Synthesis and characterization of samarium, europium and ytterbium aryloxides: Crystal structure of [Yb 6(OH) 4(OC 6H 4OMe) 14]·4THF
The reactions of samarium, europium and ytterbium metals with the potential bidentate ligand 2-methoxyphenol were investigated. The europium and ytterbium aryloxides were synthesized by dissolution of the metals in liquid ammonia, whereas the samarium aryloxide was synthesized by metal vapour synthe...
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| Veröffentlicht in: | Journal of alloys and compounds 2004-07, Vol.374 (1), p.289-292 |
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| container_issue | 1 |
| container_start_page | 289 |
| container_title | Journal of alloys and compounds |
| container_volume | 374 |
| creator | Carretas, José Branco, Joaquim Marçalo, Joaquim Valente, Nuno Carlos Waerenborgh, João Carvalho, Adelaide Marques, Noémia Domingos, Ângela Pires de Matos, António |
| description | The reactions of samarium, europium and ytterbium metals with the potential bidentate ligand 2-methoxyphenol were investigated. The europium and ytterbium aryloxides were synthesized by dissolution of the metals in liquid ammonia, whereas the samarium aryloxide was synthesized by metal vapour synthesis (MVS). The compounds obtained were formulated as Ln(OC
6H
4OMe)
3, Ln=Sm, Yb and Eu(OC
6H
4OMe)
2. Recrystallization of Yb(OC
6H
4OMe)
3 in the presence of THF/pentane resulted in the crystallographically characterized complex [Yb
6(μ
3-OH)
4(μ-OC
6H
4-η-OMe)
10(OC
6H
4-η-OMe)
2(OC
6H
4OMe)
2]·4THF. |
| doi_str_mv | 10.1016/j.jallcom.2003.11.120 |
| format | Article |
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6H
4OMe)
3, Ln=Sm, Yb and Eu(OC
6H
4OMe)
2. Recrystallization of Yb(OC
6H
4OMe)
3 in the presence of THF/pentane resulted in the crystallographically characterized complex [Yb
6(μ
3-OH)
4(μ-OC
6H
4-η-OMe)
10(OC
6H
4-η-OMe)
2(OC
6H
4OMe)
2]·4THF.</description><identifier>ISSN: 0925-8388</identifier><identifier>EISSN: 1873-4669</identifier><identifier>DOI: 10.1016/j.jallcom.2003.11.120</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Aryloxides ; Europium ; Exact sciences and technology ; Physics ; Samarium ; Ytterbium</subject><ispartof>Journal of alloys and compounds, 2004-07, Vol.374 (1), p.289-292</ispartof><rights>2003 Elsevier B.V.</rights><rights>2004 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jallcom.2003.11.120$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>309,310,314,780,784,789,790,3550,23930,23931,25140,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=15857942$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Carretas, José</creatorcontrib><creatorcontrib>Branco, Joaquim</creatorcontrib><creatorcontrib>Marçalo, Joaquim</creatorcontrib><creatorcontrib>Valente, Nuno</creatorcontrib><creatorcontrib>Carlos Waerenborgh, João</creatorcontrib><creatorcontrib>Carvalho, Adelaide</creatorcontrib><creatorcontrib>Marques, Noémia</creatorcontrib><creatorcontrib>Domingos, Ângela</creatorcontrib><creatorcontrib>Pires de Matos, António</creatorcontrib><title>Synthesis and characterization of samarium, europium and ytterbium aryloxides: Crystal structure of [Yb 6(OH) 4(OC 6H 4OMe) 14]·4THF</title><title>Journal of alloys and compounds</title><description>The reactions of samarium, europium and ytterbium metals with the potential bidentate ligand 2-methoxyphenol were investigated. The europium and ytterbium aryloxides were synthesized by dissolution of the metals in liquid ammonia, whereas the samarium aryloxide was synthesized by metal vapour synthesis (MVS). The compounds obtained were formulated as Ln(OC
6H
4OMe)
3, Ln=Sm, Yb and Eu(OC
6H
4OMe)
2. Recrystallization of Yb(OC
6H
4OMe)
3 in the presence of THF/pentane resulted in the crystallographically characterized complex [Yb
6(μ
3-OH)
4(μ-OC
6H
4-η-OMe)
10(OC
6H
4-η-OMe)
2(OC
6H
4OMe)
2]·4THF.</description><subject>Aryloxides</subject><subject>Europium</subject><subject>Exact sciences and technology</subject><subject>Physics</subject><subject>Samarium</subject><subject>Ytterbium</subject><issn>0925-8388</issn><issn>1873-4669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNotkN9KwzAUh4MoOKePIORG2MDWnCZtE29Eijphsgv1QkRClqaY0bUjycR67zN575PZuV2dP3z8OOdD6BRIDASyi0W8UHWt22WcEEJjgBgSsocGwHMasSwT-2hARJJGnHJ-iI68XxBCQFAYoO_HrgnvxluPVVNi_a6c0sE4-6WCbRvcVtirpXJ2vTzHZu3aVd_9o13osfn_5Lq6_bSl8Ze4cJ0PqsY-uLUOa2c2Ca8vc5yNZpMxZqNZgbMJZrMHM8bA3n5_2NPk9hgdVKr25mRXh-j59uapmETT2d19cT2NDKQsRDnNU6H5nFAlgImU8jIXJaMUKGO8XwEnfJ4aApXIWFbSPBOJoSWvcq24oHSIzra5K-W1qiunGm29XDnbv9hJSHmaC5b03NWWM_0xH9Y46bU1jTaldUYHWbZWApEb-3Ihd_blxr4EkL19-geFvHno</recordid><startdate>20040714</startdate><enddate>20040714</enddate><creator>Carretas, José</creator><creator>Branco, Joaquim</creator><creator>Marçalo, Joaquim</creator><creator>Valente, Nuno</creator><creator>Carlos Waerenborgh, João</creator><creator>Carvalho, Adelaide</creator><creator>Marques, Noémia</creator><creator>Domingos, Ângela</creator><creator>Pires de Matos, António</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope></search><sort><creationdate>20040714</creationdate><title>Synthesis and characterization of samarium, europium and ytterbium aryloxides: Crystal structure of [Yb 6(OH) 4(OC 6H 4OMe) 14]·4THF</title><author>Carretas, José ; Branco, Joaquim ; Marçalo, Joaquim ; Valente, Nuno ; Carlos Waerenborgh, João ; Carvalho, Adelaide ; Marques, Noémia ; Domingos, Ângela ; Pires de Matos, António</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-e154t-73759c8b03a9149538d79d433134489141808b5e01f9646d37692e3d8f7ca8933</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>Aryloxides</topic><topic>Europium</topic><topic>Exact sciences and technology</topic><topic>Physics</topic><topic>Samarium</topic><topic>Ytterbium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Carretas, José</creatorcontrib><creatorcontrib>Branco, Joaquim</creatorcontrib><creatorcontrib>Marçalo, Joaquim</creatorcontrib><creatorcontrib>Valente, Nuno</creatorcontrib><creatorcontrib>Carlos Waerenborgh, João</creatorcontrib><creatorcontrib>Carvalho, Adelaide</creatorcontrib><creatorcontrib>Marques, Noémia</creatorcontrib><creatorcontrib>Domingos, Ângela</creatorcontrib><creatorcontrib>Pires de Matos, António</creatorcontrib><collection>Pascal-Francis</collection><jtitle>Journal of alloys and compounds</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Carretas, José</au><au>Branco, Joaquim</au><au>Marçalo, Joaquim</au><au>Valente, Nuno</au><au>Carlos Waerenborgh, João</au><au>Carvalho, Adelaide</au><au>Marques, Noémia</au><au>Domingos, Ângela</au><au>Pires de Matos, António</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and characterization of samarium, europium and ytterbium aryloxides: Crystal structure of [Yb 6(OH) 4(OC 6H 4OMe) 14]·4THF</atitle><jtitle>Journal of alloys and compounds</jtitle><date>2004-07-14</date><risdate>2004</risdate><volume>374</volume><issue>1</issue><spage>289</spage><epage>292</epage><pages>289-292</pages><issn>0925-8388</issn><eissn>1873-4669</eissn><abstract>The reactions of samarium, europium and ytterbium metals with the potential bidentate ligand 2-methoxyphenol were investigated. The europium and ytterbium aryloxides were synthesized by dissolution of the metals in liquid ammonia, whereas the samarium aryloxide was synthesized by metal vapour synthesis (MVS). The compounds obtained were formulated as Ln(OC
6H
4OMe)
3, Ln=Sm, Yb and Eu(OC
6H
4OMe)
2. Recrystallization of Yb(OC
6H
4OMe)
3 in the presence of THF/pentane resulted in the crystallographically characterized complex [Yb
6(μ
3-OH)
4(μ-OC
6H
4-η-OMe)
10(OC
6H
4-η-OMe)
2(OC
6H
4OMe)
2]·4THF.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jallcom.2003.11.120</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0925-8388 |
| ispartof | Journal of alloys and compounds, 2004-07, Vol.374 (1), p.289-292 |
| issn | 0925-8388 1873-4669 |
| language | eng |
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| source | Elsevier ScienceDirect Journals Complete |
| subjects | Aryloxides Europium Exact sciences and technology Physics Samarium Ytterbium |
| title | Synthesis and characterization of samarium, europium and ytterbium aryloxides: Crystal structure of [Yb 6(OH) 4(OC 6H 4OMe) 14]·4THF |
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