Approaches to the controlled formation of network polymers:: 2. Studies of hybrid crosslinking agents

Polyacrylamide networks incorporating hybrid crosslinking agents in which amide and ester functional moieties form part of the vinylic structure have a higher degree of porosity than the more conventional systems as evidenced by electrophoresis and overswelling studies. The increase of porosity may...

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Veröffentlicht in:Polymer (Guilford) 2000-01, Vol.41 (1), p.27-34
Hauptverfasser: Chan, G.Y.N, Kambouris, P.A, Looney, M.G, Qiao, G.G, Solomon, D.H
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container_end_page 34
container_issue 1
container_start_page 27
container_title Polymer (Guilford)
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creator Chan, G.Y.N
Kambouris, P.A
Looney, M.G
Qiao, G.G
Solomon, D.H
description Polyacrylamide networks incorporating hybrid crosslinking agents in which amide and ester functional moieties form part of the vinylic structure have a higher degree of porosity than the more conventional systems as evidenced by electrophoresis and overswelling studies. The increase of porosity may be attributed to two mechanisms of network formation; star or non-star type, which are determined by the reactivity of the vinylic groups present within the monomer structure. The experimental results are in good agreement with the theoretical predictions.
doi_str_mv 10.1016/S0032-3861(99)00114-7
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source Elsevier ScienceDirect Journals Complete - AutoHoldings
subjects Applied sciences
Crosslinking agents
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polyacrylamide
Porosity
Properties and characterization
Solution and gel properties
title Approaches to the controlled formation of network polymers:: 2. Studies of hybrid crosslinking agents
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