Palladium-Catalyzed Oxidative Intramolecular CC Bond Formation via Double sp2 CH Activation between the 2-Position of Imidazoles and a Benzene Ring
Oxidative intramolecular CC bond formation via double sp2 CH activation between the 2‐position of imidazoles and a benzene ring catalyzed by palladium(II) has been developed, which provides an atom‐economical, concise and efficient methodology to synthesize imidazole‐ or benzimidazole‐fused isoqui...
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Veröffentlicht in: | Advanced synthesis & catalysis 2012-03, Vol.354 (5), p.835-838 |
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creator | Sun, Manman Wu, Huandong Zheng, Junnan Bao, Weiliang |
description | Oxidative intramolecular CC bond formation via double sp2 CH activation between the 2‐position of imidazoles and a benzene ring catalyzed by palladium(II) has been developed, which provides an atom‐economical, concise and efficient methodology to synthesize imidazole‐ or benzimidazole‐fused isoquinoline polyheteroaromatic compounds. |
doi_str_mv | 10.1002/adsc.201100801 |
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Synth. Catal</addtitle><description>Oxidative intramolecular CC bond formation via double sp2 CH activation between the 2‐position of imidazoles and a benzene ring catalyzed by palladium(II) has been developed, which provides an atom‐economical, concise and efficient methodology to synthesize imidazole‐ or benzimidazole‐fused isoquinoline polyheteroaromatic compounds.</description><subject>Chemistry</subject><subject>double sp2 CH activation</subject><subject>Exact sciences and technology</subject><subject>Heterocyclic compounds</subject><subject>Heterocyclic compounds with only one n hetero atom and condensed derivatives</subject><subject>Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings</subject><subject>imidazole- or benzimidazole-fused isoquinoline compounds</subject><subject>intramolecular CC bond formation</subject><subject>Noncondensed benzenic compounds</subject><subject>Organic chemistry</subject><subject>palladium(II) catalysis</subject><subject>Preparations and properties</subject><issn>1615-4150</issn><issn>1615-4169</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNo9UEtOwzAQjRBIQGHL2huWAdtx7HrZpvQjECD-O2sSO2BwkipOgfYmrDkIR-IKBIqymnnzPiO9IDgg-IhgTI9B--yIYtKCPiYbwQ7hJA4Z4XKz22O8Hex6_4wxEX0hdoKPS3AOtF0UYQINuOXKaHTxbjU09tWgWdnUUFTOZAsHNUq-P78SNKxKjcZVXbSaqkSvFtCoWqTOID-nf5opGmStf82npnkzpkTNk0E0vKy8_TtXOZoV7Z9Vm-4RtJGAhqZcmdKgK1s-7gVbOThv9v9nL7gdn9wk0_DsYjJLBmehJX1GQhIxnudaRxFlwDXLMWagMReUpppKnPVZLDQVWGCa5zTSqZSGQ8qollzSLOoFh-vcOfgMXF5DmVmv5rUtoF4qGnMWESlbnVzr3qwzy44nWP22r37bV137ajC6TjrUesO11_rGvHdeqF8UF5GI1f35RJGHu7GI5bU6jX4AYUqNZQ</recordid><startdate>20120316</startdate><enddate>20120316</enddate><creator>Sun, Manman</creator><creator>Wu, Huandong</creator><creator>Zheng, Junnan</creator><creator>Bao, Weiliang</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley-VCH</general><scope>BSCLL</scope><scope>IQODW</scope></search><sort><creationdate>20120316</creationdate><title>Palladium-Catalyzed Oxidative Intramolecular CC Bond Formation via Double sp2 CH Activation between the 2-Position of Imidazoles and a Benzene Ring</title><author>Sun, Manman ; Wu, Huandong ; Zheng, Junnan ; Bao, Weiliang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i1841-1346ffdd3324a6d4f004ad06722bd290c8457d270702ff23db99e6ab42d9692c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Chemistry</topic><topic>double sp2 CH activation</topic><topic>Exact sciences and technology</topic><topic>Heterocyclic compounds</topic><topic>Heterocyclic compounds with only one n hetero atom and condensed derivatives</topic><topic>Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings</topic><topic>imidazole- or benzimidazole-fused isoquinoline compounds</topic><topic>intramolecular CC bond formation</topic><topic>Noncondensed benzenic compounds</topic><topic>Organic chemistry</topic><topic>palladium(II) catalysis</topic><topic>Preparations and properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sun, Manman</creatorcontrib><creatorcontrib>Wu, Huandong</creatorcontrib><creatorcontrib>Zheng, Junnan</creatorcontrib><creatorcontrib>Bao, Weiliang</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><jtitle>Advanced synthesis & catalysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sun, Manman</au><au>Wu, Huandong</au><au>Zheng, Junnan</au><au>Bao, Weiliang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Palladium-Catalyzed Oxidative Intramolecular CC Bond Formation via Double sp2 CH Activation between the 2-Position of Imidazoles and a Benzene Ring</atitle><jtitle>Advanced synthesis & catalysis</jtitle><addtitle>Adv. Synth. Catal</addtitle><date>2012-03-16</date><risdate>2012</risdate><volume>354</volume><issue>5</issue><spage>835</spage><epage>838</epage><pages>835-838</pages><issn>1615-4150</issn><eissn>1615-4169</eissn><abstract>Oxidative intramolecular CC bond formation via double sp2 CH activation between the 2‐position of imidazoles and a benzene ring catalyzed by palladium(II) has been developed, which provides an atom‐economical, concise and efficient methodology to synthesize imidazole‐ or benzimidazole‐fused isoquinoline polyheteroaromatic compounds.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/adsc.201100801</doi><tpages>4</tpages></addata></record> |
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subjects | Chemistry double sp2 CH activation Exact sciences and technology Heterocyclic compounds Heterocyclic compounds with only one n hetero atom and condensed derivatives Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings imidazole- or benzimidazole-fused isoquinoline compounds intramolecular CC bond formation Noncondensed benzenic compounds Organic chemistry palladium(II) catalysis Preparations and properties |
title | Palladium-Catalyzed Oxidative Intramolecular CC Bond Formation via Double sp2 CH Activation between the 2-Position of Imidazoles and a Benzene Ring |
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