Guest-Dependent High Pressure Phenomena in a Nanoporous Metal−Organic Framework Material

The nanoporous metal−organic framework material Cu3(1,3,5-benzenetricarboxylate)2(H2O)3•{guest} exhibits anomalous compression under applied pressure that is associated with the hyper-filling of the pore network. This behavior involves a dramatic transition between a “hard” regime (bulk modulus, K h...

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Veröffentlicht in:	Journal of the American Chemical Society 2008-08, Vol.130 (32), p.10524-10526
Hauptverfasser:	Chapman, Karena W, Halder, Gregory J, Chupas, Peter J
Format:	Artikel
Sprache:	eng
Schlagworte:	CAVITIES COMPRESSIBILITY COPPER COMPOUNDS FLUID INJECTION MATERIALS SCIENCE NANOSCIENCE AND NANOTECHNOLOGY NANOSTRUCTURES ORGANOMETALLIC COMPOUNDS PARTICLE SIZE POROUS MATERIALS
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