Preparation of novel MgCl2-adduct supported spherical Ziegler-Natta catalyst for α-olefin polymerization
In this article, preparation of novel MgCl2‐adduct supported spherical Ziegler–Natta catalyst for α‐olefin polymerization is reported. The factors affecting the particle size (PS) and particle size distribution (PSD) of the prepared support were investigated. In this method, the internal donor added...
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| Veröffentlicht in: | Journal of applied polymer science 2006-02, Vol.99 (3), p.945-948 |
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| container_title | Journal of applied polymer science |
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| creator | Wang, Li Yu, Hao-Jie Ma, Zhen-Li Ye, Zhao-Yang Jiang, Shan Feng, Lian-Fang Gu, Xue-Ping |
| description | In this article, preparation of novel MgCl2‐adduct supported spherical Ziegler–Natta catalyst for α‐olefin polymerization is reported. The factors affecting the particle size (PS) and particle size distribution (PSD) of the prepared support were investigated. In this method, the internal donor added while preparing MgCl2‐adduct support was supposed to act as a crosslinking agent. Therefore it provided a reasonable way to enhance the morphology and control the PS of the resultant polymer particles. The possible mechanism is discussed. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 945–948, 2006 |
| doi_str_mv | 10.1002/app.22332 |
| format | Article |
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The factors affecting the particle size (PS) and particle size distribution (PSD) of the prepared support were investigated. In this method, the internal donor added while preparing MgCl2‐adduct support was supposed to act as a crosslinking agent. Therefore it provided a reasonable way to enhance the morphology and control the PS of the resultant polymer particles. The possible mechanism is discussed. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 945–948, 2006</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.22332</identifier><identifier>CODEN: JAPNAB</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc., A Wiley Company</publisher><subject>Applied sciences ; Exact sciences and technology ; morphology ; Organic polymers ; particle size ; Physicochemistry of polymers ; Polymerization ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; propene polymerization ; spherical MgCl2-adduct support ; spherical Ziegler-Natta catalyst</subject><ispartof>Journal of applied polymer science, 2006-02, Vol.99 (3), p.945-948</ispartof><rights>Copyright © 2005 Wiley Periodicals, Inc.</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.22332$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.22332$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27926,27927,45576,45577</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=17469037$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Li</creatorcontrib><creatorcontrib>Yu, Hao-Jie</creatorcontrib><creatorcontrib>Ma, Zhen-Li</creatorcontrib><creatorcontrib>Ye, Zhao-Yang</creatorcontrib><creatorcontrib>Jiang, Shan</creatorcontrib><creatorcontrib>Feng, Lian-Fang</creatorcontrib><creatorcontrib>Gu, Xue-Ping</creatorcontrib><title>Preparation of novel MgCl2-adduct supported spherical Ziegler-Natta catalyst for α-olefin polymerization</title><title>Journal of applied polymer science</title><addtitle>J. Appl. Polym. Sci</addtitle><description>In this article, preparation of novel MgCl2‐adduct supported spherical Ziegler–Natta catalyst for α‐olefin polymerization is reported. The factors affecting the particle size (PS) and particle size distribution (PSD) of the prepared support were investigated. In this method, the internal donor added while preparing MgCl2‐adduct support was supposed to act as a crosslinking agent. Therefore it provided a reasonable way to enhance the morphology and control the PS of the resultant polymer particles. The possible mechanism is discussed. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 945–948, 2006</description><subject>Applied sciences</subject><subject>Exact sciences and technology</subject><subject>morphology</subject><subject>Organic polymers</subject><subject>particle size</subject><subject>Physicochemistry of polymers</subject><subject>Polymerization</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>propene polymerization</subject><subject>spherical MgCl2-adduct support</subject><subject>spherical Ziegler-Natta catalyst</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNpFkM1KQzEQhYMoWKsL3yAbl7HJpDe3dynFVqFqF_7hJqT50WjaG5Jbtb6VL-IzeW1FYWAGzvmGmYPQIaPHjFLoqRiPATiHLdRhtCpJX8BgG3VajZFBVRW7aC_nZ0oZK6joID9NNqqkGl8vcO3won61AV88DgMQZcxSNzgvY6xTYw3O8ckmr1XAD94-BpvIpWoahbVqVFjlBrs64a9PUgfr_ALHOqzmLfCx3r6PdpwK2R789i66GZ1eD8_I5Gp8PjyZEA-CAwHBjDCi7HMHQKmDypi2NAwKVQgogbH2jQoGfVZpR2elmYHTIEDbmdDG8i462uyNKrenuqQW2mcZk5-rtJKs7IuK8rL19Ta-Nx_s6l-n8idI2QYp10HKk-l0PbQE2RA-N_b9j1DpRYqSl4W8uxxLuJhc89v7kRzxbyEaeTA</recordid><startdate>20060205</startdate><enddate>20060205</enddate><creator>Wang, Li</creator><creator>Yu, Hao-Jie</creator><creator>Ma, Zhen-Li</creator><creator>Ye, Zhao-Yang</creator><creator>Jiang, Shan</creator><creator>Feng, Lian-Fang</creator><creator>Gu, Xue-Ping</creator><general>Wiley Subscription Services, Inc., A Wiley Company</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope></search><sort><creationdate>20060205</creationdate><title>Preparation of novel MgCl2-adduct supported spherical Ziegler-Natta catalyst for α-olefin polymerization</title><author>Wang, Li ; Yu, Hao-Jie ; Ma, Zhen-Li ; Ye, Zhao-Yang ; Jiang, Shan ; Feng, Lian-Fang ; Gu, Xue-Ping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-i2632-261d6d6743f2200f29dd9ddc285a5627211899928419cf0b7db2fc262ceb6cde3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Applied sciences</topic><topic>Exact sciences and technology</topic><topic>morphology</topic><topic>Organic polymers</topic><topic>particle size</topic><topic>Physicochemistry of polymers</topic><topic>Polymerization</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>propene polymerization</topic><topic>spherical MgCl2-adduct support</topic><topic>spherical Ziegler-Natta catalyst</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Li</creatorcontrib><creatorcontrib>Yu, Hao-Jie</creatorcontrib><creatorcontrib>Ma, Zhen-Li</creatorcontrib><creatorcontrib>Ye, Zhao-Yang</creatorcontrib><creatorcontrib>Jiang, Shan</creatorcontrib><creatorcontrib>Feng, Lian-Fang</creatorcontrib><creatorcontrib>Gu, Xue-Ping</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Li</au><au>Yu, Hao-Jie</au><au>Ma, Zhen-Li</au><au>Ye, Zhao-Yang</au><au>Jiang, Shan</au><au>Feng, Lian-Fang</au><au>Gu, Xue-Ping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation of novel MgCl2-adduct supported spherical Ziegler-Natta catalyst for α-olefin polymerization</atitle><jtitle>Journal of applied polymer science</jtitle><addtitle>J. Appl. Polym. Sci</addtitle><date>2006-02-05</date><risdate>2006</risdate><volume>99</volume><issue>3</issue><spage>945</spage><epage>948</epage><pages>945-948</pages><issn>0021-8995</issn><eissn>1097-4628</eissn><coden>JAPNAB</coden><abstract>In this article, preparation of novel MgCl2‐adduct supported spherical Ziegler–Natta catalyst for α‐olefin polymerization is reported. The factors affecting the particle size (PS) and particle size distribution (PSD) of the prepared support were investigated. In this method, the internal donor added while preparing MgCl2‐adduct support was supposed to act as a crosslinking agent. Therefore it provided a reasonable way to enhance the morphology and control the PS of the resultant polymer particles. The possible mechanism is discussed. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 945–948, 2006</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc., A Wiley Company</pub><doi>10.1002/app.22332</doi><tpages>4</tpages></addata></record> |
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| subjects | Applied sciences Exact sciences and technology morphology Organic polymers particle size Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts propene polymerization spherical MgCl2-adduct support spherical Ziegler-Natta catalyst |
| title | Preparation of novel MgCl2-adduct supported spherical Ziegler-Natta catalyst for α-olefin polymerization |
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