Effect of substituents on amine N-oxides on the rates of O-atom transfer to metal carbonyls

The kinetics of CO substitution in Cr(CO) 6 to afford Cr(CO) 5PPh 3 in the presence of different alkyl amine N-oxides, R 3NO, and aryl amine N-oxides ( p-X-C 6H 4)(CH 3) 2NO, are reported. Within each type of amine N-oxide. the rates of reaction increase with increasing basicity of the amine N-oxide...

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Veröffentlicht in:	Journal of organometallic chemistry 1991-01, Vol.401 (3), p.295-303
Hauptverfasser:	Shen, Jian-Kun, Gao, Yi-Ci, Shi, Qi-Zhen, Basolo, Fred
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Inorganic chemistry and origins of life Kinetics and mechanism of reactions
Online-Zugang:	Volltext
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