Investigations of the Exothermic Reactions of Natural Graphite Anode for Li-Ion Batteries during Thermal Runaway
Advances in the comparative study of the thermal behavior of graphite during the thermal runaway process are reviewed. The differential scanning calorimeter was used to evaluate the thermal runaway behavior of natural graphite (Mag-10) electrode material with different amounts of intercalated lithiu...
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| Veröffentlicht in: | Journal of the Electrochemical Society 2005, Vol.152 (1), p.A73-A79 |
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| container_title | Journal of the Electrochemical Society |
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| creator | Yang, Hui Bang, Hyunjoo Amine, Khalil Prakash, Jai |
| description | Advances in the comparative study of the thermal behavior of graphite during the thermal runaway process are reviewed. The differential scanning calorimeter was used to evaluate the thermal runaway behavior of natural graphite (Mag-10) electrode material with different amounts of intercalated lithium ions. The effect of the polyvinylidene fluoride binder on the thermal behavior of a fully lithiated sample was also investigated. This is the first time it has been noted that graphite loses its structure with more than 0.7 intercalated lithium when electrolyte is present at high temperature by detecting the existence of (002) graphite X-ray diffraction peak. |
| doi_str_mv | 10.1149/1.1836126 |
| format | Article |
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(ANL), Argonne, IL (United States)</creatorcontrib><title>Investigations of the Exothermic Reactions of Natural Graphite Anode for Li-Ion Batteries during Thermal Runaway</title><title>Journal of the Electrochemical Society</title><description>Advances in the comparative study of the thermal behavior of graphite during the thermal runaway process are reviewed. The differential scanning calorimeter was used to evaluate the thermal runaway behavior of natural graphite (Mag-10) electrode material with different amounts of intercalated lithium ions. The effect of the polyvinylidene fluoride binder on the thermal behavior of a fully lithiated sample was also investigated. This is the first time it has been noted that graphite loses its structure with more than 0.7 intercalated lithium when electrolyte is present at high temperature by detecting the existence of (002) graphite X-ray diffraction peak.</description><subject>ANODES</subject><subject>CHEMICAL REACTIONS</subject><subject>ENERGY STORAGE</subject><subject>GRAPHITE</subject><subject>HEAT</subject><subject>LITHIUM</subject><subject>METAL-NONMETAL BATTERIES</subject><issn>0013-4651</issn><issn>1945-7111</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNo9kF9LwzAUxYMoOKcPfoP4IvjQ2fxpmz7OMedgKIz5HNL0dot0SU1Sdd_eyoZPh8v93cM9B6Fbkk4I4eUjmRDBckLzMzQiJc-SghByjkZpSljC84xcoqsQPoaRCF6MULe0XxCi2aponA3YNTjuAM9_3CB-bzReg9L_u1cVe69avPCq25kIeGpdDbhxHq9MsnQWP6kYwRsIuO69sVu8-fMZTta9Vd_qcI0uGtUGuDnpGL0_zzezl2T1tljOpqtEs4zGpNKKA4iiESLPClELRnOgFa8rJqqsLhhPqU4ZE3mdVQUvBW2A0aqsoOY1YYqN0d3R1w3pZNDDs3qnnbWgoywZLWkxMPdHpvPusx9qkHsTNLStsuD6IKnIU5GLbAAfjqD2LgQPjey82St_kCSVf71LIk-9s18wRHVZ</recordid><startdate>2005</startdate><enddate>2005</enddate><creator>Yang, Hui</creator><creator>Bang, Hyunjoo</creator><creator>Amine, Khalil</creator><creator>Prakash, Jai</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7TB</scope><scope>8FD</scope><scope>FR3</scope><scope>L7M</scope><scope>OTOTI</scope></search><sort><creationdate>2005</creationdate><title>Investigations of the Exothermic Reactions of Natural Graphite Anode for Li-Ion Batteries during Thermal Runaway</title><author>Yang, Hui ; Bang, Hyunjoo ; Amine, Khalil ; Prakash, Jai</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c352t-bca4ee87f886578d8326e2b4db38b5d73402c03386d5b74982fe32b9bed4d13a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>ANODES</topic><topic>CHEMICAL REACTIONS</topic><topic>ENERGY STORAGE</topic><topic>GRAPHITE</topic><topic>HEAT</topic><topic>LITHIUM</topic><topic>METAL-NONMETAL BATTERIES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Hui</creatorcontrib><creatorcontrib>Bang, Hyunjoo</creatorcontrib><creatorcontrib>Amine, Khalil</creatorcontrib><creatorcontrib>Prakash, Jai</creatorcontrib><creatorcontrib>Argonne National Lab. 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| fulltext | fulltext |
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| ispartof | Journal of the Electrochemical Society, 2005, Vol.152 (1), p.A73-A79 |
| issn | 0013-4651 1945-7111 |
| language | eng |
| recordid | cdi_osti_scitechconnect_932927 |
| source | IOP Publishing Journals |
| subjects | ANODES CHEMICAL REACTIONS ENERGY STORAGE GRAPHITE HEAT LITHIUM METAL-NONMETAL BATTERIES |
| title | Investigations of the Exothermic Reactions of Natural Graphite Anode for Li-Ion Batteries during Thermal Runaway |
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