The Nature of Superacid Electrophilic Species in HF/SbF5:   A Density Functional Theory Study

A density functional theory study at the B3LYP/6-31++G** + RECP(Sb) level of the HF/SbF5 superacid system was carried out. The geometries of possible electrophilic species, such as H2F+·Sb2F11 - and H3F2 +·Sb2F11 -, were calculated and correspond with available experimental results. Calculations of...

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Veröffentlicht in:	Journal of the American Chemical Society 2002-03, Vol.124 (11), p.2672-2677
Hauptverfasser:	Esteves, Pierre M, Ramírez-Solís, Alejandro, Mota, Claudio J. A
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology General and physical chemistry Solution properties Solutions
Online-Zugang:	Volltext
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