Catalytic synthesis and characterization of stereoregular and optically active polycarbosilanes

Stereoregular and optically active polycarbosilanes were synthesized by polyaddition of optically active allylsilane and propargylsilane, and ring-opening polymerization of optically pure benzosilacyclobutene. Polyaddition of allylsilane gave an isotactic polymer, but chirality at the silicon center...

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Veröffentlicht in:	Designed monomers and polymers 2004-01, Vol.7 (1-2), p.119-126
Hauptverfasser:	Kawakami, Yusuke, Takeyama, Kadai, Shinke, Satoshi, Uenishi, Kazuya, Park, Sung Young, Kakihana, Yuriko
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Inorganic and organomineral polymers MOLECULAR WEIGHT OPTICAL ACTIVITY Physicochemistry of polymers POLYCARBOSILANE Preparation REGIOREGULARITY STEREOREGULARITY
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