A Mechanistic Study of the Samarium(II)-Mediated Reduction of Aryl Nitro Compounds to the Corresponding Arylamines. The Crystal Structures of {Sm[N(SiMe3)2]2(thf)}2(μ2-O) and [(Me3Si)2N]2Sm(thf)(μ-PhNNPh)Sm[N(SiMe3)2]2

Treatment of nitrobenzene and other various nitroarenes with 6 equiv of samarium(II) under strictly anhydrous conditions allows for the isolation of aniline or the corresponding arylamine. Reducing the number of samarium(II) equivalents allows for the isolation of intermediate species, e.g., azoaren...

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Veröffentlicht in:	Journal of the American Chemical Society 2002-06, Vol.124 (24), p.7007-7015
Hauptverfasser:	Brady, Erik D, Clark, David L, Keogh, D. Webster, Scott, Brian L, Watkin, John G
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Kinetics and mechanisms Organic chemistry Reactivity and mechanisms
Online-Zugang:	Volltext
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