Adhesion behavior of PDMS-containing polyimide to glass

The effect of the incorporation of poly(dimethyl siloxane) (PDMS) segments into a poly[N,N'-(p,p'-oxydiphenylene) pyromellitimide] (PMDA-ODA) polyimide backbone on the adhesion between PMDA-ODA polyimide and glass was investigated using X-ray photoelectron spectroscopy (XPS), infrared (IR)...

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Veröffentlicht in:Journal of adhesion science and technology 1998-01, Vol.12 (3), p.253-269
Hauptverfasser: Cho, Kilwon, Lee, Daeho, Tae Oan Ahn, Kyung Hoon Seo, Han Mo Jeong
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container_end_page 269
container_issue 3
container_start_page 253
container_title Journal of adhesion science and technology
container_volume 12
creator Cho, Kilwon
Lee, Daeho
Tae Oan Ahn
Kyung Hoon Seo
Han Mo Jeong
description The effect of the incorporation of poly(dimethyl siloxane) (PDMS) segments into a poly[N,N'-(p,p'-oxydiphenylene) pyromellitimide] (PMDA-ODA) polyimide backbone on the adhesion between PMDA-ODA polyimide and glass was investigated using X-ray photoelectron spectroscopy (XPS), infrared (IR) spectroscopy, contact angle measurements, and the peel test. The peel energy of PMDA-ODA polyimide to glass was significantly improved when low molecular weight PDMS (248.5 g/mol) was incorporated, while little improvement was observed for the incorporation of high molecular weight PDMS (900 or 1680 g/mol). Exposure to air resulted in a considerable deterioration in the peel energy for the pure PMDA-ODA polyimide, while no deterioration was observed for the PDMS-containing polyimides. The improvement in peel strength was successfully achieved by the incorporation of very small quantities of PDMS such as 2 wt%. Based on XPS, IR spectroscopy, and contact angle measurements, it is suggested that the incorporated PDMS segments migrated from the bulk polyimide to the polyimide/glass interface and chemically bonded to the glass surface, which resulted in enhancement of the peel energy. However, a weak boundary layer was formed between the bulk polyimide and glass when a high molecular weight PDMS (900 or 1680 g/mol) was incorporated and thus the peel energy deteriorated.
doi_str_mv 10.1163/156856198X00867
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1568-5616
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source Taylor & Francis Journals Complete
subjects adhesion
Applied sciences
Exact sciences and technology
glass substrate
interface
peel strength
Physical properties
Polyimide
Polymer industry, paints, wood
Properties and testing
silicon
Surface properties
Technology of polymers
title Adhesion behavior of PDMS-containing polyimide to glass
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