Copolymerization of ethyl α-(hydroxymethyl)acrylate with maleimide and characterization of the resulting copolymer
Copolymerization of maleimide (MI) and ethyl α‐(hydroxymethyl)acrylate (EHMA) was performed at 60°C with AIBN as the initiator in THF. The monomer reactivity ratios were determined as r1 (MI) = 0.13 and r2 (EHMA) = 2.20. As the molar fraction of MI in the monomer feed increased, the initial rate of...
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| Veröffentlicht in: | Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 1998-06, Vol.36 (8), p.1291-1299 |
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| container_end_page | 1299 |
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| container_issue | 8 |
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| container_title | Journal of polymer science. Part A, Polymer chemistry |
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| creator | Jia, Xinqiao Pang, Yanwan Huang, Junlian |
| description | Copolymerization of maleimide (MI) and ethyl α‐(hydroxymethyl)acrylate (EHMA) was performed at 60°C with AIBN as the initiator in THF. The monomer reactivity ratios were determined as r1 (MI) = 0.13 and r2 (EHMA) = 2.20. As the molar fraction of MI in the monomer feed increased, the initial rate of copolymerization decreased. TGA diagrams suggested the crosslinking reaction of the copolymer on heating. DSC and WAXD results suggested the existence of incomplete crystallinity in the copolymer. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 1291–1299, 1998 |
| doi_str_mv | 10.1002/(SICI)1099-0518(199806)36:8<1291::AID-POLA12>3.0.CO;2-1 |
| format | Article |
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The monomer reactivity ratios were determined as r1 (MI) = 0.13 and r2 (EHMA) = 2.20. As the molar fraction of MI in the monomer feed increased, the initial rate of copolymerization decreased. TGA diagrams suggested the crosslinking reaction of the copolymer on heating. DSC and WAXD results suggested the existence of incomplete crystallinity in the copolymer. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 1291–1299, 1998</description><identifier>ISSN: 0887-624X</identifier><identifier>EISSN: 1099-0518</identifier><identifier>DOI: 10.1002/(SICI)1099-0518(199806)36:8<1291::AID-POLA12>3.0.CO;2-1</identifier><identifier>CODEN: JPLCAT</identifier><language>eng</language><publisher>New York: John Wiley & Sons, Inc</publisher><subject>Applied sciences ; characterization ; Copolymerization ; ethyl α-(hydroxymethyl)acrylate ; Exact sciences and technology ; incomplete crystallinity ; maleimide ; Organic polymers ; Physicochemistry of polymers ; Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><ispartof>Journal of polymer science. 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Part A, Polymer chemistry</title><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><description>Copolymerization of maleimide (MI) and ethyl α‐(hydroxymethyl)acrylate (EHMA) was performed at 60°C with AIBN as the initiator in THF. The monomer reactivity ratios were determined as r1 (MI) = 0.13 and r2 (EHMA) = 2.20. As the molar fraction of MI in the monomer feed increased, the initial rate of copolymerization decreased. TGA diagrams suggested the crosslinking reaction of the copolymer on heating. DSC and WAXD results suggested the existence of incomplete crystallinity in the copolymer. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 1291–1299, 1998</description><subject>Applied sciences</subject><subject>characterization</subject><subject>Copolymerization</subject><subject>ethyl α-(hydroxymethyl)acrylate</subject><subject>Exact sciences and technology</subject><subject>incomplete crystallinity</subject><subject>maleimide</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><issn>0887-624X</issn><issn>1099-0518</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNpVkM-O0zAQhy0EEmXhHXzg0B5cZuzESQoCVWEpFWULWv6eRm7iEC9pUzlZ7Ya34kV4JhJlqcRprPnNfCN_jL1CmCOAfDa9XKfrGUKSCAgxnmKSxKBnSi_iFygTXCyW69fiw3azRPlSzWGebp9LgffY5LRzn00gjiOhZfDtIXvUNFcAfRbGE9ak9bGuur317pdpXX3gdcFtW3YV__NbTMsu9_VtHw-dmcl8V5nW8hvXlnxvKuv2LrfcHHKelcabrP2P05aWe9tcV607_ODZv0uP2YPCVI19clfP2Oc355_St2KzXa3T5UY4BVKKXW6DQEWgC7CgUAcYxFn_BavABJk2oJW2YWgNYhEFQR7udgpB7bRUudWJVWfs6cg9miYzVeHNIXMNHb3bG9-RlIhhIvux7-PYjatsd4oRaPBPg34aVNKgkkb9pDT1714_9fZptE-KgNItScK7Ts8WI9s1rb09sY3_STpSUUhfL1Z0kV5-ebf5uKL36i9ItJKc</recordid><startdate>199806</startdate><enddate>199806</enddate><creator>Jia, Xinqiao</creator><creator>Pang, Yanwan</creator><creator>Huang, Junlian</creator><general>John Wiley & Sons, Inc</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope></search><sort><creationdate>199806</creationdate><title>Copolymerization of ethyl α-(hydroxymethyl)acrylate with maleimide and characterization of the resulting copolymer</title><author>Jia, Xinqiao ; Pang, Yanwan ; Huang, Junlian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i3022-bde443706f0e03164148c624e30a4c6a0636e55ea11f744d5bb3103b623de69e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>Applied sciences</topic><topic>characterization</topic><topic>Copolymerization</topic><topic>ethyl α-(hydroxymethyl)acrylate</topic><topic>Exact sciences and technology</topic><topic>incomplete crystallinity</topic><topic>maleimide</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><toplevel>online_resources</toplevel><creatorcontrib>Jia, Xinqiao</creatorcontrib><creatorcontrib>Pang, Yanwan</creatorcontrib><creatorcontrib>Huang, Junlian</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jia, Xinqiao</au><au>Pang, Yanwan</au><au>Huang, Junlian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Copolymerization of ethyl α-(hydroxymethyl)acrylate with maleimide and characterization of the resulting copolymer</atitle><jtitle>Journal of polymer science. Part A, Polymer chemistry</jtitle><addtitle>J. Polym. Sci. A Polym. Chem</addtitle><date>1998-06</date><risdate>1998</risdate><volume>36</volume><issue>8</issue><spage>1291</spage><epage>1299</epage><pages>1291-1299</pages><issn>0887-624X</issn><eissn>1099-0518</eissn><coden>JPLCAT</coden><abstract>Copolymerization of maleimide (MI) and ethyl α‐(hydroxymethyl)acrylate (EHMA) was performed at 60°C with AIBN as the initiator in THF. The monomer reactivity ratios were determined as r1 (MI) = 0.13 and r2 (EHMA) = 2.20. As the molar fraction of MI in the monomer feed increased, the initial rate of copolymerization decreased. TGA diagrams suggested the crosslinking reaction of the copolymer on heating. DSC and WAXD results suggested the existence of incomplete crystallinity in the copolymer. © 1998 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 36: 1291–1299, 1998</abstract><cop>New York</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/(SICI)1099-0518(199806)36:8<1291::AID-POLA12>3.0.CO;2-1</doi><tpages>9</tpages></addata></record> |
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| ispartof | Journal of polymer science. Part A, Polymer chemistry, 1998-06, Vol.36 (8), p.1291-1299 |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Applied sciences characterization Copolymerization ethyl α-(hydroxymethyl)acrylate Exact sciences and technology incomplete crystallinity maleimide Organic polymers Physicochemistry of polymers Preparation, kinetics, thermodynamics, mechanism and catalysts |
| title | Copolymerization of ethyl α-(hydroxymethyl)acrylate with maleimide and characterization of the resulting copolymer |
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