Fe3O4@mesoporouspolyaniline: A Highly Efficient and Magnetically Separable Catalyst for Cross-Coupling of Aryl Chlorides and Phenols
A high surface, magnetic Fe3O4@mesoporouspolyaniline core‐shell nanocomposite was synthesized from magnetic iron oxide (Fe3O4) nanoparticles and mesoporouspolyaniline (mPANI). The novel porous magnetic Fe3O4 was obtained by solvothermal method under sealed pressure reactor at high temperature to ach...
Gespeichert in:
| Veröffentlicht in: | Advanced synthesis & catalysis 2011-06, Vol.353 (9), p.1591-1600 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1600 |
|---|---|
| container_issue | 9 |
| container_start_page | 1591 |
| container_title | Advanced synthesis & catalysis |
| container_volume | 353 |
| creator | Arundhathi, R. Damodara, D. Likhar, Pravin R. Kantam, M. Lakshmi Saravanan, P. Magdaleno, Travis Kwon, Sun Hee |
| description | A high surface, magnetic Fe3O4@mesoporouspolyaniline core‐shell nanocomposite was synthesized from magnetic iron oxide (Fe3O4) nanoparticles and mesoporouspolyaniline (mPANI). The novel porous magnetic Fe3O4 was obtained by solvothermal method under sealed pressure reactor at high temperature to achieve high surface area. The mesoporouspolyaniline shell was synthesized by in situ surface polymerization onto porous magnetic Fe3O4 in the presence of polyvinylpyrrolidone (PVP) and sodium dodecylbenzenesulfonate (SDBS), as a linker and structure‐directing agent, through ‘blackberry nanostructures’ assembly. The material composition, stoichiometric ratio and reaction conditions play vital roles in the synthesis of these nanostructures as confirmed by variety of characterization techniques. The role of the mesoporouspolyaniline shell is to stabilize the porous magnetic Fe3O4 nanoparticles, and provide direct access to the core Fe3O4 nanoparticles. The catalytic activity of magnetic Fe3O4@mesoporousPANI nanocomposite was evaluated in the cross‐coupling of aryl chlorides and phenols. |
| doi_str_mv | 10.1002/adsc.201000977 |
| format | Article |
| fullrecord | <record><control><sourceid>wiley_pasca</sourceid><recordid>TN_cdi_pascalfrancis_primary_24302470</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ADSC201000977</sourcerecordid><originalsourceid>FETCH-LOGICAL-i3397-23be3fc1c6de4b0e687e18a62a817bb0a9dcf623db1d76bec0759dad6df702313</originalsourceid><addsrcrecordid>eNo9UM9P2zAYjdAmwdiuO_vCMeAfqd1wWpVCmdQNqjJxtL7En1tvbhzZQZD7_nDCOuX0vU_vh55eln1l9JJRyq_ApOaS0xHTUqmT7IxJNssLJssPE57R0-xTSr8pZWqu1Fn29xbFffHtgCl0IYbn1AU_QOu8a_GaLMid2-39QG6sdY3DtifQGvIDdi32rgE_UlvsIELtkVTQgx9ST2yIpIohpbwKz90YtSPBkkUcPKn2PkRnMP0LethjG3z6nH204BN--X_Ps1-3N4_VXb6-X32vFuvcCVGqnIsahW1YIw0WNUU5V8jmIDnMmaprCqVprOTC1MwoWWND1aw0YKSxinLBxHl2ccztII3lbYS2cUl30R0gDpoXgvJC0VFXHnUvzuMw8Yzq96H1-9B6Glovlttq-kZvfvS61OPr5IX4R0sl1Ew__Vzp5WYt-Opho5_EG2LFhcs</addsrcrecordid><sourcetype>Index Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Fe3O4@mesoporouspolyaniline: A Highly Efficient and Magnetically Separable Catalyst for Cross-Coupling of Aryl Chlorides and Phenols</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Arundhathi, R. ; Damodara, D. ; Likhar, Pravin R. ; Kantam, M. Lakshmi ; Saravanan, P. ; Magdaleno, Travis ; Kwon, Sun Hee</creator><creatorcontrib>Arundhathi, R. ; Damodara, D. ; Likhar, Pravin R. ; Kantam, M. Lakshmi ; Saravanan, P. ; Magdaleno, Travis ; Kwon, Sun Hee</creatorcontrib><description>A high surface, magnetic Fe3O4@mesoporouspolyaniline core‐shell nanocomposite was synthesized from magnetic iron oxide (Fe3O4) nanoparticles and mesoporouspolyaniline (mPANI). The novel porous magnetic Fe3O4 was obtained by solvothermal method under sealed pressure reactor at high temperature to achieve high surface area. The mesoporouspolyaniline shell was synthesized by in situ surface polymerization onto porous magnetic Fe3O4 in the presence of polyvinylpyrrolidone (PVP) and sodium dodecylbenzenesulfonate (SDBS), as a linker and structure‐directing agent, through ‘blackberry nanostructures’ assembly. The material composition, stoichiometric ratio and reaction conditions play vital roles in the synthesis of these nanostructures as confirmed by variety of characterization techniques. The role of the mesoporouspolyaniline shell is to stabilize the porous magnetic Fe3O4 nanoparticles, and provide direct access to the core Fe3O4 nanoparticles. The catalytic activity of magnetic Fe3O4@mesoporousPANI nanocomposite was evaluated in the cross‐coupling of aryl chlorides and phenols.</description><identifier>ISSN: 1615-4150</identifier><identifier>EISSN: 1615-4169</identifier><identifier>DOI: 10.1002/adsc.201000977</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>aryl chlorides ; Catalysis ; Catalysts: preparations and properties ; Chemistry ; Exact sciences and technology ; General and physical chemistry ; mesoporous polyaniline ; Noncondensed benzenic compounds ; O-arylation ; Organic chemistry ; phenols ; porous magnetic Fe3O4 ; Preparations and properties ; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><ispartof>Advanced synthesis & catalysis, 2011-06, Vol.353 (9), p.1591-1600</ispartof><rights>Copyright © 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadsc.201000977$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadsc.201000977$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=24302470$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Arundhathi, R.</creatorcontrib><creatorcontrib>Damodara, D.</creatorcontrib><creatorcontrib>Likhar, Pravin R.</creatorcontrib><creatorcontrib>Kantam, M. Lakshmi</creatorcontrib><creatorcontrib>Saravanan, P.</creatorcontrib><creatorcontrib>Magdaleno, Travis</creatorcontrib><creatorcontrib>Kwon, Sun Hee</creatorcontrib><title>Fe3O4@mesoporouspolyaniline: A Highly Efficient and Magnetically Separable Catalyst for Cross-Coupling of Aryl Chlorides and Phenols</title><title>Advanced synthesis & catalysis</title><addtitle>Adv. Synth. Catal</addtitle><description>A high surface, magnetic Fe3O4@mesoporouspolyaniline core‐shell nanocomposite was synthesized from magnetic iron oxide (Fe3O4) nanoparticles and mesoporouspolyaniline (mPANI). The novel porous magnetic Fe3O4 was obtained by solvothermal method under sealed pressure reactor at high temperature to achieve high surface area. The mesoporouspolyaniline shell was synthesized by in situ surface polymerization onto porous magnetic Fe3O4 in the presence of polyvinylpyrrolidone (PVP) and sodium dodecylbenzenesulfonate (SDBS), as a linker and structure‐directing agent, through ‘blackberry nanostructures’ assembly. The material composition, stoichiometric ratio and reaction conditions play vital roles in the synthesis of these nanostructures as confirmed by variety of characterization techniques. The role of the mesoporouspolyaniline shell is to stabilize the porous magnetic Fe3O4 nanoparticles, and provide direct access to the core Fe3O4 nanoparticles. The catalytic activity of magnetic Fe3O4@mesoporousPANI nanocomposite was evaluated in the cross‐coupling of aryl chlorides and phenols.</description><subject>aryl chlorides</subject><subject>Catalysis</subject><subject>Catalysts: preparations and properties</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>mesoporous polyaniline</subject><subject>Noncondensed benzenic compounds</subject><subject>O-arylation</subject><subject>Organic chemistry</subject><subject>phenols</subject><subject>porous magnetic Fe3O4</subject><subject>Preparations and properties</subject><subject>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</subject><issn>1615-4150</issn><issn>1615-4169</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNo9UM9P2zAYjdAmwdiuO_vCMeAfqd1wWpVCmdQNqjJxtL7En1tvbhzZQZD7_nDCOuX0vU_vh55eln1l9JJRyq_ApOaS0xHTUqmT7IxJNssLJssPE57R0-xTSr8pZWqu1Fn29xbFffHtgCl0IYbn1AU_QOu8a_GaLMid2-39QG6sdY3DtifQGvIDdi32rgE_UlvsIELtkVTQgx9ST2yIpIohpbwKz90YtSPBkkUcPKn2PkRnMP0LethjG3z6nH204BN--X_Ps1-3N4_VXb6-X32vFuvcCVGqnIsahW1YIw0WNUU5V8jmIDnMmaprCqVprOTC1MwoWWND1aw0YKSxinLBxHl2ccztII3lbYS2cUl30R0gDpoXgvJC0VFXHnUvzuMw8Yzq96H1-9B6Glovlttq-kZvfvS61OPr5IX4R0sl1Ew__Vzp5WYt-Opho5_EG2LFhcs</recordid><startdate>201106</startdate><enddate>201106</enddate><creator>Arundhathi, R.</creator><creator>Damodara, D.</creator><creator>Likhar, Pravin R.</creator><creator>Kantam, M. Lakshmi</creator><creator>Saravanan, P.</creator><creator>Magdaleno, Travis</creator><creator>Kwon, Sun Hee</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley-VCH</general><scope>BSCLL</scope><scope>IQODW</scope></search><sort><creationdate>201106</creationdate><title>Fe3O4@mesoporouspolyaniline: A Highly Efficient and Magnetically Separable Catalyst for Cross-Coupling of Aryl Chlorides and Phenols</title><author>Arundhathi, R. ; Damodara, D. ; Likhar, Pravin R. ; Kantam, M. Lakshmi ; Saravanan, P. ; Magdaleno, Travis ; Kwon, Sun Hee</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i3397-23be3fc1c6de4b0e687e18a62a817bb0a9dcf623db1d76bec0759dad6df702313</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>aryl chlorides</topic><topic>Catalysis</topic><topic>Catalysts: preparations and properties</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>mesoporous polyaniline</topic><topic>Noncondensed benzenic compounds</topic><topic>O-arylation</topic><topic>Organic chemistry</topic><topic>phenols</topic><topic>porous magnetic Fe3O4</topic><topic>Preparations and properties</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Arundhathi, R.</creatorcontrib><creatorcontrib>Damodara, D.</creatorcontrib><creatorcontrib>Likhar, Pravin R.</creatorcontrib><creatorcontrib>Kantam, M. Lakshmi</creatorcontrib><creatorcontrib>Saravanan, P.</creatorcontrib><creatorcontrib>Magdaleno, Travis</creatorcontrib><creatorcontrib>Kwon, Sun Hee</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><jtitle>Advanced synthesis & catalysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Arundhathi, R.</au><au>Damodara, D.</au><au>Likhar, Pravin R.</au><au>Kantam, M. Lakshmi</au><au>Saravanan, P.</au><au>Magdaleno, Travis</au><au>Kwon, Sun Hee</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fe3O4@mesoporouspolyaniline: A Highly Efficient and Magnetically Separable Catalyst for Cross-Coupling of Aryl Chlorides and Phenols</atitle><jtitle>Advanced synthesis & catalysis</jtitle><addtitle>Adv. Synth. Catal</addtitle><date>2011-06</date><risdate>2011</risdate><volume>353</volume><issue>9</issue><spage>1591</spage><epage>1600</epage><pages>1591-1600</pages><issn>1615-4150</issn><eissn>1615-4169</eissn><abstract>A high surface, magnetic Fe3O4@mesoporouspolyaniline core‐shell nanocomposite was synthesized from magnetic iron oxide (Fe3O4) nanoparticles and mesoporouspolyaniline (mPANI). The novel porous magnetic Fe3O4 was obtained by solvothermal method under sealed pressure reactor at high temperature to achieve high surface area. The mesoporouspolyaniline shell was synthesized by in situ surface polymerization onto porous magnetic Fe3O4 in the presence of polyvinylpyrrolidone (PVP) and sodium dodecylbenzenesulfonate (SDBS), as a linker and structure‐directing agent, through ‘blackberry nanostructures’ assembly. The material composition, stoichiometric ratio and reaction conditions play vital roles in the synthesis of these nanostructures as confirmed by variety of characterization techniques. The role of the mesoporouspolyaniline shell is to stabilize the porous magnetic Fe3O4 nanoparticles, and provide direct access to the core Fe3O4 nanoparticles. The catalytic activity of magnetic Fe3O4@mesoporousPANI nanocomposite was evaluated in the cross‐coupling of aryl chlorides and phenols.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/adsc.201000977</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1615-4150 |
| ispartof | Advanced synthesis & catalysis, 2011-06, Vol.353 (9), p.1591-1600 |
| issn | 1615-4150 1615-4169 |
| language | eng |
| recordid | cdi_pascalfrancis_primary_24302470 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | aryl chlorides Catalysis Catalysts: preparations and properties Chemistry Exact sciences and technology General and physical chemistry mesoporous polyaniline Noncondensed benzenic compounds O-arylation Organic chemistry phenols porous magnetic Fe3O4 Preparations and properties Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | Fe3O4@mesoporouspolyaniline: A Highly Efficient and Magnetically Separable Catalyst for Cross-Coupling of Aryl Chlorides and Phenols |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-05T15%3A12%3A06IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wiley_pasca&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Fe3O4@mesoporouspolyaniline:%20A%20Highly%20Efficient%20and%20Magnetically%20Separable%20Catalyst%20for%20Cross-Coupling%20of%20Aryl%20Chlorides%20and%20Phenols&rft.jtitle=Advanced%20synthesis%20&%20catalysis&rft.au=Arundhathi,%20R.&rft.date=2011-06&rft.volume=353&rft.issue=9&rft.spage=1591&rft.epage=1600&rft.pages=1591-1600&rft.issn=1615-4150&rft.eissn=1615-4169&rft_id=info:doi/10.1002/adsc.201000977&rft_dat=%3Cwiley_pasca%3EADSC201000977%3C/wiley_pasca%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |