Isothermal vapour–liquid equilibria for 1,2-dichloroethane + nitromethane and + nitroethane binary systems at temperatures between 333.15 and 353.15 K
Isothermal vapour–liquid equilibrium (VLE) data are reported at three temperatures, 333.15, 343.15 and 353.15 K, for binary mixtures containing 1,2-dichloroethane with nitromethane or nitroethane. Use has been made of an ebulliometer which allows sampling from both phases in equilibrium. The experim...
Gespeichert in:
| Veröffentlicht in: | Fluid phase equilibria 2010-05, Vol.292 (1), p.58-63 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 63 |
|---|---|
| container_issue | 1 |
| container_start_page | 58 |
| container_title | Fluid phase equilibria |
| container_volume | 292 |
| creator | Teodorescu, Mariana Barhala, Alexandru Dragoescu, Dana |
| description | Isothermal vapour–liquid equilibrium (VLE) data are reported at three temperatures, 333.15, 343.15 and 353.15
K, for binary mixtures containing 1,2-dichloroethane with nitromethane or nitroethane. Use has been made of an ebulliometer which allows sampling from both phases in equilibrium. The experimental data were correlated using the Redlich–Kister, Wilson, NRTL and UNIQUAC excess Gibbs energy models by means of the maximum likelihood method, taking into account the vapour phase imperfection in terms of the second virial coefficients. Both systems are zeotropic and show positive deviations from ideal behaviour. The experimental VLE data are analysed in terms of the Modified UNIFAC (Do) model. |
| doi_str_mv | 10.1016/j.fluid.2010.01.024 |
| format | Article |
| fullrecord | <record><control><sourceid>elsevier_pasca</sourceid><recordid>TN_cdi_pascalfrancis_primary_22757719</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0378381210000506</els_id><sourcerecordid>S0378381210000506</sourcerecordid><originalsourceid>FETCH-LOGICAL-e154t-7e084759e4a29fb34478f4fcbe72849d2f71d62ae66c83b28c9b3b0ad547b4663</originalsourceid><addsrcrecordid>eNo1UbtOAzEQtBBIhMAX0Lihgjv8uvNdQYEiHhGRaKC2bN-e4ugewXaC0vEPNHwfX8LlQbOzO5odjTQIXVKSUkLz20VaNytXpYwMDKEpYeIIjWghy4QwJo7RiHBZJLyg7BSdhbAghNAsZyP0Mw19nINvdYPXetmv_O_Xd-M-BjcMw2yc8U7juveY3rCkcnbe9L6HONcd4Gvcuej79nDqrvqnDoxxnfYbHDYhQhuwjnjAJXgdVx4CNhA_ATrMOU9ptvvn2W59OUcntW4CXBxwjN4fH94mz8ns9Wk6uZ8lQDMREwmkEDIrQWhW1oYLIYta1NaAZIUoK1ZLWuVMQ57bghtW2NJwQ3SVCWlEnvMxutr7LnWwuqm97qwLauldOyRXjMlMSloOuru9DoYwawdeBeugs1A5DzaqqneKErWtQy3Urg61rUMRqoY6-B_TmYGv</addsrcrecordid><sourcetype>Index Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Isothermal vapour–liquid equilibria for 1,2-dichloroethane + nitromethane and + nitroethane binary systems at temperatures between 333.15 and 353.15 K</title><source>ScienceDirect Journals (5 years ago - present)</source><creator>Teodorescu, Mariana ; Barhala, Alexandru ; Dragoescu, Dana</creator><creatorcontrib>Teodorescu, Mariana ; Barhala, Alexandru ; Dragoescu, Dana</creatorcontrib><description>Isothermal vapour–liquid equilibrium (VLE) data are reported at three temperatures, 333.15, 343.15 and 353.15
K, for binary mixtures containing 1,2-dichloroethane with nitromethane or nitroethane. Use has been made of an ebulliometer which allows sampling from both phases in equilibrium. The experimental data were correlated using the Redlich–Kister, Wilson, NRTL and UNIQUAC excess Gibbs energy models by means of the maximum likelihood method, taking into account the vapour phase imperfection in terms of the second virial coefficients. Both systems are zeotropic and show positive deviations from ideal behaviour. The experimental VLE data are analysed in terms of the Modified UNIFAC (Do) model.</description><identifier>ISSN: 0378-3812</identifier><identifier>EISSN: 1879-0224</identifier><identifier>DOI: 10.1016/j.fluid.2010.01.024</identifier><identifier>CODEN: FPEQDT</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>1,2-Dichloroethane ; Chemistry ; Exact sciences and technology ; General and physical chemistry ; Liquid-vapor equilibria ; Low pressure VLE ; Modified UNIFAC (Do) model ; Nitroethane ; Nitromethane ; Phase equilibria</subject><ispartof>Fluid phase equilibria, 2010-05, Vol.292 (1), p.58-63</ispartof><rights>2010 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.fluid.2010.01.024$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3548,27923,27924,45994</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22757719$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Teodorescu, Mariana</creatorcontrib><creatorcontrib>Barhala, Alexandru</creatorcontrib><creatorcontrib>Dragoescu, Dana</creatorcontrib><title>Isothermal vapour–liquid equilibria for 1,2-dichloroethane + nitromethane and + nitroethane binary systems at temperatures between 333.15 and 353.15 K</title><title>Fluid phase equilibria</title><description>Isothermal vapour–liquid equilibrium (VLE) data are reported at three temperatures, 333.15, 343.15 and 353.15
K, for binary mixtures containing 1,2-dichloroethane with nitromethane or nitroethane. Use has been made of an ebulliometer which allows sampling from both phases in equilibrium. The experimental data were correlated using the Redlich–Kister, Wilson, NRTL and UNIQUAC excess Gibbs energy models by means of the maximum likelihood method, taking into account the vapour phase imperfection in terms of the second virial coefficients. Both systems are zeotropic and show positive deviations from ideal behaviour. The experimental VLE data are analysed in terms of the Modified UNIFAC (Do) model.</description><subject>1,2-Dichloroethane</subject><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Liquid-vapor equilibria</subject><subject>Low pressure VLE</subject><subject>Modified UNIFAC (Do) model</subject><subject>Nitroethane</subject><subject>Nitromethane</subject><subject>Phase equilibria</subject><issn>0378-3812</issn><issn>1879-0224</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNo1UbtOAzEQtBBIhMAX0Lihgjv8uvNdQYEiHhGRaKC2bN-e4ugewXaC0vEPNHwfX8LlQbOzO5odjTQIXVKSUkLz20VaNytXpYwMDKEpYeIIjWghy4QwJo7RiHBZJLyg7BSdhbAghNAsZyP0Mw19nINvdYPXetmv_O_Xd-M-BjcMw2yc8U7juveY3rCkcnbe9L6HONcd4Gvcuej79nDqrvqnDoxxnfYbHDYhQhuwjnjAJXgdVx4CNhA_ATrMOU9ptvvn2W59OUcntW4CXBxwjN4fH94mz8ns9Wk6uZ8lQDMREwmkEDIrQWhW1oYLIYta1NaAZIUoK1ZLWuVMQ57bghtW2NJwQ3SVCWlEnvMxutr7LnWwuqm97qwLauldOyRXjMlMSloOuru9DoYwawdeBeugs1A5DzaqqneKErWtQy3Urg61rUMRqoY6-B_TmYGv</recordid><startdate>20100525</startdate><enddate>20100525</enddate><creator>Teodorescu, Mariana</creator><creator>Barhala, Alexandru</creator><creator>Dragoescu, Dana</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope></search><sort><creationdate>20100525</creationdate><title>Isothermal vapour–liquid equilibria for 1,2-dichloroethane + nitromethane and + nitroethane binary systems at temperatures between 333.15 and 353.15 K</title><author>Teodorescu, Mariana ; Barhala, Alexandru ; Dragoescu, Dana</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-e154t-7e084759e4a29fb34478f4fcbe72849d2f71d62ae66c83b28c9b3b0ad547b4663</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>1,2-Dichloroethane</topic><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>Liquid-vapor equilibria</topic><topic>Low pressure VLE</topic><topic>Modified UNIFAC (Do) model</topic><topic>Nitroethane</topic><topic>Nitromethane</topic><topic>Phase equilibria</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Teodorescu, Mariana</creatorcontrib><creatorcontrib>Barhala, Alexandru</creatorcontrib><creatorcontrib>Dragoescu, Dana</creatorcontrib><collection>Pascal-Francis</collection><jtitle>Fluid phase equilibria</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Teodorescu, Mariana</au><au>Barhala, Alexandru</au><au>Dragoescu, Dana</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Isothermal vapour–liquid equilibria for 1,2-dichloroethane + nitromethane and + nitroethane binary systems at temperatures between 333.15 and 353.15 K</atitle><jtitle>Fluid phase equilibria</jtitle><date>2010-05-25</date><risdate>2010</risdate><volume>292</volume><issue>1</issue><spage>58</spage><epage>63</epage><pages>58-63</pages><issn>0378-3812</issn><eissn>1879-0224</eissn><coden>FPEQDT</coden><abstract>Isothermal vapour–liquid equilibrium (VLE) data are reported at three temperatures, 333.15, 343.15 and 353.15
K, for binary mixtures containing 1,2-dichloroethane with nitromethane or nitroethane. Use has been made of an ebulliometer which allows sampling from both phases in equilibrium. The experimental data were correlated using the Redlich–Kister, Wilson, NRTL and UNIQUAC excess Gibbs energy models by means of the maximum likelihood method, taking into account the vapour phase imperfection in terms of the second virial coefficients. Both systems are zeotropic and show positive deviations from ideal behaviour. The experimental VLE data are analysed in terms of the Modified UNIFAC (Do) model.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.fluid.2010.01.024</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0378-3812 |
| ispartof | Fluid phase equilibria, 2010-05, Vol.292 (1), p.58-63 |
| issn | 0378-3812 1879-0224 |
| language | eng |
| recordid | cdi_pascalfrancis_primary_22757719 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | 1,2-Dichloroethane Chemistry Exact sciences and technology General and physical chemistry Liquid-vapor equilibria Low pressure VLE Modified UNIFAC (Do) model Nitroethane Nitromethane Phase equilibria |
| title | Isothermal vapour–liquid equilibria for 1,2-dichloroethane + nitromethane and + nitroethane binary systems at temperatures between 333.15 and 353.15 K |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-11T17%3A03%3A52IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-elsevier_pasca&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Isothermal%20vapour%E2%80%93liquid%20equilibria%20for%201,2-dichloroethane%20+%20nitromethane%20and%20+%20nitroethane%20binary%20systems%20at%20temperatures%20between%20333.15%20and%20353.15%20K&rft.jtitle=Fluid%20phase%20equilibria&rft.au=Teodorescu,%20Mariana&rft.date=2010-05-25&rft.volume=292&rft.issue=1&rft.spage=58&rft.epage=63&rft.pages=58-63&rft.issn=0378-3812&rft.eissn=1879-0224&rft.coden=FPEQDT&rft_id=info:doi/10.1016/j.fluid.2010.01.024&rft_dat=%3Celsevier_pasca%3ES0378381210000506%3C/elsevier_pasca%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rft_els_id=S0378381210000506&rfr_iscdi=true |