c68148e5ed8072f7d33df8150cbddd981ff7be8ff5f93e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><topic>Alloys</topic><topic>Applied sciences</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>Metals. Metallurgy</topic><topic>Physics</topic><topic>Quasicrystals</topic><topic>Semi-periodic solids</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Klein, H.</creatorcontrib><creatorcontrib>Boudard, M.</creatorcontrib><creatorcontrib>Audier, M.</creatorcontrib><creatorcontrib>DE BOISSIEU, M.</creatorcontrib><creatorcontrib>Vincent, H.</creatorcontrib><creatorcontrib>Beraha, L.</creatorcontrib><creatorcontrib>Duneau, M.</creatorcontrib><collection>Pascal-Francis</collection><collection>Periodicals Index Online Segment 12</collection><collection>Periodicals Index Online Segment 30</collection><collection>Periodicals Index Online</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - West</collection><collection>Primary Sources Access (Plan D) - International</collection><collection>Primary Sources Access & Build (Plan A) - MEA</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - Midwest</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - Northeast</collection><collection>Primary Sources Access (Plan D) - Southeast</collection><collection>Primary Sources Access (Plan D) - North Central</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - Southeast</collection><collection>Primary Sources Access (Plan D) - South Central</collection><collection>Primary Sources Access & Build (Plan A) - UK / I</collection><collection>Primary Sources Access (Plan D) - Canada</collection><collection>Primary Sources Access (Plan D) - EMEALA</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - North Central</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - South Central</collection><collection>Primary Sources Access & Build (Plan A) - International</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - International</collection><collection>Primary Sources Access (Plan D) - West</collection><collection>Periodicals Index Online Segments 1-50</collection><collection>Primary Sources Access (Plan D) - APAC</collection><collection>Primary Sources Access (Plan D) - Midwest</collection><collection>Primary Sources Access (Plan D) - MEA</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - Canada</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - UK / I</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - EMEALA</collection><collection>Primary Sources Access & Build (Plan A) - APAC</collection><collection>Primary Sources Access & Build (Plan A) - Canada</collection><collection>Primary Sources Access & Build (Plan A) - West</collection><collection>Primary Sources Access & Build (Plan A) - EMEALA</collection><collection>Primary Sources Access (Plan D) - Northeast</collection><collection>Primary Sources Access & Build (Plan A) - Midwest</collection><collection>Primary Sources Access & Build (Plan A) - North Central</collection><collection>Primary Sources Access & Build (Plan A) - Northeast</collection><collection>Primary Sources Access & Build (Plan A) - South Central</collection><collection>Primary Sources Access & Build (Plan A) - Southeast</collection><collection>Primary Sources Access (Plan D) - UK / I</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - APAC</collection><collection>Primary Sources Access—Foundation Edition (Plan E) - MEA</collection><jtitle>Philosophical magazine letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Klein, H.</au><au>Boudard, M.</au><au>Audier, M.</au><au>DE BOISSIEU, M.</au><au>Vincent, H.</au><au>Beraha, L.</au><au>Duneau, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The T-Al3 (Mn, Pd) quasicrystalline approximant: Chemical order and phason defects</atitle><jtitle>Philosophical magazine letters</jtitle><date>1997-04-01</date><risdate>1997</risdate><volume>75</volume><issue>4</issue><spage>197</spage><epage>208</epage><pages>197-208</pages><issn>0950-0839</issn><eissn>1362-3036</eissn><coden>PMLEEG</coden><abstract>The structure of an orthorhombic phase called T-Al
3
Mn, Pd, with the composition Al
72·
Pd
3·2
Mn
24·5
, has been determined by single-crystal X-ray diffraction. The space group is Pnma and the magnitudes of the cell parameters are a = 14.717 A, b = 12.510 Å and c = 12.594 A. The final reliability factor is R = 0.022 and for 2734 independent reflections. The structure exhibits a strong chemical ordering and is compared to the isomorphic phase T-Al
3
Mn and to the closely related R-Al
60
Mn
11
Ni
4
phase. The possibility of a phase transformation occurring through the motion of phason defects, between the T-Al
3
(Mn, Pd) orthorhombic phase and another orthorhombic phase, isomorphic to the R-Al
60
Mn
11
Ni
4
phase, is briefly discussed.</abstract><cop>London</cop><pub>Taylor & Francis Group</pub><doi>10.1080/095008397179624</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0950-0839 |
| ispartof | Philosophical magazine letters, 1997-04, Vol.75 (4), p.197-208 |
| issn | 0950-0839 1362-3036 |
| language | eng |
| recordid | cdi_pascalfrancis_primary_2625236 |
| source | Periodicals Index Online; Taylor & Francis Journals Complete |
| subjects | Alloys Applied sciences Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Metals. Metallurgy Physics Quasicrystals Semi-periodic solids Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | The T-Al3 (Mn, Pd) quasicrystalline approximant: Chemical order and phason defects |
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