Some reactions of ferrocenyl phosphines with M3(CO)12 (M = Fe, Ru). The structures of Ru3(CO)11(PFcPh2) and Ru3(CO)10{(PPh2-η-C5H4)2Fe}
Substitution reactions of M 3 (CO) 12 (M = Fe, Ru) and Ru 4 ((μ-H) 4 (CO) 12 involving a range of ferrocenyl phosphines are described. Compounds isolated and characterized include Fe 3 (CO) 11 PFcPh 2 , Fe 3 (CO) 10 (PBuFcPh) 2 , Fe(CO) 4 L (L = PFc 2 Ph, PFc 3 ), Ru 3 (CO) 11 L (L = PFc 3 , PFc 2 P...
Gespeichert in:
| Veröffentlicht in: | Canadian journal of chemistry 1990-11, Vol.68 (11), p.2001-2010 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 2010 |
|---|---|
| container_issue | 11 |
| container_start_page | 2001 |
| container_title | Canadian journal of chemistry |
| container_volume | 68 |
| creator | Chacon, Stephanie T Cullen, William R Bruce, Michael I Shawkataly, Omar Bin Einstein, Frederick W. B Jones, Richard H Willis, Anthony C |
| description | Substitution reactions of M
3
(CO)
12
(M = Fe, Ru) and Ru
4
((μ-H)
4
(CO)
12
involving a range of ferrocenyl phosphines are described. Compounds isolated and characterized include Fe
3
(CO)
11
PFcPh
2
, Fe
3
(CO)
10
(PBuFcPh)
2
, Fe(CO)
4
L (L = PFc
2
Ph, PFc
3
), Ru
3
(CO)
11
L (L = PFc
3
, PFc
2
Ph, PFcPh
2
), Ru
3
(CO)
10
L
2
(L = PFc
2
Ph, PFcPh
2
), and Ru(CO)
4
PFc
3
. Ru
4
((μ-H)
4
(CO)
10
(LL) and Ru
3
(CO)
10
(LL) result from reactions with LL = (Ph
2
PC
5
H
4
)
2
Fe. The structure of two derivatives are described. Crystals of Ru
3
(CO)
11
(PFcPh
2
) are triclinic, space group P-1, a = 8.576(1), b = 11.150(2), c = 9.160(3) Å, α = 76.65(1), β = 80.75(1), γ = 72.02(1)°, Z = 2, final R
W
= 0.027 from 3144 observed reflections. Ru
3
(CO)
10
(Ph2PC
5
H
4
)
2
Fc, monoclinic crystals, space group C 2/c, a = 17.005(2), b = 18.411(1), c = 14.961(1) Å, β = 117.112(8)°, Z = 4, final R
W
= 0.023 from 2395 observed reflections. Keywords: ferrocenylphosphines, ruthenium carbonyl derivatives, structures, synthesis, iron carbonyl derivatives. |
| doi_str_mv | 10.1139/v90-307 |
| format | Article |
| fullrecord | <record><control><sourceid>pascalfrancis_nrcre</sourceid><recordid>TN_cdi_pascalfrancis_primary_19461523</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>19461523</sourcerecordid><originalsourceid>FETCH-LOGICAL-n1297-b4767dbed924d38d7dc2fabd135ae48eb535feeca2057e9b7bbcd0e1a2d70b313</originalsourceid><addsrcrecordid>eNp1kc1Kw0AQxxdRsFbxFfaiNGLqfiTd5uBBgrFCS0ut57DZnZBITcJuqxQRxLPv41v4ED6Jq9XePAzzwW_-MP9B6JCSLqU8OnuIiM-J2EItGvRdySK6jVqEkL4fkIDtoj1r71wrCAtb6O2mvgdsQKpFWVcW1znOwZhaQbWa46aobVOUFVj8WC4KPOKdeOxRhjujz5fXcxcJnOLp0uviWQHYLsxSLZYGfnSmyzVNO5NETQrmYVnpzZQ8dSZu6H-8-3E4CDyWwPM-2snl3MLBb26j2-RyFg_84fjqOr4Y-hVlkfCzQPSEzkBHLNC8r4VWLJeZpjyUEPQhC3mYAyjJSCggykSWKU2ASqYFyTjlbXS01m2kVXKeG1mp0qaNKe-lWaU0Cno0ZNxxx2uuMsodBdKoYkM5n1Pnc9ro3IEn_4OUpN-P-VvgX4Xffns</addsrcrecordid><sourcetype>Index Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Some reactions of ferrocenyl phosphines with M3(CO)12 (M = Fe, Ru). The structures of Ru3(CO)11(PFcPh2) and Ru3(CO)10{(PPh2-η-C5H4)2Fe}</title><source>NRC Research Press</source><source>EZB-FREE-00999 freely available EZB journals</source><source>Free Full-Text Journals in Chemistry</source><creator>Chacon, Stephanie T ; Cullen, William R ; Bruce, Michael I ; Shawkataly, Omar Bin ; Einstein, Frederick W. B ; Jones, Richard H ; Willis, Anthony C</creator><creatorcontrib>Chacon, Stephanie T ; Cullen, William R ; Bruce, Michael I ; Shawkataly, Omar Bin ; Einstein, Frederick W. B ; Jones, Richard H ; Willis, Anthony C</creatorcontrib><description>Substitution reactions of M
3
(CO)
12
(M = Fe, Ru) and Ru
4
((μ-H)
4
(CO)
12
involving a range of ferrocenyl phosphines are described. Compounds isolated and characterized include Fe
3
(CO)
11
PFcPh
2
, Fe
3
(CO)
10
(PBuFcPh)
2
, Fe(CO)
4
L (L = PFc
2
Ph, PFc
3
), Ru
3
(CO)
11
L (L = PFc
3
, PFc
2
Ph, PFcPh
2
), Ru
3
(CO)
10
L
2
(L = PFc
2
Ph, PFcPh
2
), and Ru(CO)
4
PFc
3
. Ru
4
((μ-H)
4
(CO)
10
(LL) and Ru
3
(CO)
10
(LL) result from reactions with LL = (Ph
2
PC
5
H
4
)
2
Fe. The structure of two derivatives are described. Crystals of Ru
3
(CO)
11
(PFcPh
2
) are triclinic, space group P-1, a = 8.576(1), b = 11.150(2), c = 9.160(3) Å, α = 76.65(1), β = 80.75(1), γ = 72.02(1)°, Z = 2, final R
W
= 0.027 from 3144 observed reflections. Ru
3
(CO)
10
(Ph2PC
5
H
4
)
2
Fc, monoclinic crystals, space group C 2/c, a = 17.005(2), b = 18.411(1), c = 14.961(1) Å, β = 117.112(8)°, Z = 4, final R
W
= 0.023 from 2395 observed reflections. Keywords: ferrocenylphosphines, ruthenium carbonyl derivatives, structures, synthesis, iron carbonyl derivatives.</description><identifier>ISSN: 0008-4042</identifier><identifier>EISSN: 1480-3291</identifier><identifier>DOI: 10.1139/v90-307</identifier><identifier>CODEN: CJCHAG</identifier><language>eng</language><publisher>Ottawa, Canada: NRC Research Press</publisher><subject>Chemistry ; Condensed matter: structure, mechanical and thermal properties ; Exact sciences and technology ; Organic chemistry ; Organic compounds ; Organometalloidal and organometallic compounds ; Physics ; Preparations and properties ; Structure of solids and liquids; crystallography ; Structure of specific crystalline solids ; Transition metals derivatives</subject><ispartof>Canadian journal of chemistry, 1990-11, Vol.68 (11), p.2001-2010</ispartof><rights>1991 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://cdnsciencepub.com/doi/pdf/10.1139/v90-307$$EPDF$$P50$$Gnrcresearch$$H</linktopdf><linktohtml>$$Uhttps://cdnsciencepub.com/doi/full/10.1139/v90-307$$EHTML$$P50$$Gnrcresearch$$H</linktohtml><link.rule.ids>315,781,785,2933,27929,27930,64433,65239</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=19461523$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Chacon, Stephanie T</creatorcontrib><creatorcontrib>Cullen, William R</creatorcontrib><creatorcontrib>Bruce, Michael I</creatorcontrib><creatorcontrib>Shawkataly, Omar Bin</creatorcontrib><creatorcontrib>Einstein, Frederick W. B</creatorcontrib><creatorcontrib>Jones, Richard H</creatorcontrib><creatorcontrib>Willis, Anthony C</creatorcontrib><title>Some reactions of ferrocenyl phosphines with M3(CO)12 (M = Fe, Ru). The structures of Ru3(CO)11(PFcPh2) and Ru3(CO)10{(PPh2-η-C5H4)2Fe}</title><title>Canadian journal of chemistry</title><addtitle>Revue canadienne de chimie</addtitle><description>Substitution reactions of M
3
(CO)
12
(M = Fe, Ru) and Ru
4
((μ-H)
4
(CO)
12
involving a range of ferrocenyl phosphines are described. Compounds isolated and characterized include Fe
3
(CO)
11
PFcPh
2
, Fe
3
(CO)
10
(PBuFcPh)
2
, Fe(CO)
4
L (L = PFc
2
Ph, PFc
3
), Ru
3
(CO)
11
L (L = PFc
3
, PFc
2
Ph, PFcPh
2
), Ru
3
(CO)
10
L
2
(L = PFc
2
Ph, PFcPh
2
), and Ru(CO)
4
PFc
3
. Ru
4
((μ-H)
4
(CO)
10
(LL) and Ru
3
(CO)
10
(LL) result from reactions with LL = (Ph
2
PC
5
H
4
)
2
Fe. The structure of two derivatives are described. Crystals of Ru
3
(CO)
11
(PFcPh
2
) are triclinic, space group P-1, a = 8.576(1), b = 11.150(2), c = 9.160(3) Å, α = 76.65(1), β = 80.75(1), γ = 72.02(1)°, Z = 2, final R
W
= 0.027 from 3144 observed reflections. Ru
3
(CO)
10
(Ph2PC
5
H
4
)
2
Fc, monoclinic crystals, space group C 2/c, a = 17.005(2), b = 18.411(1), c = 14.961(1) Å, β = 117.112(8)°, Z = 4, final R
W
= 0.023 from 2395 observed reflections. Keywords: ferrocenylphosphines, ruthenium carbonyl derivatives, structures, synthesis, iron carbonyl derivatives.</description><subject>Chemistry</subject><subject>Condensed matter: structure, mechanical and thermal properties</subject><subject>Exact sciences and technology</subject><subject>Organic chemistry</subject><subject>Organic compounds</subject><subject>Organometalloidal and organometallic compounds</subject><subject>Physics</subject><subject>Preparations and properties</subject><subject>Structure of solids and liquids; crystallography</subject><subject>Structure of specific crystalline solids</subject><subject>Transition metals derivatives</subject><issn>0008-4042</issn><issn>1480-3291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1990</creationdate><recordtype>article</recordtype><recordid>eNp1kc1Kw0AQxxdRsFbxFfaiNGLqfiTd5uBBgrFCS0ut57DZnZBITcJuqxQRxLPv41v4ED6Jq9XePAzzwW_-MP9B6JCSLqU8OnuIiM-J2EItGvRdySK6jVqEkL4fkIDtoj1r71wrCAtb6O2mvgdsQKpFWVcW1znOwZhaQbWa46aobVOUFVj8WC4KPOKdeOxRhjujz5fXcxcJnOLp0uviWQHYLsxSLZYGfnSmyzVNO5NETQrmYVnpzZQ8dSZu6H-8-3E4CDyWwPM-2snl3MLBb26j2-RyFg_84fjqOr4Y-hVlkfCzQPSEzkBHLNC8r4VWLJeZpjyUEPQhC3mYAyjJSCggykSWKU2ASqYFyTjlbXS01m2kVXKeG1mp0qaNKe-lWaU0Cno0ZNxxx2uuMsodBdKoYkM5n1Pnc9ro3IEn_4OUpN-P-VvgX4Xffns</recordid><startdate>19901101</startdate><enddate>19901101</enddate><creator>Chacon, Stephanie T</creator><creator>Cullen, William R</creator><creator>Bruce, Michael I</creator><creator>Shawkataly, Omar Bin</creator><creator>Einstein, Frederick W. B</creator><creator>Jones, Richard H</creator><creator>Willis, Anthony C</creator><general>NRC Research Press</general><general>National Research Council of Canada</general><scope>IQODW</scope></search><sort><creationdate>19901101</creationdate><title>Some reactions of ferrocenyl phosphines with M3(CO)12 (M = Fe, Ru). The structures of Ru3(CO)11(PFcPh2) and Ru3(CO)10{(PPh2-η-C5H4)2Fe}</title><author>Chacon, Stephanie T ; Cullen, William R ; Bruce, Michael I ; Shawkataly, Omar Bin ; Einstein, Frederick W. B ; Jones, Richard H ; Willis, Anthony C</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-n1297-b4767dbed924d38d7dc2fabd135ae48eb535feeca2057e9b7bbcd0e1a2d70b313</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1990</creationdate><topic>Chemistry</topic><topic>Condensed matter: structure, mechanical and thermal properties</topic><topic>Exact sciences and technology</topic><topic>Organic chemistry</topic><topic>Organic compounds</topic><topic>Organometalloidal and organometallic compounds</topic><topic>Physics</topic><topic>Preparations and properties</topic><topic>Structure of solids and liquids; crystallography</topic><topic>Structure of specific crystalline solids</topic><topic>Transition metals derivatives</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chacon, Stephanie T</creatorcontrib><creatorcontrib>Cullen, William R</creatorcontrib><creatorcontrib>Bruce, Michael I</creatorcontrib><creatorcontrib>Shawkataly, Omar Bin</creatorcontrib><creatorcontrib>Einstein, Frederick W. B</creatorcontrib><creatorcontrib>Jones, Richard H</creatorcontrib><creatorcontrib>Willis, Anthony C</creatorcontrib><collection>Pascal-Francis</collection><jtitle>Canadian journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chacon, Stephanie T</au><au>Cullen, William R</au><au>Bruce, Michael I</au><au>Shawkataly, Omar Bin</au><au>Einstein, Frederick W. B</au><au>Jones, Richard H</au><au>Willis, Anthony C</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Some reactions of ferrocenyl phosphines with M3(CO)12 (M = Fe, Ru). The structures of Ru3(CO)11(PFcPh2) and Ru3(CO)10{(PPh2-η-C5H4)2Fe}</atitle><jtitle>Canadian journal of chemistry</jtitle><addtitle>Revue canadienne de chimie</addtitle><date>1990-11-01</date><risdate>1990</risdate><volume>68</volume><issue>11</issue><spage>2001</spage><epage>2010</epage><pages>2001-2010</pages><issn>0008-4042</issn><eissn>1480-3291</eissn><coden>CJCHAG</coden><abstract>Substitution reactions of M
3
(CO)
12
(M = Fe, Ru) and Ru
4
((μ-H)
4
(CO)
12
involving a range of ferrocenyl phosphines are described. Compounds isolated and characterized include Fe
3
(CO)
11
PFcPh
2
, Fe
3
(CO)
10
(PBuFcPh)
2
, Fe(CO)
4
L (L = PFc
2
Ph, PFc
3
), Ru
3
(CO)
11
L (L = PFc
3
, PFc
2
Ph, PFcPh
2
), Ru
3
(CO)
10
L
2
(L = PFc
2
Ph, PFcPh
2
), and Ru(CO)
4
PFc
3
. Ru
4
((μ-H)
4
(CO)
10
(LL) and Ru
3
(CO)
10
(LL) result from reactions with LL = (Ph
2
PC
5
H
4
)
2
Fe. The structure of two derivatives are described. Crystals of Ru
3
(CO)
11
(PFcPh
2
) are triclinic, space group P-1, a = 8.576(1), b = 11.150(2), c = 9.160(3) Å, α = 76.65(1), β = 80.75(1), γ = 72.02(1)°, Z = 2, final R
W
= 0.027 from 3144 observed reflections. Ru
3
(CO)
10
(Ph2PC
5
H
4
)
2
Fc, monoclinic crystals, space group C 2/c, a = 17.005(2), b = 18.411(1), c = 14.961(1) Å, β = 117.112(8)°, Z = 4, final R
W
= 0.023 from 2395 observed reflections. Keywords: ferrocenylphosphines, ruthenium carbonyl derivatives, structures, synthesis, iron carbonyl derivatives.</abstract><cop>Ottawa, Canada</cop><pub>NRC Research Press</pub><doi>10.1139/v90-307</doi><tpages>10</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0008-4042 |
| ispartof | Canadian journal of chemistry, 1990-11, Vol.68 (11), p.2001-2010 |
| issn | 0008-4042 1480-3291 |
| language | eng |
| recordid | cdi_pascalfrancis_primary_19461523 |
| source | NRC Research Press; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry |
| subjects | Chemistry Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Organic chemistry Organic compounds Organometalloidal and organometallic compounds Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids Transition metals derivatives |
| title | Some reactions of ferrocenyl phosphines with M3(CO)12 (M = Fe, Ru). The structures of Ru3(CO)11(PFcPh2) and Ru3(CO)10{(PPh2-η-C5H4)2Fe} |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-14T19%3A53%3A10IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-pascalfrancis_nrcre&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Some%20reactions%20of%20ferrocenyl%20phosphines%20with%20M3(CO)12%20(M%E2%80%82=%E2%80%82Fe,%20Ru).%20The%20structures%20of%20Ru3(CO)11(PFcPh2)%20and%20Ru3(CO)10%7B(PPh2-%CE%B7-C5H4)2Fe%7D&rft.jtitle=Canadian%20journal%20of%20chemistry&rft.au=Chacon,%20Stephanie%20T&rft.date=1990-11-01&rft.volume=68&rft.issue=11&rft.spage=2001&rft.epage=2010&rft.pages=2001-2010&rft.issn=0008-4042&rft.eissn=1480-3291&rft.coden=CJCHAG&rft_id=info:doi/10.1139/v90-307&rft_dat=%3Cpascalfrancis_nrcre%3E19461523%3C/pascalfrancis_nrcre%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |