Uranium(VI) Bis(imido) Chalcogenate Complexes: Synthesis and Density Functional Theory Analysis

Bis(imido) uranium(VI) trans- and cis-dichalcogenate complexes with the general formula U(NtBu)2(EAr)2(OPPh3)2 (EAr = O-2-tBuC6H4, SPh, SePh, TePh) and U(NtBu)2(EAr)2(R2bpy) (EAr = SPh, SePh, TePh) (R2bpy = 4,4′-disubstituted-2,2′-bipyridyl, R = Me, tBu) have been prepared. This family of complexes...

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Veröffentlicht in:	Inorganic chemistry 2009-03, Vol.48 (6), p.2693-2700
Hauptverfasser:	Spencer, Liam P, Yang, Ping, Scott, Brian L, Batista, Enrique R, Boncella, James M
Format:	Artikel
Sprache:	eng
Schlagworte:	CHEMICAL BONDS DENSITY FUNCTIONAL METHOD ELECTRONIC STRUCTURE INTERACTIONS MATERIALS SCIENCE SELENIUM COMPLEXES SULFUR COMPLEXES SYNTHESIS TELLURIUM COMPLEXES URANIUM COMPLEXES
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