$Columnar Assemblies of Aliphatic Poly(acetylene ester)s Prepared with a [Rh(norbornadiene)Cl]2 Catalyst. 1H and 13C NMR, X-Ray Diffraction and AFM Studies$

Columnar Assemblies of Aliphatic Poly(acetylene ester)s Prepared with a [Rh(norbornadiene)Cl]2 Catalyst. 1H and 13C NMR, X-Ray Diffraction and AFM Studies

Alkyl propiolates: HC≡CCOOn‐CmH2m+1(m = 2˜4), acetylene esters were polymerized with a [Rh(norbornadiene)Cl]2 catalyst in methanol as the polymerization solvent to produce poly(n‐alkyl propiolate)s, PAPAs, called polyacetylene esters, in relatively high yields. The resulting PAPAs were characterized...

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Veröffentlicht in:	Macromolecular chemistry and physics 2002-01, Vol.203 (1), p.66-70
Hauptverfasser:	Kozuka, Munehiro, Sone, Takeyuki, Sadahiro, Yoshikazu, Tabata, Masayoshi, Enoto, Takeaki
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences atomic force microscopy (AFM) columns Exact sciences and technology Organic polymers Physicochemistry of polymers polyesters Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts self-organization X-ray diffraction (XRD)
Online-Zugang:	Volltext
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