Incorporating Size Selectivity into Synergistic Solvent Extraction: A Review of Crown Ether-Containing Systems

This paper provides a comprehensive review of synergistic solvent extraction using crown ethers with a focus on the role of both extractants in facilitating cation-specific separations. An introduction to the various equilibria affecting synergistic extraction using crown ethers is followed by a rev...

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Veröffentlicht in:	Industrial & engineering chemistry research 2000-10, Vol.39 (10), p.3442-3464
Hauptverfasser:	Bond, Andrew H, Dietz, Mark L, Chiarizia, Renato
Format:	Artikel
Sprache:	eng
Schlagworte:	CATIONS Chemistry CROWN ETHERS Exact sciences and technology Inorganic chemistry and origins of life INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Kinetics and mechanism of reactions SIZE SOLVENT EXTRACTION SYNERGISM
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creator	Bond, Andrew H Dietz, Mark L Chiarizia, Renato
description	This paper provides a comprehensive review of synergistic solvent extraction using crown ethers with a focus on the role of both extractants in facilitating cation-specific separations. An introduction to the various equilibria affecting synergistic extraction using crown ethers is followed by a review of the work published in this field during the 1972−1999 time period. The influence of various solvent extraction parameters on the potential for cation-selective synergism is critically examined. Those synergistic extractant combinations showing cation selectivity are highlighted, as are the fundamental investigations that are the foundation of the current understanding of synergistic solvent extraction using crown ethers.
doi_str_mv	10.1021/ie000356j
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Res</addtitle><date>2000-10-01</date><risdate>2000</risdate><volume>39</volume><issue>10</issue><spage>3442</spage><epage>3464</epage><pages>3442-3464</pages><issn>0888-5885</issn><eissn>1520-5045</eissn><coden>IECRED</coden><abstract>This paper provides a comprehensive review of synergistic solvent extraction using crown ethers with a focus on the role of both extractants in facilitating cation-specific separations. An introduction to the various equilibria affecting synergistic extraction using crown ethers is followed by a review of the work published in this field during the 1972−1999 time period. The influence of various solvent extraction parameters on the potential for cation-selective synergism is critically examined. 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subjects	CATIONS Chemistry CROWN ETHERS Exact sciences and technology Inorganic chemistry and origins of life INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Kinetics and mechanism of reactions SIZE SOLVENT EXTRACTION SYNERGISM
title	Incorporating Size Selectivity into Synergistic Solvent Extraction: A Review of Crown Ether-Containing Systems
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