Possible Superhigh-Spin Cluster in the Crystals of a Novel Nitronyl Nitroxide Radical as Studied by FT Pulsed ESR
Syntheses and magnetic properties of novel nitronyl nitroxide derivatives are reported. In the derivatives under study, the bulky tetramethylethylene group of the conventional nitronyl nitroxide has been replaced by aromatic rings, giving planar π-conjugation systems. The first half of the paper is...
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| Veröffentlicht in: | Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals Molecular crystals and liquid crystals, 1999-09, Vol.335 (1), p.359-369 |
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| container_title | Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals |
| container_volume | 335 |
| creator | Shiomi, Daisuke Sato, Kazunobu Takui, Takeji Itoh, Koichi Tamura, Masafumi Nishio, Yutaka Kajita, Koji Nakagawa, Mitsutoshi Takayukiishida Nogami, Takashi |
| description | Syntheses and magnetic properties of novel nitronyl nitroxide derivatives are reported. In the derivatives under study, the bulky tetramethylethylene group of the conventional nitronyl nitroxide has been replaced by aromatic rings, giving planar π-conjugation systems. The first half of the paper is devoted to the syntheses and characterization of new derivatives of such radical, 2-phenylbenzimidazol-l-yl-N,N′-dioxide (PBIDO). Chemical stability, π-spin density distribution, and solid state magnetic properties have been examined from solution ESR and static susceptibility measurements. In the latter half, we discuss an anomaly of paramagnetic relaxation found in crystals of PBIDO by pulsed ESR spectroscopy. The origin of the anomaly is attributed to a possible formation of paramagnetic species with huge S, or "super-high-spin cluster" at lattice defects in the crystal. |
| doi_str_mv | 10.1080/10587259908028880 |
| format | Article |
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| ispartof | Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 1999-09, Vol.335 (1), p.359-369 |
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| language | eng |
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| source | Taylor & Francis Journals Complete |
| subjects | and T Condensed matter: electronic structure, electrical, magnetic, and optical properties Exact sciences and technology imidazole-1-oxyl-3-oxide lattice defect Magnetic properties and materials Molecular magnets nitronyl nitroxide Physics pulsed ESR relaxation time Studies of specific magnetic materials |
| title | Possible Superhigh-Spin Cluster in the Crystals of a Novel Nitronyl Nitroxide Radical as Studied by FT Pulsed ESR |
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