Effect of H2O2 on Pt electrode dissolution in H2SO4 solution based on electrochemical quartz crystal microbalance study

The effect of H2O2 on the Pt dissolution in 0.5 mol dm−3 H2SO4 was investigated using an electrochemical quartz crystal microbalance (EQCM). For the potential cycling at 50 mV s−1, the Pt weight irreversibly decreases in a N2 atmosphere with H2O2, while only a negligible Pt weight-loss is observed i...

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Veröffentlicht in:International journal of hydrogen energy 2012-01, Vol.37 (2), p.1226-1235
Hauptverfasser: Inoue, Mitsuhiro, Nakazawa, Akira, Umeda, Minoru
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container_title International journal of hydrogen energy
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creator Inoue, Mitsuhiro
Nakazawa, Akira
Umeda, Minoru
description The effect of H2O2 on the Pt dissolution in 0.5 mol dm−3 H2SO4 was investigated using an electrochemical quartz crystal microbalance (EQCM). For the potential cycling at 50 mV s−1, the Pt weight irreversibly decreases in a N2 atmosphere with H2O2, while only a negligible Pt weight-loss is observed in the N2 and O2 atmospheres without H2O2. The EQCM data measured by the potential step showed that the Pt dissolution in the presence of H2O2 depends on the electrode potential and the H2O2 concentration. For the stationary electrolysis, the Pt dissolution occurs at 0.61–1.06 and 1.06–1.36 V vs. RHE. It should be noted that the Pt dissolution phenomenon in the presence of H2O2 is also affected by the potential scanning time. Based on these results, H2O2 is considered not only to contribute to the formation of Pt-oxide causing the cathodic Pt dissolution, but also to participate in the anodic Pt dissolution and the chemical Pt dissolution. ► The Pt dissolution is accelerated by potential scanning in H2O2-containing H2SO4. ► The Pt dissolution in the presence of H2O2 depends on the electrode potential and the H2O2 amount. ► The potential scanning time affects the Pt dissolution phenomenon in H2SO4 containing H2O2. ► H2O2 contributes to the Pt-oxide formation causing the cathodic Pt dissolution. ► H2O2 also participates in the anodic Pt dissolution and the chemical Pt dissolution.
doi_str_mv 10.1016/j.ijhydene.2011.09.130
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For the potential cycling at 50 mV s−1, the Pt weight irreversibly decreases in a N2 atmosphere with H2O2, while only a negligible Pt weight-loss is observed in the N2 and O2 atmospheres without H2O2. The EQCM data measured by the potential step showed that the Pt dissolution in the presence of H2O2 depends on the electrode potential and the H2O2 concentration. For the stationary electrolysis, the Pt dissolution occurs at 0.61–1.06 and 1.06–1.36 V vs. RHE. It should be noted that the Pt dissolution phenomenon in the presence of H2O2 is also affected by the potential scanning time. Based on these results, H2O2 is considered not only to contribute to the formation of Pt-oxide causing the cathodic Pt dissolution, but also to participate in the anodic Pt dissolution and the chemical Pt dissolution. ► The Pt dissolution is accelerated by potential scanning in H2O2-containing H2SO4. ► The Pt dissolution in the presence of H2O2 depends on the electrode potential and the H2O2 amount. ► The potential scanning time affects the Pt dissolution phenomenon in H2SO4 containing H2O2. ► H2O2 contributes to the Pt-oxide formation causing the cathodic Pt dissolution. ► H2O2 also participates in the anodic Pt dissolution and the chemical Pt dissolution.</description><identifier>ISSN: 0360-3199</identifier><identifier>EISSN: 1879-3487</identifier><identifier>DOI: 10.1016/j.ijhydene.2011.09.130</identifier><identifier>CODEN: IJHEDX</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Applied sciences ; Cathode catalyst ; Electrochemical quartz crystal microbalance (EQCM) ; Energy ; Energy. 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For the potential cycling at 50 mV s−1, the Pt weight irreversibly decreases in a N2 atmosphere with H2O2, while only a negligible Pt weight-loss is observed in the N2 and O2 atmospheres without H2O2. The EQCM data measured by the potential step showed that the Pt dissolution in the presence of H2O2 depends on the electrode potential and the H2O2 concentration. For the stationary electrolysis, the Pt dissolution occurs at 0.61–1.06 and 1.06–1.36 V vs. RHE. It should be noted that the Pt dissolution phenomenon in the presence of H2O2 is also affected by the potential scanning time. Based on these results, H2O2 is considered not only to contribute to the formation of Pt-oxide causing the cathodic Pt dissolution, but also to participate in the anodic Pt dissolution and the chemical Pt dissolution. ► The Pt dissolution is accelerated by potential scanning in H2O2-containing H2SO4. ► The Pt dissolution in the presence of H2O2 depends on the electrode potential and the H2O2 amount. ► The potential scanning time affects the Pt dissolution phenomenon in H2SO4 containing H2O2. ► H2O2 contributes to the Pt-oxide formation causing the cathodic Pt dissolution. ► H2O2 also participates in the anodic Pt dissolution and the chemical Pt dissolution.</description><subject>Applied sciences</subject><subject>Cathode catalyst</subject><subject>Electrochemical quartz crystal microbalance (EQCM)</subject><subject>Energy</subject><subject>Energy. 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Thermal use of fuels</topic><topic>Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc</topic><topic>Exact sciences and technology</topic><topic>Fuel cells</topic><topic>H2O2</topic><topic>H2SO4</topic><topic>Polymer electrolyte fuel cells (PEFCs)</topic><topic>Pt dissolution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Inoue, Mitsuhiro</creatorcontrib><creatorcontrib>Nakazawa, Akira</creatorcontrib><creatorcontrib>Umeda, Minoru</creatorcontrib><collection>Pascal-Francis</collection><jtitle>International journal of hydrogen energy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Inoue, Mitsuhiro</au><au>Nakazawa, Akira</au><au>Umeda, Minoru</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of H2O2 on Pt electrode dissolution in H2SO4 solution based on electrochemical quartz crystal microbalance study</atitle><jtitle>International journal of hydrogen energy</jtitle><date>2012-01</date><risdate>2012</risdate><volume>37</volume><issue>2</issue><spage>1226</spage><epage>1235</epage><pages>1226-1235</pages><issn>0360-3199</issn><eissn>1879-3487</eissn><coden>IJHEDX</coden><abstract>The effect of H2O2 on the Pt dissolution in 0.5 mol dm−3 H2SO4 was investigated using an electrochemical quartz crystal microbalance (EQCM). For the potential cycling at 50 mV s−1, the Pt weight irreversibly decreases in a N2 atmosphere with H2O2, while only a negligible Pt weight-loss is observed in the N2 and O2 atmospheres without H2O2. The EQCM data measured by the potential step showed that the Pt dissolution in the presence of H2O2 depends on the electrode potential and the H2O2 concentration. For the stationary electrolysis, the Pt dissolution occurs at 0.61–1.06 and 1.06–1.36 V vs. RHE. It should be noted that the Pt dissolution phenomenon in the presence of H2O2 is also affected by the potential scanning time. Based on these results, H2O2 is considered not only to contribute to the formation of Pt-oxide causing the cathodic Pt dissolution, but also to participate in the anodic Pt dissolution and the chemical Pt dissolution. ► The Pt dissolution is accelerated by potential scanning in H2O2-containing H2SO4. ► The Pt dissolution in the presence of H2O2 depends on the electrode potential and the H2O2 amount. ► The potential scanning time affects the Pt dissolution phenomenon in H2SO4 containing H2O2. ► H2O2 contributes to the Pt-oxide formation causing the cathodic Pt dissolution. ► H2O2 also participates in the anodic Pt dissolution and the chemical Pt dissolution.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.ijhydene.2011.09.130</doi><tpages>10</tpages></addata></record>
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subjects Applied sciences
Cathode catalyst
Electrochemical quartz crystal microbalance (EQCM)
Energy
Energy. Thermal use of fuels
Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc
Exact sciences and technology
Fuel cells
H2O2
H2SO4
Polymer electrolyte fuel cells (PEFCs)
Pt dissolution
title Effect of H2O2 on Pt electrode dissolution in H2SO4 solution based on electrochemical quartz crystal microbalance study
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