Quasi-solid dye-sensitized solar cells containing chemically cross-linked gel: How to make gels with a small amount of gelator

Quasi-solid dye-sensitized solar cells equipped with chemically cross-linked gels are reported. The gelator contains multi-functional pyridine or imidazole derivatives and multifunctional halogen derivatives. The former reacts with the latter to give three-dimensional ionomer structures even in liqu...

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Veröffentlicht in:Journal of photochemistry and photobiology. A, Chemistry Chemistry, 2002-05, Vol.148 (1), p.33-39
Hauptverfasser: Murai, Shinji, Mikoshiba, Satoshi, Sumino, Hiroyasu, Hayase, Shuzi
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container_issue 1
container_start_page 33
container_title Journal of photochemistry and photobiology. A, Chemistry
container_volume 148
creator Murai, Shinji
Mikoshiba, Satoshi
Sumino, Hiroyasu
Hayase, Shuzi
description Quasi-solid dye-sensitized solar cells equipped with chemically cross-linked gels are reported. The gelator contains multi-functional pyridine or imidazole derivatives and multifunctional halogen derivatives. The former reacts with the latter to give three-dimensional ionomer structures even in liquid electrolytes. Gelators polymerized directly in liquid electrolytes of cells have not been reported so far. This makes the cell fabrication process easier, where electrolyte precursors are injected into cells, followed by gelled directly in the cells. In addition, a micro-phase separation technique is introduced in order to decrease the amount of gelators. This makes it possible for the liquid electrolytes to be solidified without losing the high performance of liquid-type cells before gelation.
doi_str_mv 10.1016/S1010-6030(02)00046-1
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1873-2666
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source Elsevier ScienceDirect Journals
subjects Applied sciences
Chemically cross-linked
Chemistry
Dye sensitized
Electrochemistry
Energy
Exact sciences and technology
Gel electrolyte
Gelation
General and physical chemistry
Natural energy
Phase separation
Photoelectrochemistry. Electrochemiluminescence
Photovoltaic conversion
Solar cells. Photoelectrochemical cells
Solar energy
title Quasi-solid dye-sensitized solar cells containing chemically cross-linked gel: How to make gels with a small amount of gelator
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