Synthesis of phenol formaldehyde-containing pendant itaconamic, itaconimide and poly[N-(substituted) itaconimides]
Ortho- and meta-aminophenols were allowed to react with itaconic anhydride, forming N-ortho- and N-meta-hydroxyphenyl itaconamic acids in good yields. The above substituted itaconamic acids were allowed to react with formaldehyde in conditions similar to those of Novolac preparation and novel phenol...
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| Veröffentlicht in: | Designed monomers and polymers 2003-01, Vol.6 (1), p.115-122 |
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| container_title | Designed monomers and polymers |
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| creator | Pyriadi, Thanun M. Berzinji, Azad S. |
| description | Ortho- and meta-aminophenols were allowed to react with itaconic anhydride, forming N-ortho- and N-meta-hydroxyphenyl itaconamic acids in good yields. The above
substituted itaconamic acids were allowed to react with formaldehyde in conditions similar to those of Novolac preparation and novel phenol formaldehyde resins were obtained having pendant itaconamic acids.
Similarly, formaldehyde was allowed to react with N-ortho- and N-meta-hydroxyphenyl itaconimides, producing novel resins. Furthermore, the itacon vinyls of the pendant groups
of itaconamic acids as well as their corresponding imides were polymerized free radically using AIBN as an initiator and tough cross-linked resins were obtained. |
| doi_str_mv | 10.1163/156855503321127583 |
| format | Article |
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substituted itaconamic acids were allowed to react with formaldehyde in conditions similar to those of Novolac preparation and novel phenol formaldehyde resins were obtained having pendant itaconamic acids.
Similarly, formaldehyde was allowed to react with N-ortho- and N-meta-hydroxyphenyl itaconimides, producing novel resins. Furthermore, the itacon vinyls of the pendant groups
of itaconamic acids as well as their corresponding imides were polymerized free radically using AIBN as an initiator and tough cross-linked resins were obtained.</description><identifier>ISSN: 1385-772X</identifier><identifier>ISSN: 1568-5551</identifier><identifier>EISSN: 1568-5551</identifier><identifier>DOI: 10.1163/156855503321127583</identifier><language>eng</language><publisher>Lieden: Taylor & Francis Group</publisher><subject>Applied sciences ; CITRACONIMIDE ; Exact sciences and technology ; ITACONAMIC ACID ; ITACONIMIDES ; Organic polymers ; PHENOL FORMALDEHYDE ; Physicochemistry of polymers ; POLYCONDENSATION ; POLYN-SUBSTITUTED ITACONIMIDE ; Preparation, kinetics, thermodynamics, mechanism and catalysts ; THERMAL CURING</subject><ispartof>Designed monomers and polymers, 2003-01, Vol.6 (1), p.115-122</ispartof><rights>Copyright Taylor & Francis Group, LLC 2003</rights><rights>2003 INIST-CNRS</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c422t-cd059b914d978a58722c771408c5161be30431299005b82d60e583267f5a313c3</citedby><cites>FETCH-LOGICAL-c422t-cd059b914d978a58722c771408c5161be30431299005b82d60e583267f5a313c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,778,782,4012,27906,27907,27908</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=14565093$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Pyriadi, Thanun M.</creatorcontrib><creatorcontrib>Berzinji, Azad S.</creatorcontrib><title>Synthesis of phenol formaldehyde-containing pendant itaconamic, itaconimide and poly[N-(substituted) itaconimides]</title><title>Designed monomers and polymers</title><description>Ortho- and meta-aminophenols were allowed to react with itaconic anhydride, forming N-ortho- and N-meta-hydroxyphenyl itaconamic acids in good yields. The above
substituted itaconamic acids were allowed to react with formaldehyde in conditions similar to those of Novolac preparation and novel phenol formaldehyde resins were obtained having pendant itaconamic acids.
Similarly, formaldehyde was allowed to react with N-ortho- and N-meta-hydroxyphenyl itaconimides, producing novel resins. Furthermore, the itacon vinyls of the pendant groups
of itaconamic acids as well as their corresponding imides were polymerized free radically using AIBN as an initiator and tough cross-linked resins were obtained.</description><subject>Applied sciences</subject><subject>CITRACONIMIDE</subject><subject>Exact sciences and technology</subject><subject>ITACONAMIC ACID</subject><subject>ITACONIMIDES</subject><subject>Organic polymers</subject><subject>PHENOL FORMALDEHYDE</subject><subject>Physicochemistry of polymers</subject><subject>POLYCONDENSATION</subject><subject>POLYN-SUBSTITUTED ITACONIMIDE</subject><subject>Preparation, kinetics, thermodynamics, mechanism and catalysts</subject><subject>THERMAL CURING</subject><issn>1385-772X</issn><issn>1568-5551</issn><issn>1568-5551</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNqFkEtLxDAUhYMoOI7-AVfdCApW82iadOFCBl8w6EIFQaSkSepE2qQkGbT_3o4zojCgq3s4nO9e7gFgH8EThHJyimjOKaWQEIwQZpSTDTBamOngos1BE05TxvDTNtgJ4Q1CTAjPRsDf9zbOdDAhcXXSzbR1TVI734pG6VmvdCqdjcJYY1-TTlslbExMFIMrWiOPV9q0RulEWJV0rumfb9PDMK9CNHEetTr6HQovu2CrFk3Qe6s5Bo-XFw-T63R6d3UzOZ-mMsM4plJBWlQFylTBuKCcYSwZQxnkkqIcVZrAjCBcFBDSimOVQz28jXNWU0EQkWQM8HKv9C4Er-uy86YVvi8RLBetleutDdDBEupEkKKpvbDShB8yozmFxSJ3tswZ-9XWu_ONKqPoG-e_IfLnHf4vv46V8SOST53Hk0A</recordid><startdate>20030101</startdate><enddate>20030101</enddate><creator>Pyriadi, Thanun M.</creator><creator>Berzinji, Azad S.</creator><general>Taylor & Francis Group</general><general>VSP</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20030101</creationdate><title>Synthesis of phenol formaldehyde-containing pendant itaconamic, itaconimide and poly[N-(substituted) itaconimides]</title><author>Pyriadi, Thanun M. ; Berzinji, Azad S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c422t-cd059b914d978a58722c771408c5161be30431299005b82d60e583267f5a313c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Applied sciences</topic><topic>CITRACONIMIDE</topic><topic>Exact sciences and technology</topic><topic>ITACONAMIC ACID</topic><topic>ITACONIMIDES</topic><topic>Organic polymers</topic><topic>PHENOL FORMALDEHYDE</topic><topic>Physicochemistry of polymers</topic><topic>POLYCONDENSATION</topic><topic>POLYN-SUBSTITUTED ITACONIMIDE</topic><topic>Preparation, kinetics, thermodynamics, mechanism and catalysts</topic><topic>THERMAL CURING</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pyriadi, Thanun M.</creatorcontrib><creatorcontrib>Berzinji, Azad S.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Designed monomers and polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pyriadi, Thanun M.</au><au>Berzinji, Azad S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of phenol formaldehyde-containing pendant itaconamic, itaconimide and poly[N-(substituted) itaconimides]</atitle><jtitle>Designed monomers and polymers</jtitle><date>2003-01-01</date><risdate>2003</risdate><volume>6</volume><issue>1</issue><spage>115</spage><epage>122</epage><pages>115-122</pages><issn>1385-772X</issn><issn>1568-5551</issn><eissn>1568-5551</eissn><abstract>Ortho- and meta-aminophenols were allowed to react with itaconic anhydride, forming N-ortho- and N-meta-hydroxyphenyl itaconamic acids in good yields. The above
substituted itaconamic acids were allowed to react with formaldehyde in conditions similar to those of Novolac preparation and novel phenol formaldehyde resins were obtained having pendant itaconamic acids.
Similarly, formaldehyde was allowed to react with N-ortho- and N-meta-hydroxyphenyl itaconimides, producing novel resins. Furthermore, the itacon vinyls of the pendant groups
of itaconamic acids as well as their corresponding imides were polymerized free radically using AIBN as an initiator and tough cross-linked resins were obtained.</abstract><cop>Lieden</cop><pub>Taylor & Francis Group</pub><doi>10.1163/156855503321127583</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1385-772X |
| ispartof | Designed monomers and polymers, 2003-01, Vol.6 (1), p.115-122 |
| issn | 1385-772X 1568-5551 1568-5551 |
| language | eng |
| recordid | cdi_pascalfrancis_primary_14565093 |
| source | EZB-FREE-00999 freely available EZB journals |
| subjects | Applied sciences CITRACONIMIDE Exact sciences and technology ITACONAMIC ACID ITACONIMIDES Organic polymers PHENOL FORMALDEHYDE Physicochemistry of polymers POLYCONDENSATION POLYN-SUBSTITUTED ITACONIMIDE Preparation, kinetics, thermodynamics, mechanism and catalysts THERMAL CURING |
| title | Synthesis of phenol formaldehyde-containing pendant itaconamic, itaconimide and poly[N-(substituted) itaconimides] |
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