The state of ion aggregation in ionomers based on copolymers of styrene and acrylic acid: 1. Small-angle X-ray scattering studies
Small-angle X-ray scattering results for random ionomers based on copolymers of styrene and acrylic acid containing ions of alkali metals are presented. A study has been made on the influence of the content and type of acrylate in styrene-based ionomers on the state of ion aggregation. The obtained...
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| Veröffentlicht in: | European polymer journal 2000-10, Vol.36 (10), p.2167-2174 |
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| container_issue | 10 |
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| container_title | European polymer journal |
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| creator | Suchocka-Gałaś, Kazimiera Ślusarczyk, Czesław Włochowicz, Andrzej |
| description | Small-angle X-ray scattering results for random ionomers based on copolymers of styrene and acrylic acid containing ions of alkali metals are presented. A study has been made on the influence of the content and type of acrylate in styrene-based ionomers on the state of ion aggregation. The obtained results indicate that in the case of the ionomers containing caesium ion clusters of sizes ∼100 Å and multiplets of sizes ∼20 Å are formed. For these ionomers, the increase of the temperature causes the increase of the size of clusters.
In the case of ionomers containing lithium and potassium ions, only the smaller aggregate multiplets are formed. |
| doi_str_mv | 10.1016/S0014-3057(99)00290-6 |
| format | Article |
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In the case of ionomers containing lithium and potassium ions, only the smaller aggregate multiplets are formed.</description><subject>Applied sciences</subject><subject>Clusters</subject><subject>Exact sciences and technology</subject><subject>Multiplets</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Properties and characterization</subject><subject>Small-angle X-ray scattering</subject><subject>Structure, morphology and analysis</subject><subject>Styrene-based ionomers</subject><issn>0014-3057</issn><issn>1873-1945</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><recordid>eNo9kE9L5EAQxZvFBUd3P8JCHzzoIVqVTjrTXkTEfyB4mFnYW1PprmRbMsnQHYUc_eZmRvH0isd7xeMnxB-EcwTUFysALDIFZXVqzBlAbiDTP8QCl5XK0BTlgVh8Rw7FUUovAFAprRbiff2fZRppZDk0Mgy9pLaN3NK4u0O_s4YNxyRrSuzlbLphO3TT3psraZwi9yyp95JcnLrgZg3-UuK5XG2o6zLq247lvyzSJJOjceQY-nZuvvrA6Zf42VCX-PeXHou_d7frm4fs6fn-8eb6KeNcLcdMe-KiUlyb2lPNRhdeIVZMFRAaDbhUpSOvQJWEJTWc11wqrCvQpWl0ro7FyeffLc0juiZS70Ky2xg2FCeLBaocYY5dfcZ43vIWONrkAveOfYjsRuuHYBHsDrzdg7c7qtYYuwdvtfoAEoB4KQ</recordid><startdate>20001001</startdate><enddate>20001001</enddate><creator>Suchocka-Gałaś, Kazimiera</creator><creator>Ślusarczyk, Czesław</creator><creator>Włochowicz, Andrzej</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope></search><sort><creationdate>20001001</creationdate><title>The state of ion aggregation in ionomers based on copolymers of styrene and acrylic acid: 1. Small-angle X-ray scattering studies</title><author>Suchocka-Gałaś, Kazimiera ; Ślusarczyk, Czesław ; Włochowicz, Andrzej</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-e238t-6dae473eb9bdabe964d3117ea70a19601835cad3035a15afe2be531b70659f623</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2000</creationdate><topic>Applied sciences</topic><topic>Clusters</topic><topic>Exact sciences and technology</topic><topic>Multiplets</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>Properties and characterization</topic><topic>Small-angle X-ray scattering</topic><topic>Structure, morphology and analysis</topic><topic>Styrene-based ionomers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Suchocka-Gałaś, Kazimiera</creatorcontrib><creatorcontrib>Ślusarczyk, Czesław</creatorcontrib><creatorcontrib>Włochowicz, Andrzej</creatorcontrib><collection>Pascal-Francis</collection><jtitle>European polymer journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Suchocka-Gałaś, Kazimiera</au><au>Ślusarczyk, Czesław</au><au>Włochowicz, Andrzej</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The state of ion aggregation in ionomers based on copolymers of styrene and acrylic acid: 1. Small-angle X-ray scattering studies</atitle><jtitle>European polymer journal</jtitle><date>2000-10-01</date><risdate>2000</risdate><volume>36</volume><issue>10</issue><spage>2167</spage><epage>2174</epage><pages>2167-2174</pages><issn>0014-3057</issn><eissn>1873-1945</eissn><coden>EUPJAG</coden><abstract>Small-angle X-ray scattering results for random ionomers based on copolymers of styrene and acrylic acid containing ions of alkali metals are presented. A study has been made on the influence of the content and type of acrylate in styrene-based ionomers on the state of ion aggregation. The obtained results indicate that in the case of the ionomers containing caesium ion clusters of sizes ∼100 Å and multiplets of sizes ∼20 Å are formed. For these ionomers, the increase of the temperature causes the increase of the size of clusters.
In the case of ionomers containing lithium and potassium ions, only the smaller aggregate multiplets are formed.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/S0014-3057(99)00290-6</doi><tpages>8</tpages></addata></record> |
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| ispartof | European polymer journal, 2000-10, Vol.36 (10), p.2167-2174 |
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| language | eng |
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| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Applied sciences Clusters Exact sciences and technology Multiplets Organic polymers Physicochemistry of polymers Properties and characterization Small-angle X-ray scattering Structure, morphology and analysis Styrene-based ionomers |
| title | The state of ion aggregation in ionomers based on copolymers of styrene and acrylic acid: 1. Small-angle X-ray scattering studies |
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