Organic-Inorganic Hybrid Materials for Nonlinear Optics Applications

Three types of organic-inorganic hybrid materials were prepared by the sol-gel processable monomers derived from 3-isocyanatopropyltriethoxysilane with three different hydroxy-functionalized nonlinear optical chromophores. The measured values of NLO coefficient strongly depended on conditions such a...

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Veröffentlicht in:Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals Molecular crystals and liquid crystals, 2000-12, Vol.353 (1), p.525-537
Hauptverfasser: Lee, Kwang-Sup, Kim, Tae-Dong, Min, Yu Hong, Yoon, Choon Sup, Samoc, Marek, Samoc, Anna
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container_title Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals
container_volume 353
creator Lee, Kwang-Sup
Kim, Tae-Dong
Min, Yu Hong
Yoon, Choon Sup
Samoc, Marek
Samoc, Anna
description Three types of organic-inorganic hybrid materials were prepared by the sol-gel processable monomers derived from 3-isocyanatopropyltriethoxysilane with three different hydroxy-functionalized nonlinear optical chromophores. The measured values of NLO coefficient strongly depended on conditions such as poling temperature, poling time and heating rate. The hybrid films heated at 200°C exhibited d 33 = 50-58 pm/V in Maker-fringe measurement. It was found that the thermal stabilities of the films were greatly enhanced as poling time increased and a poling temperature became higher. Also, we observed good waveguiding properties of the films at 810 nm and 1064 nm. The optical propagation losses of the films for TE mode were about 2 dB/cm at 810 nm and 0.5 dB/cm at 1064 nm.
doi_str_mv 10.1080/10587250008025686
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source Taylor & Francis Journals Complete
subjects Exact sciences and technology
Fundamental areas of phenomenology (including applications)
optical loss
Optical materials
Optics
organic-inorganic hybrid films
Other nonlinear optical materials
photorefractive and semiconductor materials
Physics
poling condition
second-order nonlinearity
thermal relaxation
title Organic-Inorganic Hybrid Materials for Nonlinear Optics Applications
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