A Supramolecular Oscillator Composed of Carbon Nanocluster C120 and a Rhodium(III) Porphyrin Cyclic Dimer

A rhodium(III) porphyrin cyclic dimer (1) included carbon nanocluster C120 (2) to form a π-electronic supramolecular complex (1⊃2), in which 2 oscillated back and forth within its cavity. Spectroscopic titration of 1 with 2 and line shape analysis on variable-temperature 1H NMR spectral profiles of...

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Veröffentlicht in:	Journal of the American Chemical Society 2002-10, Vol.124 (41), p.12086-12087
Hauptverfasser:	Tashiro, Kentaro, Hirabayashi, Yusuke, Aida, Takuzo, Saigo, Kazuhiko, Fujiwara, Koichi, Komatsu, Koichi, Sakamoto, Shigeru, Yamaguchi, Kentaro
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Inorganic chemistry and origins of life Miscellaneous Preparations and properties
Online-Zugang:	Volltext
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