δ-Bonding in the [Pd4(μ4-C9H9)(μ4-C8H8)]+ sandwich complex
A remarkable triple-decker sandwich complex [Pd 4 (μ 4 -C 9 H 9 )(μ 4 -C 8 H 8 )][BAr f 4 ] (BAr f 4 = B{3,5-(CF 3 ) 2 (C 6 H 3 )} 4 ) composed of cyclononatetraenyl anion and cyclooctatetraene as "bread pieces" and square tetrapalladium dication as "meat" ( Fig. 1a ) has been sy...
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| creator | Sergeeva, Alina P Boldyrev, Alexander I |
| description | A remarkable triple-decker sandwich complex [Pd
4
(μ
4
-C
9
H
9
)(μ
4
-C
8
H
8
)][BAr
f
4
] (BAr
f
4
= B{3,5-(CF
3
)
2
(C
6
H
3
)}
4
) composed of cyclononatetraenyl anion and cyclooctatetraene as "bread pieces" and square tetrapalladium dication as "meat" (
Fig. 1a
) has been synthesized recently [Murahashi
et al
.,
J. Am. Chem. Soc.
, 2009,
131
, 9888]. This complex attracted our attention because of the presence of an almost perfect square sheet composed of four palladium atoms. Such a structure could be a sign of aromatic nature of chemical bonding as it was shown to be present in the square Al
4
2−
cluster [Li
et al
.,
Science
, 2001,
291
, 859]. In this work we show that according to our chemical bonding analysis the bonding in the Pd
4
2+
unit of [Pd
4
(μ
4
-C
9
H
9
)(μ
4
-C
8
H
8
)]
+
is of δ-character among four palladium atoms, making the triple-decker sandwich complex the first synthesized compound identified as having δ-bonding in its cyclic building block when it's in solution or in a crystalline state.
For the first time, we discovered delocalized δ-bonding in a condense-phase [Pd
4
(μ
4
-C
9
H
9
)(μ
4
-C
8
H
8
)]
+
triple-decker sandwich complex using the Adaptive Natural Density Partitioning method. |
| doi_str_mv | 10.1039/c0cp00475h |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pasca</sourceid><recordid>TN_cdi_pascalfrancis_primary_23324575</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>755177961</sourcerecordid><originalsourceid>FETCH-LOGICAL-c364t-b9529dca483cfb21295dfff3bd2909bca36acd0008c8f29f98404dd55a7ce3703</originalsourceid><addsrcrecordid>eNp90M1KAzEQB_AgitXqxbuyHkSrrCabZJMcPGhRKxT0oCeRJTtJ7Mp-uWlR38ujz9BncqW1vXmagfkxM_wR2iH4lGCqzgBDjTETfLSCNgiLaaiwZKuLXsQdtOn9K8aYcELXUSfCIuKxZBvofPoVXlalycqXICuD8cgGT_eGHU2_WdhXA9WbdXIge88ngdelec9gFEBV1Ln92EJrTufebs9rFz1eXz30B-Hw7ua2fzEMgcZsHKaKR8qAZpKCSyMSKW6cczQ1kcIqBU1jDaZ9T4J0kXJKMsyM4VwLsFRg2kWHs711U71NrB8nRebB5rkubTXxieCcCKFi0srjmYSm8r6xLqmbrNDNZ0Jw8ptWskyrxXvztZO0sGZB_-JpwcEcaA86d40uIfNLR2nEuOCt25-5xsNiujyU1Ma1Zvc_Q38AIJKF9g</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>755177961</pqid></control><display><type>article</type><title>δ-Bonding in the [Pd4(μ4-C9H9)(μ4-C8H8)]+ sandwich complex</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Sergeeva, Alina P ; Boldyrev, Alexander I</creator><creatorcontrib>Sergeeva, Alina P ; Boldyrev, Alexander I</creatorcontrib><description>A remarkable triple-decker sandwich complex [Pd
4
(μ
4
-C
9
H
9
)(μ
4
-C
8
H
8
)][BAr
f
4
] (BAr
f
4
= B{3,5-(CF
3
)
2
(C
6
H
3
)}
4
) composed of cyclononatetraenyl anion and cyclooctatetraene as "bread pieces" and square tetrapalladium dication as "meat" (
Fig. 1a
) has been synthesized recently [Murahashi
et al
.,
J. Am. Chem. Soc.
, 2009,
131
, 9888]. This complex attracted our attention because of the presence of an almost perfect square sheet composed of four palladium atoms. Such a structure could be a sign of aromatic nature of chemical bonding as it was shown to be present in the square Al
4
2−
cluster [Li
et al
.,
Science
, 2001,
291
, 859]. In this work we show that according to our chemical bonding analysis the bonding in the Pd
4
2+
unit of [Pd
4
(μ
4
-C
9
H
9
)(μ
4
-C
8
H
8
)]
+
is of δ-character among four palladium atoms, making the triple-decker sandwich complex the first synthesized compound identified as having δ-bonding in its cyclic building block when it's in solution or in a crystalline state.
For the first time, we discovered delocalized δ-bonding in a condense-phase [Pd
4
(μ
4
-C
9
H
9
)(μ
4
-C
8
H
8
)]
+
triple-decker sandwich complex using the Adaptive Natural Density Partitioning method.</description><identifier>ISSN: 1463-9076</identifier><identifier>EISSN: 1463-9084</identifier><identifier>DOI: 10.1039/c0cp00475h</identifier><identifier>PMID: 20725684</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Chemistry ; Exact sciences and technology ; General and physical chemistry</subject><ispartof>Physical chemistry chemical physics : PCCP, 2010-10, Vol.12 (38), p.125-1254</ispartof><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c364t-b9529dca483cfb21295dfff3bd2909bca36acd0008c8f29f98404dd55a7ce3703</citedby><cites>FETCH-LOGICAL-c364t-b9529dca483cfb21295dfff3bd2909bca36acd0008c8f29f98404dd55a7ce3703</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=23324575$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/20725684$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Sergeeva, Alina P</creatorcontrib><creatorcontrib>Boldyrev, Alexander I</creatorcontrib><title>δ-Bonding in the [Pd4(μ4-C9H9)(μ4-C8H8)]+ sandwich complex</title><title>Physical chemistry chemical physics : PCCP</title><addtitle>Phys Chem Chem Phys</addtitle><description>A remarkable triple-decker sandwich complex [Pd
4
(μ
4
-C
9
H
9
)(μ
4
-C
8
H
8
)][BAr
f
4
] (BAr
f
4
= B{3,5-(CF
3
)
2
(C
6
H
3
)}
4
) composed of cyclononatetraenyl anion and cyclooctatetraene as "bread pieces" and square tetrapalladium dication as "meat" (
Fig. 1a
) has been synthesized recently [Murahashi
et al
.,
J. Am. Chem. Soc.
, 2009,
131
, 9888]. This complex attracted our attention because of the presence of an almost perfect square sheet composed of four palladium atoms. Such a structure could be a sign of aromatic nature of chemical bonding as it was shown to be present in the square Al
4
2−
cluster [Li
et al
.,
Science
, 2001,
291
, 859]. In this work we show that according to our chemical bonding analysis the bonding in the Pd
4
2+
unit of [Pd
4
(μ
4
-C
9
H
9
)(μ
4
-C
8
H
8
)]
+
is of δ-character among four palladium atoms, making the triple-decker sandwich complex the first synthesized compound identified as having δ-bonding in its cyclic building block when it's in solution or in a crystalline state.
For the first time, we discovered delocalized δ-bonding in a condense-phase [Pd
4
(μ
4
-C
9
H
9
)(μ
4
-C
8
H
8
)]
+
triple-decker sandwich complex using the Adaptive Natural Density Partitioning method.</description><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><issn>1463-9076</issn><issn>1463-9084</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNp90M1KAzEQB_AgitXqxbuyHkSrrCabZJMcPGhRKxT0oCeRJTtJ7Mp-uWlR38ujz9BncqW1vXmagfkxM_wR2iH4lGCqzgBDjTETfLSCNgiLaaiwZKuLXsQdtOn9K8aYcELXUSfCIuKxZBvofPoVXlalycqXICuD8cgGT_eGHU2_WdhXA9WbdXIge88ngdelec9gFEBV1Ln92EJrTufebs9rFz1eXz30B-Hw7ua2fzEMgcZsHKaKR8qAZpKCSyMSKW6cczQ1kcIqBU1jDaZ9T4J0kXJKMsyM4VwLsFRg2kWHs711U71NrB8nRebB5rkubTXxieCcCKFi0srjmYSm8r6xLqmbrNDNZ0Jw8ptWskyrxXvztZO0sGZB_-JpwcEcaA86d40uIfNLR2nEuOCt25-5xsNiujyU1Ma1Zvc_Q38AIJKF9g</recordid><startdate>20101014</startdate><enddate>20101014</enddate><creator>Sergeeva, Alina P</creator><creator>Boldyrev, Alexander I</creator><general>Royal Society of Chemistry</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20101014</creationdate><title>δ-Bonding in the [Pd4(μ4-C9H9)(μ4-C8H8)]+ sandwich complex</title><author>Sergeeva, Alina P ; Boldyrev, Alexander I</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c364t-b9529dca483cfb21295dfff3bd2909bca36acd0008c8f29f98404dd55a7ce3703</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sergeeva, Alina P</creatorcontrib><creatorcontrib>Boldyrev, Alexander I</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Physical chemistry chemical physics : PCCP</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sergeeva, Alina P</au><au>Boldyrev, Alexander I</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>δ-Bonding in the [Pd4(μ4-C9H9)(μ4-C8H8)]+ sandwich complex</atitle><jtitle>Physical chemistry chemical physics : PCCP</jtitle><addtitle>Phys Chem Chem Phys</addtitle><date>2010-10-14</date><risdate>2010</risdate><volume>12</volume><issue>38</issue><spage>125</spage><epage>1254</epage><pages>125-1254</pages><issn>1463-9076</issn><eissn>1463-9084</eissn><abstract>A remarkable triple-decker sandwich complex [Pd
4
(μ
4
-C
9
H
9
)(μ
4
-C
8
H
8
)][BAr
f
4
] (BAr
f
4
= B{3,5-(CF
3
)
2
(C
6
H
3
)}
4
) composed of cyclononatetraenyl anion and cyclooctatetraene as "bread pieces" and square tetrapalladium dication as "meat" (
Fig. 1a
) has been synthesized recently [Murahashi
et al
.,
J. Am. Chem. Soc.
, 2009,
131
, 9888]. This complex attracted our attention because of the presence of an almost perfect square sheet composed of four palladium atoms. Such a structure could be a sign of aromatic nature of chemical bonding as it was shown to be present in the square Al
4
2−
cluster [Li
et al
.,
Science
, 2001,
291
, 859]. In this work we show that according to our chemical bonding analysis the bonding in the Pd
4
2+
unit of [Pd
4
(μ
4
-C
9
H
9
)(μ
4
-C
8
H
8
)]
+
is of δ-character among four palladium atoms, making the triple-decker sandwich complex the first synthesized compound identified as having δ-bonding in its cyclic building block when it's in solution or in a crystalline state.
For the first time, we discovered delocalized δ-bonding in a condense-phase [Pd
4
(μ
4
-C
9
H
9
)(μ
4
-C
8
H
8
)]
+
triple-decker sandwich complex using the Adaptive Natural Density Partitioning method.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><pmid>20725684</pmid><doi>10.1039/c0cp00475h</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1463-9076 |
| ispartof | Physical chemistry chemical physics : PCCP, 2010-10, Vol.12 (38), p.125-1254 |
| issn | 1463-9076 1463-9084 |
| language | eng |
| recordid | cdi_pascalfrancis_primary_23324575 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Chemistry Exact sciences and technology General and physical chemistry |
| title | δ-Bonding in the [Pd4(μ4-C9H9)(μ4-C8H8)]+ sandwich complex |
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