Self-assembled monolayers as selective filters for chemical sensors

The lateral electrical conductivity of gold layers with thickness in the nanometer range was found to decrease due to adsorption of mercury, water, iodine and sulphuric compounds onto the gold surface. A self-assembled monolayer of hexadecanethiol, deposited on the gold surface, blocked the effects...

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Veröffentlicht in:Nanotechnology 2002-04, Vol.13 (2), p.175-178
Hauptverfasser: Mirsky, Vladimir M, Vasjari, Majlinda, Novotny, Ivan, Rehacek, Vlastimil, Tvarozek, Vladimir, Wolfbeis, Otto S
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container_end_page 178
container_issue 2
container_start_page 175
container_title Nanotechnology
container_volume 13
creator Mirsky, Vladimir M
Vasjari, Majlinda
Novotny, Ivan
Rehacek, Vlastimil
Tvarozek, Vladimir
Wolfbeis, Otto S
description The lateral electrical conductivity of gold layers with thickness in the nanometer range was found to decrease due to adsorption of mercury, water, iodine and sulphuric compounds onto the gold surface. A self-assembled monolayer of hexadecanethiol, deposited on the gold surface, blocked the effects of water and volatile sulphuric compounds on the lateral conductivity of the gold layers, but does not block the effects of iodine and mercury. The results indicate a selective permeability of hexadecanethiol monolayers for mercury vapor, thus providing a method for development of ultrathin filters for chemical sensors. (Author)
doi_str_mv 10.1088/0957-4484/13/2/309
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source IOP Publishing Journals; Institute of Physics (IOP) Journals - HEAL-Link
subjects Analytical chemistry
Chemistry
Exact sciences and technology
General equipment and techniques
General, instrumentation
Instruments, apparatus, components and techniques common to several branches of physics and astronomy
Physics
Sensors (chemical, optical, electrical, movement, gas, etc.)
remote sensing
title Self-assembled monolayers as selective filters for chemical sensors
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