Measurement of free radical kinetics in pulsed plasmas by UV and VUV absorption spectroscopy and by modulated beam mass spectrometry

This paper reviews recent progress in the development of time-resolved diagnostics to probe high-density pulsed plasma sources. We focus on time-resolved measurements of radicals' densities in the afterglow of pulsed discharges to provide useful information on production and loss mechanisms of...

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Veröffentlicht in:Plasma sources science & technology 2012-04, Vol.21 (2), p.24006-1-9
Hauptverfasser: Cunge, G, Bodart, P, Brihoum, M, Boulard, F, Chevolleau, T, Sadeghi, N
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container_issue 2
container_start_page 24006
container_title Plasma sources science & technology
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creator Cunge, G
Bodart, P
Brihoum, M
Boulard, F
Chevolleau, T
Sadeghi, N
description This paper reviews recent progress in the development of time-resolved diagnostics to probe high-density pulsed plasma sources. We focus on time-resolved measurements of radicals' densities in the afterglow of pulsed discharges to provide useful information on production and loss mechanisms of free radicals. We show that broad-band absorption spectroscopy in the ultraviolet and vacuum ultraviolet spectral domain and threshold ionization modulated beam mass spectrometry are powerful techniques for the determination of the time variation of the radicals' densities in pulsed plasmas. The combination of these complementary techniques allows detection of most of the reactive species present in industrial etching plasmas, giving insights into the physico-chemistry reactions involving these species. As an example, we discuss briefly the radicals' kinetics in the afterglow of a SiCl4/Cl2/Ar discharge.
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subjects Absorption spectroscopy
Afterglows
Beams (radiation)
Density
Exact sciences and technology
Free radicals
Ionization of plasmas
Mass spectrometry
Optical (ultraviolet, visible, infrared) measurements
Optics
Physics
Physics of gases, plasmas and electric discharges
Physics of plasmas and electric discharges
Plasma diagnostic techniques and instrumentation
Plasma Physics
Plasma production and heating
Plasma properties
Plasma sources
Plasmas
Radicals
title Measurement of free radical kinetics in pulsed plasmas by UV and VUV absorption spectroscopy and by modulated beam mass spectrometry
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