Palladium-Catalyzed Synthesis of 2-Fluoroalkyl-3-methylene-3H-indoles Through a Domino Carbopalladation/CH Activation Process

A novel palladium‐catalyzed synthesis of substituted 3‐methylene‐3H‐indoles from readily accessible alkynylimines has been developed. A wide variety of 2‐fluoroalkyl‐3‐methylene‐3H‐indoles were synthesized in moderate to good yields through this cascade carbopalladation/CH activation process. This...

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Veröffentlicht in:	Advanced synthesis & catalysis 2011-02, Vol.353 (2-3), p.325-330
Hauptverfasser:	Chen, Zixian, Zhu, Jiangtao, Xie, Haibo, Li, Shan, Wu, Yongming, Gong, Yuefa
Format:	Artikel
Sprache:	eng
Schlagworte:	cascade reactions Chemistry CH activation Exact sciences and technology fluorine Heterocyclic compounds Heterocyclic compounds with only one n hetero atom and condensed derivatives indoles Organic chemistry palladium Preparations and properties
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