Bulk heterojunction photovoltaic cells based on vacuum evaporated cadmium sulfide–phthalocyanine hybrid structures
Bulk heterojunction (BHJ) photovoltaic (PV) cells have been prepared by vacuum co-deposition of inorganic cadmium sulfide (CdS) and organic zinc phthalocyanine (PcZn) materials. Characteristics of the BHJ cells were compared with the cells based on vacuum evaporated bilayer CdS/PcZn heterojunctions,...
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Veröffentlicht in: | Journal of physics. D, Applied physics Applied physics, 2009-10, Vol.42 (19), p.195104-195104 (8) |
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container_title | Journal of physics. D, Applied physics |
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creator | Grynko, D O Kislyuk, V V Smertenko, P S Dimitriev, O P |
description | Bulk heterojunction (BHJ) photovoltaic (PV) cells have been prepared by vacuum co-deposition of inorganic cadmium sulfide (CdS) and organic zinc phthalocyanine (PcZn) materials. Characteristics of the BHJ cells were compared with the cells based on vacuum evaporated bilayer CdS/PcZn heterojunctions, and it was found that the BHJ structure possesses higher PV performance due to higher interface area at which excitons can dissociate. Variation of the component ratio in the BHJ devices and comparison of their photocurrent spectra allowed us to distinguish the contribution of CdS, CdS/PcZn interface and PcZn to the PV response. The mechanism of charge transport was attributed to the model of space-charge-limited current with traps; however, the concentration of traps was different in the bilayer and BHJ structures. |
doi_str_mv | 10.1088/0022-3727/42/19/195104 |
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D, Applied physics</title><description>Bulk heterojunction (BHJ) photovoltaic (PV) cells have been prepared by vacuum co-deposition of inorganic cadmium sulfide (CdS) and organic zinc phthalocyanine (PcZn) materials. Characteristics of the BHJ cells were compared with the cells based on vacuum evaporated bilayer CdS/PcZn heterojunctions, and it was found that the BHJ structure possesses higher PV performance due to higher interface area at which excitons can dissociate. Variation of the component ratio in the BHJ devices and comparison of their photocurrent spectra allowed us to distinguish the contribution of CdS, CdS/PcZn interface and PcZn to the PV response. The mechanism of charge transport was attributed to the model of space-charge-limited current with traps; however, the concentration of traps was different in the bilayer and BHJ structures.</description><subject>Applied sciences</subject><subject>Energy</subject><subject>Exact sciences and technology</subject><subject>Natural energy</subject><subject>Photovoltaic conversion</subject><subject>Solar cells. 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subjects | Applied sciences Energy Exact sciences and technology Natural energy Photovoltaic conversion Solar cells. Photoelectrochemical cells Solar energy |
title | Bulk heterojunction photovoltaic cells based on vacuum evaporated cadmium sulfide–phthalocyanine hybrid structures |
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