Approaches to the controlled formation of network polymers:: 2. Studies of hybrid crosslinking agents
Polyacrylamide networks incorporating hybrid crosslinking agents in which amide and ester functional moieties form part of the vinylic structure have a higher degree of porosity than the more conventional systems as evidenced by electrophoresis and overswelling studies. The increase of porosity may...
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Veröffentlicht in: | Polymer (Guilford) 2000-01, Vol.41 (1), p.27-34 |
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container_title | Polymer (Guilford) |
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creator | Chan, G.Y.N Kambouris, P.A Looney, M.G Qiao, G.G Solomon, D.H |
description | Polyacrylamide networks incorporating hybrid crosslinking agents in which amide and ester functional moieties form part of the vinylic structure have a higher degree of porosity than the more conventional systems as evidenced by electrophoresis and overswelling studies. The increase of porosity may be attributed to two mechanisms of network formation; star or non-star type, which are determined by the reactivity of the vinylic groups present within the monomer structure. The experimental results are in good agreement with the theoretical predictions. |
doi_str_mv | 10.1016/S0032-3861(99)00114-7 |
format | Article |
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The experimental results are in good agreement with the theoretical predictions.</description><identifier>ISSN: 0032-3861</identifier><identifier>EISSN: 1873-2291</identifier><identifier>DOI: 10.1016/S0032-3861(99)00114-7</identifier><identifier>CODEN: POLMAG</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Applied sciences ; Crosslinking agents ; Exact sciences and technology ; Organic polymers ; Physicochemistry of polymers ; Polyacrylamide ; Porosity ; Properties and characterization ; Solution and gel properties</subject><ispartof>Polymer (Guilford), 2000-01, Vol.41 (1), p.27-34</ispartof><rights>1999 Elsevier Science Ltd</rights><rights>2000 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0032-3861(99)00114-7$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,778,782,3539,4012,27910,27911,27912,45982</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=1216577$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Chan, G.Y.N</creatorcontrib><creatorcontrib>Kambouris, P.A</creatorcontrib><creatorcontrib>Looney, M.G</creatorcontrib><creatorcontrib>Qiao, G.G</creatorcontrib><creatorcontrib>Solomon, D.H</creatorcontrib><title>Approaches to the controlled formation of network polymers:: 2. Studies of hybrid crosslinking agents</title><title>Polymer (Guilford)</title><description>Polyacrylamide networks incorporating hybrid crosslinking agents in which amide and ester functional moieties form part of the vinylic structure have a higher degree of porosity than the more conventional systems as evidenced by electrophoresis and overswelling studies. The increase of porosity may be attributed to two mechanisms of network formation; star or non-star type, which are determined by the reactivity of the vinylic groups present within the monomer structure. The experimental results are in good agreement with the theoretical predictions.</description><subject>Applied sciences</subject><subject>Crosslinking agents</subject><subject>Exact sciences and technology</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polyacrylamide</subject><subject>Porosity</subject><subject>Properties and characterization</subject><subject>Solution and gel properties</subject><issn>0032-3861</issn><issn>1873-2291</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2000</creationdate><recordtype>article</recordtype><recordid>eNo9kEtLAzEUhYMoWKs_QcjChS6m5jGvdCOl-IKCi-o6ZJI7bew0GZKo9N87bcXV5cB3DpcPoWtKJpTQ8n5JCGcZr0t6K8QdIZTmWXWCRrSueMaYoKdo9I-co4sYPwkhrGD5CMGs74NXeg0RJ4_TGrD2LgXfdWBw68NWJesd9i12kH582ODed7sthDidYjbBy_Rl7FAegPWuCdZgHXyMnXUb61ZYrcCleInOWtVFuPq7Y_Tx9Pg-f8kWb8-v89kiA8brlFUMDIWccWFANU2jhiCKRtW1YBUVBQHe6BKgpIy2iuU11SpXQjclrVsDhI_RzXG3V1Grrg3KaRtlH-xWhZ0camVRVQP2cMRg-OXbQpBRW3AajA2gkzTeSkrkXq48yJV7c1IIeZArK_4Lz2lvcg</recordid><startdate>200001</startdate><enddate>200001</enddate><creator>Chan, G.Y.N</creator><creator>Kambouris, P.A</creator><creator>Looney, M.G</creator><creator>Qiao, G.G</creator><creator>Solomon, D.H</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope></search><sort><creationdate>200001</creationdate><title>Approaches to the controlled formation of network polymers:: 2. 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subjects | Applied sciences Crosslinking agents Exact sciences and technology Organic polymers Physicochemistry of polymers Polyacrylamide Porosity Properties and characterization Solution and gel properties |
title | Approaches to the controlled formation of network polymers:: 2. Studies of hybrid crosslinking agents |
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