How To Insulate a Reactive Site from a Perfluoroalkyl Group:  Photoelectron Spectroscopy, Calorimetric, and Computational Studies of Long-Range Electronic Effects in Fluorous Phosphines P((CH2) m (CF2)7CF3)3

This study advances strategy and design in catalysts and reagents for fluorous and supercritical CO2 chemistry by defining the structural requirements for insulating a typical active site from a perfluoroalkyl segment. The vertical ionization potentials of the phosphines P((CH2) m Rf8)3 (m = 2 (2) t...

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Veröffentlicht in:	Journal of the American Chemical Society 2002-02, Vol.124 (7), p.1516-1523
Hauptverfasser:	Jiao, Haijun, Le Stang, Sylvie, Soós, Tibor, Meier, Ralf, Kowski, Klaus, Rademacher, Paul, Jafarpour, Laleh, Hamard, Jean-Benoit, Nolan, Steven P, Gladysz, J. A
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic and molecular physics Exact sciences and technology Ionization potentials, electron affinities, molecular core binding energy Molecular properties and interactions with photons Physics Properties of molecules and molecular ions
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