LIPASES AND LIPASE-CATALYZED ESTERIFICATION REACTIONS IN NONAQUEOUS MEDIA
Enzymatic reactions in nonaqueous solvents offer new possibilities for the biotechnological production of many useful chemicals using reactions that are not feasible in aqueous media. In the recent years, the use of enzymes in nonaqueous media has found applications in organic synthesis, chiral synt...
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| Veröffentlicht in: | Catalysis reviews. Science and engineering 2002-12, Vol.44 (4), p.499-591 |
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| container_title | Catalysis reviews. Science and engineering |
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| creator | Hari Krishna, S. Karanth, N. G. |
| description | Enzymatic reactions in nonaqueous solvents offer new possibilities for the biotechnological production of many useful chemicals using reactions that are not feasible in aqueous media. In the recent years, the use of enzymes in nonaqueous media has found applications in organic synthesis, chiral synthesis or resolution, modification of fats and oils, synthesis of sugar-based polymers, etc. The use of lipases in esterification reactions to produce industrially important products such as emulsifiers, surfactants, wax esters, chiral molecules, biopolymers, modified fats and oils, structured lipids, and flavor esters is well documented. The interest in using lipases as biotechnological vectors for performing various reactions in both macro- and microaqueous systems has picked up tremendously during the last decade. This review covers important features of lipases and lipase-catalyzed esterification reactions including the kinetics and stability of lipases, and modeling aspects. |
| doi_str_mv | 10.1081/CR-120015481 |
| format | Article |
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G.</creatorcontrib><title>LIPASES AND LIPASE-CATALYZED ESTERIFICATION REACTIONS IN NONAQUEOUS MEDIA</title><title>Catalysis reviews. Science and engineering</title><description>Enzymatic reactions in nonaqueous solvents offer new possibilities for the biotechnological production of many useful chemicals using reactions that are not feasible in aqueous media. In the recent years, the use of enzymes in nonaqueous media has found applications in organic synthesis, chiral synthesis or resolution, modification of fats and oils, synthesis of sugar-based polymers, etc. The use of lipases in esterification reactions to produce industrially important products such as emulsifiers, surfactants, wax esters, chiral molecules, biopolymers, modified fats and oils, structured lipids, and flavor esters is well documented. The interest in using lipases as biotechnological vectors for performing various reactions in both macro- and microaqueous systems has picked up tremendously during the last decade. This review covers important features of lipases and lipase-catalyzed esterification reactions including the kinetics and stability of lipases, and modeling aspects.</description><subject>Biological and medical sciences</subject><subject>Biopolymers</subject><subject>Biosurfactants</subject><subject>Catalysis</subject><subject>Catalytic reactions</subject><subject>Chemistry</subject><subject>Emulsifiers</subject><subject>Esterification</subject><subject>Esterification reactions</subject><subject>Esters</subject><subject>Exact sciences and technology</subject><subject>Fats</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>General and physical chemistry</subject><subject>Lipase</subject><subject>Lipases</subject><subject>Lipids</subject><subject>Mathematical analysis</subject><subject>Mechanisms. Catalysis. Electron transfer. Models</subject><subject>Media</subject><subject>Molecular biophysics</subject><subject>Nonaqueous media</subject><subject>Organic solvents</subject><subject>Physical chemistry in biology</subject><subject>Synthesis</subject><subject>Theory of reactions, general kinetics. Catalysis. 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Models</topic><topic>Media</topic><topic>Molecular biophysics</topic><topic>Nonaqueous media</topic><topic>Organic solvents</topic><topic>Physical chemistry in biology</topic><topic>Synthesis</topic><topic>Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hari Krishna, S.</creatorcontrib><creatorcontrib>Karanth, N. G.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Catalysis reviews. 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| ispartof | Catalysis reviews. Science and engineering, 2002-12, Vol.44 (4), p.499-591 |
| issn | 0161-4940 1520-5703 |
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| source | Taylor & Francis:Master (3349 titles) |
| subjects | Biological and medical sciences Biopolymers Biosurfactants Catalysis Catalytic reactions Chemistry Emulsifiers Esterification Esterification reactions Esters Exact sciences and technology Fats Fundamental and applied biological sciences. Psychology General and physical chemistry Lipase Lipases Lipids Mathematical analysis Mechanisms. Catalysis. Electron transfer. Models Media Molecular biophysics Nonaqueous media Organic solvents Physical chemistry in biology Synthesis Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
| title | LIPASES AND LIPASE-CATALYZED ESTERIFICATION REACTIONS IN NONAQUEOUS MEDIA |
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